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Volume 104
Main Index

Issue 1


Molecular orbital study of cyanide complexes of BX3 and AlX3 (X = hydrogen, methyl, fluorine and chlorine)
Dennis S. Marynick, Linda Throckmorton, and Russell Bacquet
pp 1 - 5; DOI:
10.1021/ja00365a001
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Carbon-hydrogen bond dissociation energies in alkylbenzenes. Proton affinities of the radicals and the absolute proton affinity scale
Michael Mautner
pp 5 - 10; DOI:
10.1021/ja00365a002
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Electron spin echo studies of cholestane nitroxide motion in lecithin multibilayer dispersions and vesicles: detection of nitroxide probe motion and vesicle rotation
Keith Madden, Larry Kevan, Philip D. Morse, and Robert N. Schwartz
pp 10 - 13; DOI:
10.1021/ja00365a003
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Electron photodetachment study of sulfur hexafluoride anion: comments on the structure of sulfur hexafluoride anion
Paul S. Drzaic and John I. Brauman
pp 13 - 19; DOI:
10.1021/ja00365a004
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Chloronium ions as alkylating agents in the gas-phase ion-molecule reactions with negative temperature dependence
D. K. Sen Sharma and P. Kebarle
pp 19 - 24; DOI:
10.1021/ja00365a005
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The 6-X-benzonorbornyl system: a new motional dynamics probe
George C. Levy, D. J. Craik, B. Norden, Minh Tan Phan Viet, and A. Dekmezian
pp 25 - 28; DOI:
10.1021/ja00365a006
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Propagation of a redox reaction through a quinoid polymer film on an electrode
Motoo Fukui, Akira Kitani, Chantal Degrand, and Larry L. Miller
pp 28 - 33; DOI:
10.1021/ja00365a007
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Orientation of hyperfine tensors with respect to chemical bonds. Experimental and ab initio SCF + CI study in the nitroxide series
R. Briere, T. A. Claxton, Y. Ellinger, P. Rey, and J. Laugier
pp 34 - 38; DOI:
10.1021/ja00365a008
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The oscillatory Briggs-Rauscher reaction. 1. Examination of subsystems
Stanley D. Furrow and Richard M. Noyes
pp 38 - 42; DOI:
10.1021/ja00365a009
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The oscillatory Briggs-Rauscher reaction. 2. Effects of substitutions and additions
Stanley D. Furrow and Richard M. Noyes
pp 42 - 45; DOI:
10.1021/ja00365a010
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The oscillatory Briggs-Rauscher reaction. 3. A skeleton mechanism for oscillations
Richard M. Noyes and Stanley D. Furrow
pp 45 - 48; DOI:
10.1021/ja00365a011
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Mechanistic study of oscillations and bistability in the Briggs-Rauscher reaction
Patrick De Kepper and Irving R. Epstein
pp 49 - 55; DOI:
10.1021/ja00365a012
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Olefin rearrangement resulting from the gas-phase krypton fluoride laser photolysis of chromium hexacarbonyl
William Tumas, Barbara Gitlin, Alan M. Rosan, and James T. Yardley
pp 55 - 59; DOI:
10.1021/ja00365a013
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Localized excitations and the geometry of the n.pi.* excited states of pyrazine
Daniel A. Kleier, Richard L. Martin, Willard R. Wadt, and William R. Moomaw
pp 60 - 65; DOI:
10.1021/ja00365a014
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Comparison of minimal and extended basis sets in terms of resonant formulas. Application to 1,3 dipoles
P. C. Hiberty and G. Ohanessian
pp 66 - 70; DOI:
10.1021/ja00365a015
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Ab initio quantum mechanical calculations of the magnetic shielding constants of the different nuclei of cytosine
C. Giessner-Prettre and B. Pullman
pp 70 - 73; DOI:
10.1021/ja00365a016
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Electrostatic binding of electroactive and nonelectroactive anions in a surface-confined, electroactive polymer: selectivity of binding measured by Auger spectroscopy and cyclic voltammetry
James A. Bruce and Mark S. Wrighton
pp 74 - 82; DOI:
10.1021/ja00365a017
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(Tetrabenzoporphyrinato)nickel(II) iodide. A doubly mixed valence molecular conductor
Jens Martinsen, Laurel J. Pace, Terry E. Phillips, Brian M. Hoffman, and James A. Ibers
pp 83 - 91; DOI:
10.1021/ja00365a018
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Role of the crystal-field theory in determining the structures of spinels
Jeremy K. Burdett, Geoffrey D. Price, and Sarah L. Price
pp 92 - 95; DOI:
10.1021/ja00365a019
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Structures of [(Ph3C3)M(PPh3)2]+X- complexes. An experimental and theoretical study of ring-whizzing
Carlo Mealli, Stefano Midollini, Simonetta Moneti, Luigi Sacconi, Jerome Silvestre, and Thomas A. Albright
pp 95 - 107; DOI:
10.1021/ja00365a020
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Alkane dehydrogenation by iridium complexes
Robert H. Crabtree, Michelle F. Mellea, Jean M. Mihelcic, and Jennifer M. Quirk
pp 107 - 113; DOI:
10.1021/ja00365a021
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A second-order Jahn-Teller effect in a tetranuclear metal atom cluster compound
F. Albert Cotton and Anne Fang
pp 113 - 119; DOI:
10.1021/ja00365a022
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Electrophilic attack on a metal alkynyl by carbon disulfide: preparation and structure of [Fe(C2MeCS2Me)(dppe)(Cp)]I.MeOH, a cationic vinylidene complex
John P. Selegue
pp 119 - 124; DOI:
10.1021/ja00365a023
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Cyclometalation of dialkylbis(triethylphosphine)platinum(II) complexes: formation of Pt,Pt-bis(triethylphosphine)platinacycloalkanes
Robert DiCosimo, Stephen S. Moore, Allan F. Sowinski, and George M. Whitesides
pp 124 - 133; DOI:
10.1021/ja00365a024
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Higher coordinate cyanide and isocyanide complexes. 13. Crystal structure of the homoleptic seven-coordinate complex heptakis(tert-butyl isocyanide)chromium(II) hexafluorophosphate, [Cr(CN-t-Bu)7](PF6)2
John C. Dewan, William S. Mialki, Richard A. Walton, and Stephen J. Lippard
pp 133 - 136; DOI:
10.1021/ja00365a025
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Synthesis of a chiral O-bound sulfoxide from an S-bound sulfenate ion
Graeme J. Gainsford, William Gregory Jackson, and Alan M. Sargeson
pp 137 - 141; DOI:
10.1021/ja00365a026
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Synthesis and electrophile-induced disproportionation of the neutral formyl triphenylphosphinenitrosyl-.eta.-cyclopentadienylrhenium formyl ((.eta.-C5H5)Re(NO)(PPh3)(CHO))
Wilson Tam, Gong Yu Lin, Wai Kwok Wong, William A. Kiel, Victor K. Wong, and J. A. Gladysz
pp 141 - 152; DOI:
10.1021/ja00365a027
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Synthesis and chemistry of binary zerovalent transition metal phosphite complexes
Henry W. Choi and E. L. Muetterties
pp 153 - 161; DOI:
10.1021/ja00365a028
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Reaction of bicyclo[3.2.1]octa-2,6-diene with 1,2,4-triazoline-3,5-diones: competitive dipolar and homocycloaddition
Waldemar Adam, Ottorino De Lucchi, Karl Peters, Eva Maria Peters, and Hans Georg Von Schnering
pp 161 - 166; DOI:
10.1021/ja00365a029
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Asymmetric synthesis of (S)- and (R)-malic acid from ketene and chloral
Hans Wynberg and Emiel G. J. Staring
pp 166 - 168; DOI:
10.1021/ja00365a030
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Reaction of cyclohexane and cyclohexyl radicals with atomic and molecular oxygen
Nobuaki Washida and Hiroo Takagi
pp 168 - 173; DOI:
10.1021/ja00365a031
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Synthesis of an actinomycin-related peptide, cyclo-(Thr-D-Val-Pro-Sar-MeAla), and conformational studies by nuclear magnetic resonance and x-ray crystallography
A. B. Mauger, O. A. Stuart, R. J. Highet, and J. V. Silverton
pp 174 - 180; DOI:
10.1021/ja00365a032
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Asymmetric synthesis catalyzed by chiral ferrocenylphosphine-transition metal complexes. 2. Nickel- and palladium-catalyzed asymmetric Grignard cross-coupling
Tamio Hayashi, Mitsuo Konishi, Motoo Fukushima, Takaya Mise, Masahiro Kagotani, Masatoyo Tajika, and Makoto Kumada
pp 180 - 186; DOI:
10.1021/ja00365a033
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A qualitative valence-bond approach to organic reactivity. Application to elimination reactions
Addy Pross and Sason S. Shaik
pp 187 - 195; DOI:
10.1021/ja00365a034
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Positional selectivity in an encounter-controlled reaction: base-catalyzed proton exchange in amidinium ions
Charles L. Perrin, David A. Schiraldi, and Gloria Meichia L. Lin
pp 196 - 201; DOI:
10.1021/ja00365a035
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Displacement stereochemistry and product-formation selectivities in the solvolysis of cyclooctyl p-bromobenzenesulfonate
J. Eric Nordlander, Philip O. Owuor, Donna J. Cabral, and Jerome E. Haky
pp 201 - 206; DOI:
10.1021/ja00365a036
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Solvolytic reactivity of 1-trifluoromethyl-1-phenylethyl tosylate. Correlation of substituent effects in the formation of highly destabilized carbonium ions
Annette D. Allen, Michael P. Jansen, Kalavelil M. Koshy, Nevindra N. Mangru, and Thomas T. Tidwell
pp 207 - 211; DOI:
10.1021/ja00365a037
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Solvolytic studies of the highly deactivated 1-aryl-1-(trifluoromethyl)ethyl tosylates
Kwang Ting Liu, Mann Yan Kuo, and Ching Fen Sheu
pp 211 - 215; DOI:
10.1021/ja00365a038
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Mechanism for oxidation of phenylacetylenes with peroxymonophosphoric acid. Oxirene as an intermediate inconvertible to ketocarbene
Yoshiro Ogata, Yasuhiko Sawaki, and Takashi Ohno
pp 216 - 219; DOI:
10.1021/ja00365a039
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Generation of peroxy radicals from peroxynitrates (ROONO2). Decomposition of peroxybenzoyl nitrate (PBZN)
Richard A. Kenley and Dale G. Hendry
pp 220 - 224; DOI:
10.1021/ja00365a040
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Disproportionation-combination reactions of caged geminate radical pairs formed from the photodecomposition of 2,2'-azoisobutane. Anisotropic reorientation of tert-butyl radicals in viscous media and birth effects in very viscous media
Dennis D. Tanner and Parviz M. Rahimi
pp 225 - 229; DOI:
10.1021/ja00365a041
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Comparison of the solid and liquid solution states of representative phosphoranes by phosphorus-31 NMR
Larry W. Dennis, Victor J. Bartuska, and Gary E. Maciel
pp 230 - 235; DOI:
10.1021/ja00365a042
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5-Methyladenine: a transient intermediate in a translocative rearrangement
Ramachandra S. Hosmane, Venkatesalu Bakthavachalam, and Nelson J. Leonard
pp 235 - 239; DOI:
10.1021/ja00365a043
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Conformational dependence of isotope effects for hyperconjugating methyl groups. Nonadditivity of NMR isotope shifts in benzylic ions
David A. Forsyth, Peter Lucas, and Robert M. Burk
pp 240 - 245; DOI:
10.1021/ja00365a044
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A picosecond kinetic study of the excited-state properties of some osmium octaethylporphyrins
Nick Serpone, Thomas L. Netzel, and Martin Gouterman
pp 246 - 252; DOI:
10.1021/ja00365a045
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Quenching of the singlet excited states of meso-substituted porphines by p-benzoquinone under unimolecular and bimolecular conditions: evidence for electron transfer in competition with vibrational relaxation
M. A. Bergkamp, J. Dalton, and T. L. Netzel
pp 253 - 259; DOI:
10.1021/ja00365a046
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Antiallergenic 8-azapurines. 3. Structural characterization of 2-(2-propoxyphenyl)-8-azahypoxanthine, 2-[2-propoxy-5-(propylsulfonyl)phenyl]-8-azahypoxanthine, and 2-[2-propoxy-5-(N-methyl-N-isopropylsulfamoyl)phenyl]-8-azahypoxanthine
Scott R. Wilson, Roxy B. Wilson, Anita L. Shoemaker, K. R. H. Wooldridge, and Derek J. Hodgson
pp 259 - 264; DOI:
10.1021/ja00365a047
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Antimicrobial metabolites of the sponge Reniera sp
James M. Frincke and D. John Faulkner
pp 265 - 269; DOI:
10.1021/ja00365a048
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How flexible is the furanose ring? 1. A comparison of experimental and theoretical studies
Wilma K. Olson and Joel L. Sussman
pp 270 - 278; DOI:
10.1021/ja00365a049
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How flexible is the furanose ring? 2. An updated potential energy estimate
Wilma K. Olson
pp 278 - 286; DOI:
10.1021/ja00365a050
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Small ring heterocycles. Role of azabenzvalenes in the thermolysis of 3-cyclopropenyl substituted oxazolinones
Albert Padwa, Mitsuo Akiba, Leslie Cohen, Henry Gingrich, and Nobumasa Kamigata
pp 286 - 288; DOI:
10.1021/ja00365a051
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Stable monomeric complexes of molybdenum(III) and tungsten(III)
M. Millar, S. Lincoln, and S. A. Koch
pp 288 - 289; DOI:
10.1021/ja00365a052
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Nuclear shielding of trapped xenon obtained by proton-enhanced, magic-angle spinning xenon-129 NMR spectroscopy
John A. Ripmeester
pp 289 - 290; DOI:
10.1021/ja00365a053
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Organophosphorus compounds: the first applications of sulfuryl chloride fluoride SO2FCl in synthesis
Andrzej Lopusinski and Jan Michalski
pp 290 - 291; DOI:
10.1021/ja00365a054
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Macrocyclic effect in transition metal ion complexes of a mixed (nitrogen, oxygen) donor macrocycle
Robert D. Hancock and Vivienne J. Thom
pp 291 - 292; DOI:
10.1021/ja00365a055
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Photochemistry of syn- and anti-9,10-epoxy-1,4-dihydro-1,4-dipropyl-1,4-ethanonaphthalene-2,3-dione
C. C. Liao, H. S. Lin, T. H. Hseu, C. P. Tang, and J. L. Wang
pp 292 - 294; DOI:
10.1021/ja00365a056
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Twisting in alkene ion radicals
Dennis J. Bellville and Nathan L. Bauld
pp 294 - 295; DOI:
10.1021/ja00365a057
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Sequence-selective inhibition of restriction endonucleases by the polyintercalator bis(methidium)spermine
Richard A. Ikeda and Peter B. Dervan
pp 296 - 297; DOI:
10.1021/ja00365a058
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Titanocyclobutane: structural considerations
Anthony K. Rappe and William A. Goddard
pp 297 - 299; DOI:
10.1021/ja00365a059
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Deuterium isotope effects on carbon-13 chemical shifts in cyclophanes. Deshielding intrinsic through-space and through-bond effects
Ludger Ernst, Sayed Eltamany, and Henning Hopf
pp 299 - 300; DOI:
10.1021/ja00365a060
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Crystal structure of tetrakis(trimethylsilyl)ethylene at -70.degree.C
Hideki Sakurai, Yasuhiro Nakadaira, Hiromi Tobita, Tasuka Ito, Koshiro Toriumi, and Haruko Ito
pp 300 - 302; DOI:
10.1021/ja00365a061
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Reactions of carbon monoxide and alkyl isonitriles with rhodium octaethylporphyrin species: metallo formyl and formimidoyl complexes
Bradford B. Wayland, Bruce A. Woods, and Roberta Pierce
pp 302 - 303; DOI:
10.1021/ja00365a062
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A formal total synthesis of fusidic acid
William G. Dauben, Carl R. Kessel, Morio Kishi, Masanori Somei, Masahiro Tada, and Danielle Guillerm
pp 303 - 305; DOI:
10.1021/ja00365a063
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Structural effects on the photopolymerization of bilayer membranes
Encarnacion Lopez, David F. O'Brien, and Thomas H. Whitesides
pp 305 - 307; DOI:
10.1021/ja00365a064
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Measurement of relative rates of type I photolysis by chemically induced dynamic nuclear polarization
Linda J. Johnston, Paul De Mayo, and S. King Wong
pp 307 - 309; DOI:
10.1021/ja00365a065
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Inversion at tetracoordinate silicon in nucleophilic media. Ligand permutation in 3,3,3',3'-tetrakis(trifluoromethyl)-1,1'(3H,3'H)spirobi[2,1-benzoxasilole]
William H. Stevenson and J. C. Martin
pp 309 - 310; DOI:
10.1021/ja00365a066
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Stereochemical control of the internal Michael reaction. A new construction of trans-hydrindan systems
Gilbert Stork, Christopher S. Shiner, and Jeffrey D. Winkler
pp 310 - 312; DOI:
10.1021/ja00365a067
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Gas-phase reactions. 29. Thioacrolein
Hans Bock, Shamsher Mohmand, Takakuni Hirabayashi, and Andrzej Semkow
pp 312 - 313; DOI:
10.1021/ja00365a068
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Cleavage of double helical DNA by methidium-propyl-EDTA-iron(II)
Robert P. Hertzberg and Peter B. Dervan
pp 313 - 315; DOI:
10.1021/ja00365a069
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Crystal and molecular structure of the isobacteriochlorin 3,7-dimethyl-3',7'-dihydro-2,2',8,8',12,13,17,18-octaethylporphyrin. A model for sirohydrochlorin and siroheme
K. M. Barkigia, J. Fajer, C. K. Chang, and G. J. B. Williams
pp 315 - 317; DOI:
10.1021/ja00365a070
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Trans lengthening of metal-hydrogen bonds and steric modification of metal-phosphorus bond lengths in chloro- and hydrido-transition-metal-phosphine complexes
Glen B. Robertson and Paul A. Tucker
pp 317 - 318; DOI:
10.1021/ja00365a071
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Regiospecific cleavage of strained tri- and tetraquinane .beta.-diketones via retro-Claisen reaction
W. C. Han, K. Takahashi, J. M. Cook, U. Weiss, and J. V. Silverton
pp 318 - 321; DOI:
10.1021/ja00365a072
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Alkynolate anions via a new rearrangement: the carbon analog of the Hofmann reaction
Conrad J. Kowalski and Kevin W. Fields
pp 321 - 323; DOI:
10.1021/ja00365a073
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Syn and anti transition states in the addition of ammonia to cyanoacetylene. Formation of a stable zwitterionic intermediate
K. N. Houk, Robert W. Strozier, Melvin D. Rozeboom, and Shigeru Nagase
pp 323 - 325; DOI:
10.1021/ja00365a074
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Stabilization of the monoanion of 1,8-diaminonaphthalene by intramolecular hydrogen bonding. A novel case of amide ion homoconjugation in a superbase solution
Edward M. Arnett, K. G. Venkatasubramanian, Robert T. McIver, Elaine K. Fukuda, Frederick G. Bordwell, and Richard D. Press
pp 325 - 326; DOI:
10.1021/ja00365a075
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Chemical excision of apurinic acids from RNA. A structurally modified yeast tRNAPhe
Kazuya Nishikawa, Benjamin L. Adams, and Sidney M. Hecht
pp 326 - 328; DOI:
10.1021/ja00365a076
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A mixed-metal nitridocarbonyl cluster compound. Synthesis and x-ray structure of the [PtRh10N(.mu.-CO)10(CO)11]3- anion
Secondo Martinengo, Gianfranco Ciani, and Angelo Sironi
pp 328 - 330; DOI:
10.1021/ja00365a077
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Geometric and electronic structure of ethane dication
George A. Olah and Massimo Simonetta
pp 330 - 331; DOI:
10.1021/ja00365a078
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Phosphinyl radicals as ligands: preparation of novel paramagnetic organometallic compounds
A. H. Cowley, R. A. Kemp, and J. C. Wilburn
pp 331 - 332; DOI:
10.1021/ja00365a079
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.beta.-Methylene-DL-aspartic acid: a selective inhibitor of glutamate-aspartate transaminase
Arthur J. L. Cooper, Susan M. Fitzpatrick, Christopher Kaufman, and Paul Dowd
pp 332 - 334; DOI:
10.1021/ja00365a080
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Bimolecular thermal reactions of 5-methylene-1,3-cyclohexadiene (o-isotoluene) and 3-methylene-1,4-cyclohexadiene (p-isotoluene)
Joseph J. Gajewski and Andrea M. Gortva
pp 334 - 335; DOI:
10.1021/ja00365a081
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Gas-phase ion chemistry of 5-methylene-1,3-cyclohexadiene (o-isotoluene) and 3-methylene-1,4-cyclohexadiene (p-isotoluene)
John E. Bartmess
pp 335 - 337; DOI:
10.1021/ja00365a082
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Ziegler-Natta polymerization: the lanthanide model
Patricia L. Watson
pp 337 - 339; DOI:
10.1021/ja00365a083
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Biosynthesis of elaiomycin. 1. Incorporation of labeled forms of n-octylamine
Ronald J. Parry, H. Surya Prakash Rao, and Jay Mueller
pp 339 - 340; DOI:
10.1021/ja00365a084
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Synthesis and spectroscopic properties of a novel cofacial chlorophyll-based dimer
Rodney R. Bucks and Steven G. Boxer
pp 340 - 343; DOI:
10.1021/ja00365a085
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The biosynthesis of streptonigrin. 5. Biosynthesis of streptonigrin from [U-13C6]-D-glucose. Origin of the quinoline quinone
Steven J. Gould and David E. Cane
pp 343 - 346; DOI:
10.1021/ja00365a086
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The synthesis of a helical ferrocene
Thomas J. Katz and Jaan Pesti
pp 346 - 347; DOI:
10.1021/ja00365a087
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Catalytic hydrolysis of esters of p-nitrophenol bound by amylose in the dimethyl sulfoxide-water mixed-solvent system
Yongzheng Hui, Shujing Wang, and Kikui Jiang
pp 347 - 349; DOI:
10.1021/ja00365a088
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Reduction of carbon dioxide and carbonyl sulfide by anionic Group VIB metal hydrides and alkyls. Carbon-hydrogen and carbon-carbon bond formation processes and the structure of [PNP][Cr(CO)5SC(O)H]
Donald J. Darensbourg and Andrzej Rokicki
pp 349 - 350; DOI:
10.1021/ja00365a089
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Structure and dynamics of the trimethylcyclopropenyl radical as determined by electron and nuclear magnetic resonance
G. L. Closs, W. T. Evanochko, and J. R. Norris
pp 350 - 352; DOI:
10.1021/ja00365a090
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Carbon-hydrogen activation in completely saturated hydrocarbons: direct observation of M + R-H .fwdarw. M(R)(H)
Andrew H. Janowicz and Robert G. Bergman
pp 352 - 354; DOI:
10.1021/ja00365a091
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Deuterium isotope effects on the solvolysis of 1-(1-adamantyl)ethyl sulfonate esters
V. J. Shiner, Thomas E. Neumann, and Robert D. Fisher
pp 354 - 355; DOI:
10.1021/ja00365a092
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Wavelength-controlled production of previtamin D3
William G. Dauben and Richard B. Phillips
pp 355 - 356; DOI:
10.1021/ja00365a093
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A threo and Cram selective aldol-lactonization reaction and its application to the synthesis of Prelog-Djerassi lactonic acid
R. H. Schlessinger and M. A. Poss
pp 357 - 358; DOI:
10.1021/ja00365a094
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Lewis acid catalyzed cyclocondensations of functionalized dienes with aldehydes
Samuel Danishefsky, James F. Kerwin, and Susumu Kobayashi
pp 358 - 360; DOI:
10.1021/ja00365a095
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Stereochemical consequences of the Lewis acid catalyzed cyclocondensation of oxygenated dienes with aldehydes. A rapid and stereoselective entry to various natural products derived from propionate
Samuel Danishefsky, Nobuo Kato, David Askin, and James F. Kerwin
pp 360 - 362; DOI:
10.1021/ja00365a096
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Two-dimensional NMR investigation of amide proton exchange in aqueous solution
J. D. Cutnell
pp 362 - 363; DOI:
10.1021/ja00365a097
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Structure of ristocetin A: configurational studies of the peptide
Constance M. Harris and Thomas M. Harris
pp 363 - 365; DOI:
10.1021/ja00365a098
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Preparation and crystal structure of [Mo3S8(NNMe2)2]2- a trinuclear sulfido-bridged molybdenum anion with coordinated isodiazene ligands
J. R. Dilworth, Jon Zubieta, and J. R. Hyde
pp 365 - 367; DOI:
10.1021/ja00365a099
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Annulated sugars: the 1,2-O-isopropylidene ring as a stereo-, regio-, and chemoselective agent
King Mo Sun, Bert Fraser-Reid, and Tim Fat Tam
pp 367 - 369; DOI:
10.1021/ja00365a100
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Book Reviews

pp 369 - 372; DOI:
10.1021/ja00365a600
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Issue 2


Quantum and statistical mechanical studies of liquids. 20. Pressure dependence of hydrogen bonding in liquid methanol
William L. Jorgensen and Mustafa Ibrahim
pp 373 - 378; DOI:
10.1021/ja00366a001
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Applicability of the Solomon-Bloembergen equation to the study of paramagnetic transition metal-water complexes. An ab initio SCF-MO study
Lars Nordenskiold, Aatto Laaksonen, and Jozef Kowalewski
pp 379 - 382; DOI:
10.1021/ja00366a002
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Nuclear magnetic resonance studies of terpenes with chiral and achiral lanthanide(III)-silver(I) binuclear shift reagents
Thomas J. Wenzel and Robert E. Sievers
pp 382 - 388; DOI:
10.1021/ja00366a003
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Chiral discrimination in the monolayer packing of N-(.alpha.-methylbenzyl)stearamides on aqueous acid subphases: thermodynamic behavior
Edward M. Arnett, Jean Chao, Barbara Kinzig, Martin V. Stewart, Orlean Thompson, and Robert J. Verbiar
pp 389 - 400; DOI:
10.1021/ja00366a004
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Covalently attached dianions as sensitizers for photogalvanic effects at semiconductor electrodes
James R. Hohman and Marye Anne Fox
pp 401 - 404; DOI:
10.1021/ja00366a005
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Iterative analysis of exchange-broadened NMR band shapes. The mechanism of correlated rotations in triaryl derivatives of phosphorus and arsenic
Eva E. Wille, David S. Stephenson, Peter Capriel, and Gerhard Binsch
pp 405 - 415; DOI:
10.1021/ja00366a006
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Assignment of the infrared spectrum for the ethyl radical
J. Pacansky and M. Dupuis
pp 415 - 421; DOI:
10.1021/ja00366a007
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In vitro analogs of photosystem II. Combined flash photolytic and conductometric study of light-induced oxygen evolution from water mediated by colloidal rubidium dioxide/titanium dioxide
Robin Humphry-Baker, Jochen Lilie, and Michael Graetzel
pp 422 - 425; DOI:
10.1021/ja00366a008
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Temporary anion states of phosphabenzene, arsabenzene, and stibabenzene. Trends in the .pi. and .pi.* orbital energies
P. D. Burrow, A. J. Ashe, D. J. Bellville, and K. D. Jordan
pp 425 - 429; DOI:
10.1021/ja00366a009
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Monomer-to-micelle transition of dihexanoylphosphatidylcholine: carbon-13 NMR and Raman studies
Ramon A. Burns, Mary F. Roberts, Richard Dluhy, and Richard Mendelsohn
pp 430 - 438; DOI:
10.1021/ja00366a010
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Studies of phosphorus(III) ligands and their complexes of nickel(II), palladium(II), and platinum(II) immobilized on insoluble supports by high-resolution solid-state phosphorus-31 NMR using magic-angle spinning techniques
L. Bemi, H. C. Clark, J. A. Davies, C. A. Fyfe, and R. E. Wasylishen
pp 438 - 445; DOI:
10.1021/ja00366a011
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Effects of magnesium(II) on the conformation of tetracycline in dimethyl sulfoxide solution
Grover W. Everett, Janet Gulbis, and Jiajiu Shaw
pp 445 - 447; DOI:
10.1021/ja00366a012
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Olefin metathesis - a mechanistic study of high-valent Group VI catalysts
Anthony K. Rappe and William A. Goddard
pp 448 - 456; DOI:
10.1021/ja00366a013
PDF
Functionally polymerized surfactant vesicles. Synthesis and characterization
Pietro Tundo, Donald J. Kippenberger, Patricia L. Klahn, E. Prieto Nelson, T. C. Jao, and Janos H. Fendler
pp 456 - 461; DOI:
10.1021/ja00366a014
PDF
Nucleoside complexing: a carbon-13 NMR spectroscopic study of binding of metal ions to guanosine and related nucleosides in solution. Evidence for O-6 binding under basic conditions
Luigi G. Marzilli, Baltazar De Castro, and Carmen Solorzano
pp 461 - 466; DOI:
10.1021/ja00366a015
PDF
Improvement of photoelectrochemical hydrogen generation by surface modification of p-type silicon semiconductor photocathodes
Raymond N. Dominey, Nathan S. Lewis, James A. Bruce, Dana C. Bookbinder, and Mark S. Wrighton
pp 467 - 482; DOI:
10.1021/ja00366a016
PDF
Reactivity of .mu.-(.eta.1:.eta.5-cyclopentadienyl)-tris(.eta.-cyclopentadienyl)dititanium ([.mu.-(.eta.1:.eta.5-C5H4)](.eta.-C5H5)3Ti2) with dinitrogen. Structure of a titanium complex with a triply coordinated dinitrogen ligand
Guido P. Pez, Peter Apgar, and Richard K. Crissey
pp 482 - 490; DOI:
10.1021/ja00366a017
PDF
Electron paramagnetic resonance spectra and molecular structure of vanadium hexacarbonyl
Stephen W. Bratt, Andrew Kassyk, Robin N. Perutz, and Martyn C. R. Symons
pp 490 - 494; DOI:
10.1021/ja00366a018
PDF
Structural characterization of a variable-spin(porphinato)iron(III) complex. Molecular stereochemistry of bis(3-chloropyridine)(octaethylporphinato)iron(III) perchlorate at 98 K (S = 1/2) and 293 K (S = 1/2, S = 5/2)
W. Robert Scheidt, David K. Geiger, and Kenneth J. Haller
pp 495 - 499; DOI:
10.1021/ja00366a019
PDF
Reactions of iron pentacarbonyl and dihydrogen tetracarbonylferrate related to the water-gas shift reaction
Ralph G. Pearson and Heiko Mauermann
pp 500 - 504; DOI:
10.1021/ja00366a020
PDF
Systematic design of chemical oscillators. 5. Bistability and oscillations in the autocatalytic chlorite-iodide reaction in a stirred-flow reactor
Christopher E. Dateo, Miklos Orban, Patrick De Kepper, and Irving R. Epstein
pp 504 - 509; DOI:
10.1021/ja00366a021
PDF
Diacetylene monomers and polymers with chiral substituents: structure, solid-state polymerization, and properties
Roxy B. Wilson, Eileen N. Duesler, David Y. Curtin, Iain C. Paul, Ray H. Baughman, and Anthony F. Preziosi
pp 509 - 516; DOI:
10.1021/ja00366a022
PDF
Mechanisms for the photooxidation of protoporphyrin IX in solution
G. Sidney Cox and David G. Whitten
pp 516 - 521; DOI:
10.1021/ja00366a023
PDF
Preliminary studies of the mechanism of metal-halogen exchange. The kinetics of reaction of n-butyllithium with substituted bromobenzenes in hexane solution
Harold R. Rogers and Janette Houk
pp 522 - 525; DOI:
10.1021/ja00366a024
PDF
Kinetics of reductions of substituted benzaldehydes with B-alkyl-9-borabicyclo[3.3.1]nonane (9-BBN)
M. Mark Midland and Stephen A. Zderic
pp 525 - 528; DOI:
10.1021/ja00366a025
PDF
Thermal reactions of B-alkyl-9-borabicyclo[3.3.1]nonane (9-BBN). Evidence for unusually facile dehydroboration with B-pinanyl-9-BBN
M. Mark Midland, Janet E. Petre, Stephen A. Zderic, and Aleksander Kazubski
pp 528 - 531; DOI:
10.1021/ja00366a026
PDF
Hydroboration kinetics. 3. Kinetics and mechanism of the hydroboration of alkynes with 9-borabicyclo[3.3.1]nonane dimer. Effect of structure on the reactivity of representative alkynes
Kung K. Wang, Charles G. Scouten, and Herbert C. Brown
pp 531 - 536; DOI:
10.1021/ja00366a027
PDF
Total synthesis of the antitumor antibiotic streptonigrin
Steven M. Weinreb, Fatima Z. Basha, Satoshi Hibino, Nazir A. Khatri, Deukjoon Kim, Walter E. Pye, and Tai Teh Wu
pp 536 - 544; DOI:
10.1021/ja00366a028
PDF
Photochemical epoxidation of aflatoxin B1 and sterigmatocystin: synthesis of guanine-containing adducts
George Buechi, Kerry W. Fowler, and Alex M. Nadzan
pp 544 - 547; DOI:
10.1021/ja00366a029
PDF
Crown cation complex effects. 15. Phase-transfer synthesis of arenediazocyanides and synthesis of arenediazosulfones from arenediazonium cations and the formation of reduced pyridazines by 2 + 4 cycloaddition reactions
Michael F. Ahern, Ahuva Leopold, James R. Beadle, and George W. Gokel
pp 548 - 554; DOI:
10.1021/ja00366a030
PDF
Dimethylaluminum chloride catalyzed ene reactions of aldehydes
Barry B. Snider, David J. Rodini, Thomas C. Kirk, and Robert Cordova
pp 555 - 563; DOI:
10.1021/ja00366a031
PDF
Coenzyme models. 31. Efficient trapping of transient thiazolium-aldehyde adducts (active aldehydes) by intramolecular and quasi-intramolecular flavins. Flavin-thiamin biscoenzyme
Seiji Shinkai, Takaharu Yamashita, Yumiko Kusano, and Osamu Manabe
pp 563 - 568; DOI:
10.1021/ja00366a032
PDF
Evaluation of addition rates of thiyl radicals to vinyl monomers by flash photolysis. 4. Solvent effects on rates of free-radical reactions. Addition of the p-aminobenzenethiyl radical to styrene
Osamu Ito and Minoru Matsuda
pp 568 - 572; DOI:
10.1021/ja00366a033
PDF
Determination of proline ring nonplanarity from proton spin-spin coupling constants: applications to two cyclic pentapeptides
Alvin C. Bach, Aksel A. Bothner-By, and Lila M. Gierasch
pp 572 - 576; DOI:
10.1021/ja00366a034
PDF
Direct observation of the calcium-43 NMR signals from calcium(2+) bound to proteins
Thomas Andersson, Torbjoern Drakenberg, Sture Forsen, Eva Thulin, and Marianne Swaerd
pp 576 - 580; DOI:
10.1021/ja00366a035
PDF
Luminescent photoelectrochemical cells. 6. Spatial aspects of the photoluminescence and electroluminescence of cadmium selenide electrodes
Holger H. Streckert, Jiuru Tong, and Arthur B. Ellis
pp 581 - 588; DOI:
10.1021/ja00366a036
PDF
Theory of nuclear substitution and the hemistructural relationship. The origin of bond length and bond energy additivity
Joseph R. Murdoch
pp 588 - 600; DOI:
10.1021/ja00366a037
PDF
Proton-transfer reactions between 9-alkylfluorene and (9-alkylfluorenyl)lithium in ether
J. R. Murdoch, J. A. Bryson, D. F. McMillen, and J. I. Brauman
pp 600 - 610; DOI:
10.1021/ja00366a038
PDF
Molecular structure of dichloro(endo-dicyclopentadiene)palladium(II). Unsymmetrically bound olefins and the preferred site of nucleophilic attack
Laura L. Wright, Richard M. Wing, and Michael F. Rettig
pp 610 - 612; DOI:
10.1021/ja00366a039
PDF
Nickel(II)-promoted ethanolysis and hydrolysis of N-(2-pyridylmethyl)urea. A model for urease
Robert L. Blakeley, Anthony Treston, Robert K. Andrews, and Burt Zerner
pp 612 - 614; DOI:
10.1021/ja00366a040
PDF
Reactions in molecular inclusion complexes. 5. Differentiation between reaction pathways in the photoaddition of guest p-fluoroacetophenone to host deoxycholic acid via x-ray analysis of a complex undergoing a single-crystal-to-single-crystal transformation
H. C. Chang, R. Popovitz-Biro, M. Lahav, and L. Leiserowitz
pp 614 - 616; DOI:
10.1021/ja00366a041
PDF
Experimental analysis of .gamma.-hydrogen hyperfine splittings in acyclic aliphatic radicals. Confirmation of theoretical predictions
K. U. Ingold and J. C. Walton
pp 616 - 617; DOI:
10.1021/ja00366a042
PDF
Electron-transfer initiated photoaddition of allylsilanes to 1-methyl-2-phenylpyrrolinium perchlorate. A novel allylation methodology
Kazuya Ohga and Patrick S. Mariano
pp 617 - 619; DOI:
10.1021/ja00366a043
PDF
Diverse mechanisms of carbon-hydrogen bond formation through binuclear reductive elimination reactions
Mario J. Nappa, Roberto Santi, Steven P. Diefenbach, and Jack Halpern
pp 619 - 621; DOI:
10.1021/ja00366a044
PDF
Ligand effects on transition metal-alkyl bond dissociation energies
Flora T. T. Ng and Garry L. Rempel
pp 621 - 623; DOI:
10.1021/ja00366a045
PDF
Kinetic determination of transition metal-alkyl bond dissociation energies: application to organocobalt compounds related to B12 coenzymes
Tsung Ting Tsou, Melanie Loots, and Jack Halpern
pp 623 - 624; DOI:
10.1021/ja00366a046
PDF
Crown-cation complex effects. 15. Lariat ethers. 4. Chain length and ring size effects in macrocyclic polyethers having neutral donor groups on flexible arms
Rose Ann Schultz, Dennis M. Dishong, and George W. Gokel
pp 625 - 626; DOI:
10.1021/ja00366a047
PDF
Soret-excited resonance Raman spectrum of (carbon monoxy)leghemoglobin: assignment of .nu.Fe-CO
R. S. Armstrong, M. J. Irwin, and P. E. Wright
pp 626 - 627; DOI:
10.1021/ja00366a048
PDF
Lewis acid assisted reaction of N-formylimidazole with a transition metal complex. Formyl group transfer
Phillip A. Kongshaug, Kim R. Haugen, and Roy G. Miller
pp 627 - 629; DOI:
10.1021/ja00366a049
PDF
Some structural effects on triplet biradical lifetimes. Norrish II and Paterno-Buchi biradicals
Richard A. Caldwell, Tetsuro Majima, and Chyongjin Pac
pp 629 - 630; DOI:
10.1021/ja00366a050
PDF
Application of the energy gap law to the decay of charge-transfer excited states
Jonathan V. Caspar, Edward M. Kober, B. Patrick Sullivan, and Thomas J. Meyer
pp 630 - 632; DOI:
10.1021/ja00366a051
PDF
On coupling carbenes and carbynes
Roald Hoffmann, Charles N. Wilker, and Odile Eisenstein
pp 632 - 634; DOI:
10.1021/ja00366a052
PDF
Oligomerization of Vinyl Monomers. 2. Evidence for a conformationally restrained six-membered ring containing lithium ion
C. Mathis and T. E. Hogen-Esch
pp 634 - 635; DOI:
10.1021/ja00366a053
PDF
Chiral aggregation phenomena. 4. A search for stereospecific interactions between highly purified enantiomeric and racemic dipalmitoyl phosphatidylcholines and other chiral surfactants in monolayers, vesicles, and gels
Edward M. Arnett and Jeffrey M. Gold
pp 636 - 639; DOI:
10.1021/ja00366a054
PDF
Book Reviews

pp 640 - 640; DOI:
10.1021/ja00366a600
PDF

Issue 3


XPS studies of core binding energies in transition metal complexes. 2. Ligand group shifts
Robert D. Feltham and Patrick Brant
pp 641 - 645; DOI:
10.1021/ja00367a001
PDF
Photofragment spectrum of C-state hydrogen cyanide. Theoretical interpretation
David T. Chuljian and Jack Simons
pp 646 - 652; DOI:
10.1021/ja00367a002
PDF
Infrared photochemistry of [(C2H5)2O]2H+ and C3F6+. A comparison of pulsed and continuous-wave laser photodissociation methods
Joseph M. Jasinski, Robert N. Rosenfeld, Felix K. Meyer, and John I. Brauman
pp 652 - 658; DOI:
10.1021/ja00367a003
PDF
Infrared multiphoton dissociation of the methanol solvate of the fluoride ion, CH3OHF-
Robert N. Rosenfeld, Joseph M. Jasinski, and John I. Brauman
pp 658 - 663; DOI:
10.1021/ja00367a004
PDF
Infrared multiphoton photodetachment of negative ion ions in the gas phase
Felix K. Meyer, Joseph M. Jasinski, Robert N. Rosenfeld, and John I. Brauman
pp 663 - 667; DOI:
10.1021/ja00367a005
PDF
Peroxy radical probe for motion in poly(tetrafluoroethylene) chains
Darbha Suryanarayana, Larry Kevan, and Shulamith Schlick
pp 668 - 673; DOI:
10.1021/ja00367a006
PDF
Proton, carbon-13, and phosphorus-31 NMR study of primary and secondary phenylamines, -phosphines, and -arsines and their anions
Raymond Batchelor and Thomas Birchall
pp 674 - 679; DOI:
10.1021/ja00367a007
PDF
Comparative studies of molybdenum-molybdenum and tungsten-tungsten quadruple bonds by SCF-X.alpha.-SW calculations and photoelectron spectroscopy
F. Albert Cotton, John L. Hubbard, Dennis L. Lichtenberger, and Irene Shim
pp 679 - 686; DOI:
10.1021/ja00367a008
PDF
Sodium(+) complexes with spiro-bis-crown ethers: stoichiometries, stabilities, and labilities in pyridine solution
James Bouquant, Alfred Delville, Jean Grandjean, and Pierre Laszlo
pp 686 - 691; DOI:
10.1021/ja00367a009
PDF
Ab initio SCF studies of interactions of lithium(+), sodium(+), beryllium(2+), and magnesium(2+) ions with dihydrogen phosphate(-) ion: model for cation binding to nucleic acids
Peter Liebmann, Gilda Loew, A. D. McLean, and George R. Pack
pp 691 - 697; DOI:
10.1021/ja00367a010
PDF
(.pi.-Allyl)palladium complex ion pairs containing two different, mobile .pi.-allyl groups: NMR and x-ray crystallographic studies
Louis S. Hegedus, Bjoern Aakermark, David J. Olsen, Oren P. Anderson, and Krister Zetterberg
pp 697 - 704; DOI:
10.1021/ja00367a011
PDF
Reaction of isopropyl(pentaaqua)chromium(III) ion with molecular oxygen in aqueous solution: kinetics of the chain reaction and effects of chain-breaking reagents and of variable ionic strength
Debra Ann Ryan and James H. Espenson
pp 704 - 712; DOI:
10.1021/ja00367a012
PDF
Systematic design of chemical oscillators. 6. Nitrous acid decomposition catalyzed by an iron(II) complex: tris(3,4,7,8-tetramethyl-1,10-phenanthroline)iron(II)
Irving R. Epstein, Kenneth Kustin, and Reuben H. Simoyi
pp 712 - 717; DOI:
10.1021/ja00367a013
PDF
Magnetic exchange in imidazolate-bridged copper(II) complexes
Gary Kolks, Stephen J. Lippard, Joseph V. Waszczak, and Henry R. Lilienthal
pp 717 - 725; DOI:
10.1021/ja00367a014
PDF
Neighboring group participation in organic redox reactions. 5. The directive and kinetic effects of hydroxyl groups on thioether oxidation
Albert S. Hirschon, Joyce Takahashi Doi, and W. Kenneth Musker
pp 725 - 730; DOI:
10.1021/ja00367a015
PDF
Intramolecular general-base catalysis of Schiff-base hydrolysis by tertiary amino groups
Tadashi Okuyama, Hiroshi Shibuya, and Takayuki Fueno
pp 730 - 736; DOI:
10.1021/ja00367a016
PDF
Synthesis, structure, and bonding of the [Fe4(NO)4(.mu.3-S)2(.mu.3-NCMe3)2]n series (n = 0,-1) containing a cubane-like Fe4S2N2 core: stereochemical influence due to one-electron reduction of a completely bonding tetrahedral metal system
Cynthia Ting Wah Chu, Robert S. Gall, and Lawrence F. Dahl
pp 737 - 746; DOI:
10.1021/ja00367a017
PDF
Synthesis of racemic fomannosin and illudol using a biosynthetically patterned common intermediate
M. F. Semmelhack, Shuji Tomoda, Hiroto Nagaoka, Susan D. Boettger, and Kenneth M. Hurst
pp 747 - 759; DOI:
10.1021/ja00367a018
PDF
Synthetic models related to DNA intercalating molecules: comparison between quinacrine and chloroquine in their ring-ring interaction with adenine and thymine
Jean Bolte, Colette Demuynck, M. France Lhomme, Jean Lhomme, Jacques Barbet, and Bernard P. Roques
pp 760 - 765; DOI:
10.1021/ja00367a019
PDF
Direct studies of 1,1-diazenes. Syntheses, infrared and electronic spectra, and kinetics of the thermal decomposition of N-(2,2,6,6-tetramethylpiperidyl)nitrene and N-(2,2,5,5-tetramethylpyrrolidyl)nitrene
William D. Hinsberg, Peter G. Schultz, and Peter B. Dervan
pp 766 - 773; DOI:
10.1021/ja00367a020
PDF
An expedient synthesis of 1,16-dimethyldodecahedrane
Leo A. Paquette and Douglas W. Balogh
pp 774 - 783; DOI:
10.1021/ja00367a021
PDF
Comparative x-ray crystal structure analysis of C2v-dimethylmonosecododecahedrane and D3d-dimethyldodecahedrane. The remarkable consequences of a missing framework bond on molecular topology
Gary G. Christoph, Peter Engel, R. Usha, Douglas W. Balogh, and Leo A. Paquette
pp 784 - 791; DOI:
10.1021/ja00367a022
PDF
Polymerized phosphatidylcholine vesicles. Synthesis and characterization
Steven L. Regen, Alok Singh, Guenther Oehme, and Maninder Singh
pp 791 - 795; DOI:
10.1021/ja00367a023
PDF
Generation of superoxide radicals by photolysis of oxygenated ethanol solutions
Benon H. J. Bielski and Janusz M. Gebicki
pp 796 - 798; DOI:
10.1021/ja00367a024
PDF
Poly(ethylenimines) with alternative (alkylamino)pyridines as nucleophilic catalysts
Edward J. Delaney, Leigh E. Wood, and Irving M. Klotz
pp 799 - 807; DOI:
10.1021/ja00367a025
PDF
The pyridinium-dihydropyridine system. Reduction potentials and the mechanism of oxidation of 1,4-dihydropyridines by a Schiff base
R. Srinivasan, Richard T. Medary, Harvey F. Fisher, Donald J. Norris, and Ross Stewart
pp 807 - 812; DOI:
10.1021/ja00367a026
PDF
Ozonolysis of cis- and trans-1,2-difluoroethylene: isolation and characterization of trans-1,2-difluoroethylene oxide and cis,trans-1,2,3-trifluorocyclopropane
John W. Agopovich and Charles W. Gillies
pp 813 - 817; DOI:
10.1021/ja00367a027
PDF
Electron transfer induced reactions. Electrochemically stimulated aromatic nucleophilic substitution in organic solvents
Christian Amatore, Jean Pinson, Jean Michel Saveant, and Andre Thiebault
pp 817 - 826; DOI:
10.1021/ja00367a028
PDF
2,2-Disubstituted-4,4-dimethylimidazolidinyl-3-oxy nitroxides: indicators of aqueous acidity through variation of aN with pH
John F. W. Keana, Michael J. Acarregui, and Sharyl L. M. Boyle
pp 827 - 830; DOI:
10.1021/ja00367a029
PDF
Studies on spin-trapped radicals in .gamma.-irradiated aqueous solutions of L-alanylglycine and L-alanyl-L-alanine by high-performance liquid chromatography and ESR spectroscopy
Fumio Moriya, Keisuke Makino, Nobuhiro Suzuki, Souji Rokushika, and Hiroyuki Hatano
pp 830 - 836; DOI:
10.1021/ja00367a030
PDF
Active site studies of neurohypophyseal hormones: comparison of oxytocin and arginine-vasopressin with analogs containing 4-D-glutamine
Victor J. Hruby, Henry I. Mosberg, and Venkatappa Viswanatha
pp 837 - 841; DOI:
10.1021/ja00367a031
PDF
Kinetics analysis of cytochrome b5 reduction by (ethylenediaminetetraacetato)ferrate(2-) ion
Lorne S. Reid and A. Grant Mauk
pp 841 - 845; DOI:
10.1021/ja00367a032
PDF
Stereochemistry and mechanism of an acid-catalyzed 1,2-phospho group migration: evidence for pseudorotation in the reaction of a phosphoric monoester
Stephen L. Buchwald, Diana H. Pliura, and Jeremy R. Knowles
pp 845 - 847; DOI:
10.1021/ja00367a033
PDF
A cyclobutadiene oxide (Dewar furan)
David Wirth and David M. Lemal
pp 847 - 848; DOI:
10.1021/ja00367a034
PDF
Silver ion affinities of alcohols as ordered by mass spectrometry/mass spectrometry
S. A. McLuckey, A. E. Schoen, and R. G. Cooks
pp 848 - 850; DOI:
10.1021/ja00367a035
PDF
MINDO/3-based transition-state models for the menshutkin reaction. Iodomethylation of alkylpyridines
Jimmy W. Viers, John C. Schug, and Jeffrey I. Seeman
pp 850 - 851; DOI:
10.1021/ja00367a036
PDF
Lyophilization results in cleavage of the active-site histidine bridge in the four-copper form of bovine erythrocyte superoxide dismutase
Kenneth G. Strothkamp and Stephen J. Lippard
pp 852 - 853; DOI:
10.1021/ja00367a037
PDF
Chemistry of exciplexes. 12. Chemistry of heterodimers of benzene and anthracene
Nien Chu C. Yang, Ming Jang Chen, Peter Chen, and Kwok Tim Mak
pp 853 - 855; DOI:
10.1021/ja00367a038
PDF
Heptamethylindenyl lanthanide(III) complexes of lanthanum, neodymium, and erbium
Minoru Tsutsui, Li Ban Chen, David E. Bergbreiter, and T. Ken Miyamoto
pp 855 - 856; DOI:
10.1021/ja00367a039
PDF
The laser vs. the lamp: a novel laser-induced adiabatic reaction and luminescence of benzophenones
Nicholas J. Turro, Masayuki Aikawa, and Ian R. Gould
pp 856 - 858; DOI:
10.1021/ja00367a040
PDF
Metal-metal bonded complexes of the early transition metals. 3. Synthesis, structure, and reactivity of hydrobis(trimethylphosphine)dichlorotantalum dimer (Ta2Cl4(PMe3)4H2 (Ta:Ta))
R. B. Wilson, A. P. Sattelberger, and J. C. Huffman
pp 858 - 860; DOI:
10.1021/ja00367a041
PDF
Molybdenum-95 and proton ENDOR spectroscopy of the nitrogenase molybdenum-iron protein
Brian M. Hoffman, James E. Roberts, and W. H. Orme-Johnson
pp 860 - 862; DOI:
10.1021/ja00367a042
PDF
Carbon-13-carbon-13 coupling constants in bicyclic hydrocarbons
Ernest W. Della and Paul E. Pigou
pp 862 - 863; DOI:
10.1021/ja00367a043
PDF
Phospholipids chiral at phosphorus. 1. Stereochemistry of transphosphatidylation catalyzed by phospholipase D
Karol Bruzik and Ming Daw Tsai
pp 863 - 865; DOI:
10.1021/ja00367a044
PDF
Synthesis, properties, and molecular structure of a trivalent organouranium diphosphine hydride
Michael R. Duttera, Paul J. Fagan, Tobin J. Marks, and Victor W. Day
pp 865 - 867; DOI:
10.1021/ja00367a045
PDF
Total synthesis of (.+-.)-triptonide and (.+-.)-triptolide
Lee C. Garver and Eugene E. Van Tamelen
pp 867 - 869; DOI:
10.1021/ja00367a046
PDF
Metalloprotein electron-transfer mechanisms. Quenching of electronically excited tris(2,2'-bipyridine)ruthenium(II) by reduced blue copper proteins
Ann M. English, Patricia J. DeLaive, Harry B. Gray, and Vanessa R. Lum
pp 870 - 871; DOI:
10.1021/ja00367a047
PDF
Studies of enzyme stereochemistry. Elucidation of the stereochemistry of S-adenosylmethionine formation by yeast methionine adenosyltransferase
Ronald J. Parry and Akwasi Minta
pp 871 - 872; DOI:
10.1021/ja00367a048
PDF
A novel and efficient entry to (.+-.)-quadrone
Steven D. Burke, Charles William Murtiashaw, Jeffrey O. Saunders, and Meera S. Dike
pp 872 - 874; DOI:
10.1021/ja00367a049
PDF
Microsomal reduction of the carcinogen chromate produces chromium(V)
K. Wetterhahn Jennette
pp 874 - 875; DOI:
10.1021/ja00367a050
PDF
Intermediates in the reaction of catechol 1,2-dioxygenase with pyrogallol and oxygen
Lawrence Que and Ruth Mayer
pp 875 - 877; DOI:
10.1021/ja00367a051
PDF
Enamidines. Versatile vehicles for homologation of carbonyl compounds
A. I. Meyers and G. Erik Jagdmann
pp 877 - 879; DOI:
10.1021/ja00367a052
PDF
Enantioselective synthesis of binaphthyls via nucleophilic aromatic substitution on chiral oxazolines
A. I. Meyers and Kathryn A. Lutomski
pp 879 - 881; DOI:
10.1021/ja00367a053
PDF
Chiral leaving groups induce asymmetry in syntheses of binaphthyls in nucleophilic aromatic substitution reactions
Janet M. Wilson and Donald J. Cram
pp 881 - 884; DOI:
10.1021/ja00367a054
PDF
A new, general route to .eta.5-vinylcyclopentadienyl organometallic monomers
David W. Macomber, William P. Hart, Marvin D. Rausch, Ralph D. Priester, and Charles U. Pittman
pp 884 - 886; DOI:
10.1021/ja00367a055
PDF
Ion pair effects in an intercalation process. An approach to the bicyclo[5.3.1]undecyl system of taxane
Barry M. Trost and Henk Hiemstra
pp 886 - 887; DOI:
10.1021/ja00367a056
PDF
Bond energies in two-ligand gas-phase metal-ion complexes exhibit trans influence
Manfred M. Kappes, Roger W. Jones, and Ralph H. Staley
pp 888 - 889; DOI:
10.1021/ja00367a057
PDF
Reactivity of .mu.-alkylidene complexes: bridge-to-terminal alkylidene ligand conversion in a dimolybdenum complex
Louis Messerle and M. David Curtis
pp 889 - 891; DOI:
10.1021/ja00367a058
PDF
A formal [1,3]-sigmatropic rearrangement of an anionic oxy-Cope system. A consecutive mechanism
Tsutomu Miyashi, Atsuo Hazato, and Toshio Mukai
pp 891 - 893; DOI:
10.1021/ja00367a059
PDF
Enzymic reduction of an epoxide to an alcohol
Sharon R. Steckbeck, James A. Nelson, and Thomas A. Spencer
pp 893 - 895; DOI:
10.1021/ja00367a060
PDF
The pKa of acetone: a kinetic method for determining the pKas of ketones in aqueous solution
J. Peter Guthrie, John Cossar, and Alex Klym
pp 895 - 896; DOI:
10.1021/ja00367a061
PDF
cis-Diammineplatinum .alpha.-pyrrolidone tan, a structural analog of platinum blues
Kazuko Matsumoto and Keiichiro Fuwa
pp 897 - 898; DOI:
10.1021/ja00367a062
PDF
Photochemistry of surface-confined mononuclear and trinuclear ruthenium carbonyl complexes. Direct evidence for the ability to isolate photogenerated intermediates from each other on high surface area silica
David K. Liu and Mark S. Wrighton
pp 898 - 901; DOI:
10.1021/ja00367a063
PDF
Gas-phase reactions of certain nucleophiles with alkyl trifluoroacetates. A new probe to distinguish between SN2 and E2 mechanisms for alkyl derivatives
Richard N. McDonald and A. Kasem Chowdhury
pp 901 - 902; DOI:
10.1021/ja00367a064
PDF
A periodonium trifluoromethanesulfonate. An isolable 10-I-4 organoiodine species
D. B. Dess and J. C. Martin
pp 902 - 903; DOI:
10.1021/ja00367a065
PDF
Involvement of the azide radical in the quenching of singlet oxygen by azide anion in water
John R. Harbour and Sandra L. Issler
pp 903 - 905; DOI:
10.1021/ja00367a066
PDF
Antineoplastic agents. 3. Structure of the cyclic peptide dolastatin 3 from Dolabella auricularia
George R. Pettit, Yoshiaki Kamano, Peter Brown, Devens Gust, Masuo Inoue, and Cherry L. Herald
pp 905 - 907; DOI:
10.1021/ja00367a067
PDF
Carbon-13 NMR spectra of carbonium ions in the solid state: The 2-norbornyl cation
Costantino S. Yannoni, Volker Macho, and Philip C. Myhre
pp 907 - 909; DOI:
10.1021/ja00367a068
PDF
Stable vinyl cations. Direct spectroscopic observation of vinyl-substituted vinyl cations
Hans Ullrich Siehl and Herbert Mayr
pp 909 - 910; DOI:
10.1021/ja00367a069
PDF
Preparation, structural characterization, and reactivity of bis(triethylphosphine)carbonylrhodiumtetracarbonylcobalt ((PEt3)2(CO)Rh-Co(CO)4). A quantitative study of the reversible heterolytic cleavage of the polar rhodium-cobalt bond
David A. Roberts, William C. Mercer, Susan M. Zahurak, Gregory L. Geoffroy, C. W. De Brosse, Marion E. Cass, and Cortlandt G. Pierpont
pp 910 - 913; DOI:
10.1021/ja00367a070
PDF
Biosynthetic source of oxygens in griseofulvin. Spin-echo resolution of oxygen-18 isotope shifts in carbon-13 NMR spectroscopy
Martin P. Lane, Thomas T. Nakashima, and John C. Vederas
pp 913 - 915; DOI:
10.1021/ja00367a071
PDF
A fluxional .eta.1-cycloheptatrienyl derivative of ruthenium exhibiting both 1,2 and 1,4 metal migrations
D. Michael Heinekey and William A. G. Graham
pp 915 - 917; DOI:
10.1021/ja00367a072
PDF
Deuteron NMR study of molecular order and motion in a liquid crystalline polymer
H. Geib, B. Hisgen, U. Pschorn, H. Ringsdorf, and H. W. Spiess
pp 917 - 919; DOI:
10.1021/ja00367a073
PDF
High-resolution NMR spectroscopy of quadrupolar nuclei in solids: sodium salts
Eric Oldfield, Suzanne Schramm, Michael D. Meadows, Karen Ann Smith, Robert A. Kinsey, and Jerome Ackerman
pp 919 - 920; DOI:
10.1021/ja00367a074
PDF
Pyrazolyl-bridged iridium dimers. 1. Accommodation of both weak and strong metal-metal interactions by a bridging pyrazolyl framework in dissymmetric dimeric structures
Kathy A. Beveridge, Gordon W. Bushnell, Keith R. Dixon, Donald T. Eadie, Stephen R. Stobart, Jerry L. Atwood, and Michael J. Zaworotko
pp 920 - 922; DOI:
10.1021/ja00367a075
PDF
Pyrazolyl-bridged iridium dimers. 2. Contrasting modes of two-center oxidative addition to a bimetallic system and reductive access to the starting complex: three key diiridium structures representing short nonbonding and long and short bonding metal-metal interactions
A. W. Coleman, Donald T. Eadie, Stephen R. Stobart, Michael J. Zaworotko, and Jerry L. Atwood
pp 922 - 923; DOI:
10.1021/ja00367a076
PDF
Book Reviews

pp 924 - 924; DOI:
10.1021/ja00367a600
PDF

Issue 4


Quantum chemical and statistical thermodynamic investigations of anesthetic activity. 2. The interaction between chloroform, fluoroform, and an NH...O:C hydrogen bond
Pavel Hobza, Fred Mulder, and Camille Sandorfy
pp 925 - 928; DOI:
10.1021/ja00368a001
PDF
Models for DNA backbone motions: an interpretation of NMR relaxation experiments
Joe W. Keepers and Thomas L. James
pp 929 - 939; DOI:
10.1021/ja00368a002
PDF
Molecular structure and its change: hydrocarbons
Richard F. W. Bader, Ting Hua Tang, Yoram Tal, and Friedrich W. Biegler-Koenig
pp 940 - 945; DOI:
10.1021/ja00368a003
PDF
Properties of atoms and bonds in hydrocarbon molecules
Richard F. W. Bader, Ting Hua Tang, Yoram Tal, and Friedrich W. Biegler-Koenig
pp 946 - 952; DOI:
10.1021/ja00368a004
PDF
Theoretical study of the reaction phosphorane .fwdarw. phosphine + hydrogen
Werner Kutzelnigg and Jan Wasilewski
pp 953 - 960; DOI:
10.1021/ja00368a005
PDF
Concerted dihydrogen exchange between ethane and ethylene. SCF and FORS calculations of the barrier
David F. Feller, Michael W. Schmidt, and Klaus Ruedenberg
pp 960 - 967; DOI:
10.1021/ja00368a006
PDF
Potential surface for the methylenecyclopropane rearrangement
David Feller, Kiyoshi Tanaka, Ernest R. Davidson, and Weston Thatcher Borden
pp 967 - 972; DOI:
10.1021/ja00368a007
PDF
A new method for sequencing fully protected oligonucleotides using californium-252 plasma desorption mass spectrometry. 1. Negative ions of dinucleoside monophosphates
Catherine J. McNeal, Kelvin K. Ogilvie, Nicole Y. Theriault, and Mona J. Nemer
pp 972 - 975; DOI:
10.1021/ja00368a008
PDF
A new method for sequencing fully protected oligonucleotides using californium-252 plasma desorption mass spectrometry. 2. Negative ions of subunits in the stepwise synthesis of a heptaribonucleotide
Catherine J. McNeal, Kelvin K. Ogilvie, Nicole Y. Theriault, and Mona J. Nemer
pp 976 - 980; DOI:
10.1021/ja00368a009
PDF
A new method for the analysis of fully protected oligonucleotides by californium-252 plasma desorption mass spectrometry. 3. Positive ions
Catherine J. McNeal, Kelvin K. Ogilvie, Nicole Y. Theriault, and Mona J. Nemer
pp 981 - 984; DOI:
10.1021/ja00368a010
PDF
Electronic spectroscopy of diphosphine- and diarsine-bridged rhodium(I) dimers
W. A. Fordyce and G. A. Crosby
pp 985 - 988; DOI:
10.1021/ja00368a011
PDF
Synthesis, microwave spectrum, electric dipole moment, molecular structure, and anomeric effect in fluoroethylene ozonide
Kurt W. Hillig, R. P. Lattimer, and Robert L. Kuczkowski
pp 988 - 993; DOI:
10.1021/ja00368a012
PDF
Synthesis, x-ray analysis, and chemical properties of binuclear complexes with trans bis(palladium(II)-carbon) .sigma. bonds and bridging ligands
George R. Newkome, Dalip K. Kohli, and Frank R. Fronczek
pp 994 - 998; DOI:
10.1021/ja00368a013
PDF
Copper(I) catalysis of olefin photoreactions. 9. Photobicyclization of .alpha.-, .beta.-, and .gamma.-alkenylallyl alcohols
Robert G. Salomon, Daniel J. Coughlin, Subrata Ghosh, and Michael G. Zagorski
pp 998 - 1007; DOI:
10.1021/ja00368a014
PDF
Total synthesis refutes the postulated structure of leucogenenol
Robert G. Salomon, Mary F. Salomon, Michael G. Zagorski, James M. Reuter, and Daniel J. Coughlin
pp 1008 - 1013; DOI:
10.1021/ja00368a015
PDF
Low-temperature reactions of metal atoms with methyl bromide
Yasutaka Tanaka, Stephen C. Davis, and Kenneth J. Klabunde
pp 1013 - 1016; DOI:
10.1021/ja00368a016
PDF
Mechanism of the cyanide-induced formation of methyl acetate from [(methoxycarbonyl)methyl]cobalamin
William W. Reenstra, Robert H. Abeles, and William P. Jencks
pp 1016 - 1024; DOI:
10.1021/ja00368a017
PDF
Fluoride-mediated reactions of enol silyl ethers. Regiospecific monoalkylation of ketones
Isao Kuwajima, Eiichi Nakamura, and Makoto Shimizu
pp 1025 - 1030; DOI:
10.1021/ja00368a018
PDF
Stable carbocations. 238. Two- and threefold degenerate rearrangements in di- and trimethylcyclopropylcarbinyl cations
George A. Olah, G. K. Surya Prakash, and Tadashi Nakajima
pp 1031 - 1033; DOI:
10.1021/ja00368a019
PDF
Stereochemical control in the intramolecular Diels-Alder reaction. 2. Structural and electronic effects on reactivity and selectivity
Robert K. Boeckman and Soo Sung Ko
pp 1033 - 1041; DOI:
10.1021/ja00368a020
PDF
Chemiluminescence of organic peroxides. Thermal generation of an o-xylylene peroxide
Jimmie P. Smith, Alan K. Schrock, and Gary B. Schuster
pp 1041 - 1047; DOI:
10.1021/ja00368a021
PDF
Effects of substituents and generation methods for insertion-addition selectivities of arylcarbene in alcohol-olefin binary mixtures. Intervention of reaction of diazo compounds masquerading as carbenes
Hideo Tomioka, Shinji Suzuki, and Yasuji Izawa
pp 1047 - 1050; DOI:
10.1021/ja00368a022
PDF
Synthesis and characterization of an oligonucleotide containing a carcinogen-modified base: O6-methylguanine
Kerry W. Fowler, George Buechi, and John M. Essigmann
pp 1050 - 1054; DOI:
10.1021/ja00368a023
PDF
Total synthesis of lycopodium alkaloids: (.+-.)-lycopodine, (.+-.)-lycodine, and (.+-.)-lycodoline
Clayton H. Heathcock, Edward F. Kleinman, and Edward S. Binkley
pp 1054 - 1068; DOI:
10.1021/ja00368a024
PDF
Rhodopsin reconstitution in vesicles formed from simple, fully synthetic amphiphiles
Ernst J. R. Sudhoelter, Willem J. De Grip, and Jan B. F. N. Engberts
pp 1069 - 1072; DOI:
10.1021/ja00368a025
PDF
Pyrazolopyrimidine nucleosides. 13. Synthesis of the novel C-nucleoside 5-amino-3-(.beta.-D-ribofuranosyl)pyrazolo[4,3-d]pyrimidin-7-one, a guanosine analog related to the nucleoside antibiotic formycin B
Arthur F. Lewis and Leroy B. Townsend
pp 1073 - 1077; DOI:
10.1021/ja00368a026
PDF
A unified view of carbon bound hydrogen exchange of H(2) in imidazoles and H(8) in purine nucleosides and their metal ion complexes
Bela Noszal, Verena Scheller-Krattiger, and R. Bruce Martin
pp 1078 - 1081; DOI:
10.1021/ja00368a027
PDF
2-Amino-8-methyladenosine 5'-monophosphate dihydrate. A nucleotide with syn C4'-exo conformation and "triple-stranded" packing
J. V. Silverton, W. Limn, and H. T. Miles
pp 1081 - 1087; DOI:
10.1021/ja00368a028
PDF
Kinetics of model threonine aldolase reactions
Joseph A. Marcello and Arthur E. Martell
pp 1087 - 1093; DOI:
10.1021/ja00368a029
PDF
Resolution of chiral olefinic hydrocarbons and sulfoxides by high-performance liquid chromatography via diastereomeric platinum complexes
M. Goldman, Z. Kustanovich, S. Weinstein, A. Tishbee, and E. Gil-Av
pp 1093 - 1095; DOI:
10.1021/ja00368a030
PDF
A new role for hydrogen-bond acceptors in influencing packing patterns of carboxylic acids and amides
Margaret C. Etter
pp 1095 - 1096; DOI:
10.1021/ja00368a031
PDF
Retention of configuration during ligand-substitution reactions of cyclopentadienylrhodium complexes containing an acyl ligand
Susan Quinn, Alan Shaver, and Victor W. Day
pp 1096 - 1099; DOI:
10.1021/ja00368a032
PDF
Long-range proton-carbon-13 NMR spin coupling constants
Ad Bax and Ray Freeman
pp 1099 - 1100; DOI:
10.1021/ja00368a033
PDF
Bridging the gap between the gas phase and solution: transition in the kinetics of acid-base reactions
Diethard K. Bohme, Asit B. Rakshit, and Gervase I. Mackay
pp 1100 - 1101; DOI:
10.1021/ja00368a034
PDF
Stereo- and regiocontrolled synthesis of methyl N-acetyl-.alpha.-D-sibirosaminide
Michael Georges, Donald MacKay, and Bert Fraser-Reid
pp 1101 - 1103; DOI:
10.1021/ja00368a035
PDF
Photooxidation of water by p-benzoquinone
S. M. Beck and L. E. Brus
pp 1103 - 1104; DOI:
10.1021/ja00368a036
PDF
Generation of oxygen O2(1.DELTA.g) by direct absorption of radiation by ground-state oxygen
Walter C. Eisenberg, Kevin Taylor, James Veltman, and Robert W. Murray
pp 1104 - 1105; DOI:
10.1021/ja00368a037
PDF
Stereochemical control by an allylic substitutent of an acyclic dienophile in the Diels-Alder reaction
Richard W. Franck, Thomas V. John, Kazimierz Olejniczak, and John F. Blount
pp 1106 - 1107; DOI:
10.1021/ja00368a038
PDF
Triplet exciplex formation in the external heavy-atom effect
Maria C. Tamargo and Dwaine O. Cowan
pp 1107 - 1109; DOI:
10.1021/ja00368a039
PDF
Stereocontrolled synthesis of D-pentitols, 2-amino-2-deoxy-D-pentitols and 2-deoxy-D-pentitols from D-glyceraldehyde acetonide
Norio Minami, Soo Sung Ko, and Yoshito Kishi
pp 1109 - 1111; DOI:
10.1021/ja00368a040
PDF
Preparation and characterization of HFe4(BH2)(CO)12. A hydrogenated iron boride cluster
Kwai Sam Wong, W. Robert Scheidt, and Thomas P. Fehlner
pp 1111 - 1113; DOI:
10.1021/ja00368a041
PDF
Total synthesis of (.+-.)-pseudomonic acids A and C
Barry B. Snider and Gary B. Phillips
pp 1113 - 1114; DOI:
10.1021/ja00368a042
PDF
Stereoselective synthesis of calonectrin
George A. Kraus, Bruce Roth, Kevin Frazier, and Masayuki Shimagaki
pp 1114 - 1116; DOI:
10.1021/ja00368a043
PDF
Total synthesis of racemic verrucarol
R. H. Schlessinger and R. A. Nugent
pp 1116 - 1118; DOI:
10.1021/ja00368a044
PDF
Total synthesis of (.+-.)-limaspermine derivatives using organoiron chemistry
Anthony J. Pearson and David C. Rees
pp 1118 - 1119; DOI:
10.1021/ja00368a045
PDF
Silyl ketone chemistry. Synthesis and reactions of olefinic and acetylenic silyl ketones
Hans J. Reich and Martha J. Kelly
pp 1119 - 1120; DOI:
10.1021/ja00368a046
PDF
Pentadienyl compounds of vanadium, chromium, and manganese
David R. Wilson, Ju Zheng Liu, and Richard D. Ernst
pp 1120 - 1122; DOI:
10.1021/ja00368a047
PDF
Direct observation of metal-centered radicals in an oxidative-addition reaction
Gregory M. Williams and Jeffrey Schwartz
pp 1122 - 1124; DOI:
10.1021/ja00368a048
PDF
A silicon-mediated homo-Claisen rearrangement
Stephen R. Wilson and Martyn F. Price
pp 1124 - 1126; DOI:
10.1021/ja00368a049
PDF
Single-collision chemiluminescent reactions of ozone with hydrogen sulfide and methyl mercaptan
Robert J. Glinski, John A. Sedarski, and David A. Dixon
pp 1126 - 1128; DOI:
10.1021/ja00368a050
PDF
Elimination-addition mechanisms of sulfonyl group transfer: evidence for a sulfoquinone intermediate in the hydrolysis of 2,4-dinitrophenyl 3,5-dimethyl-4-hydroxybenzenesulfonate
Sergio Thea, Giuseppe Guanti, Andrew Hopkins, and Andrew Williams
pp 1128 - 1129; DOI:
10.1021/ja00368a051
PDF
Why do rate-equilibrium relationships break down?
Addy Pross and Sason S. Shaik
pp 1129 - 1130; DOI:
10.1021/ja00368a052
PDF
Phase-dependent stereochemistry and chemical activation in the thermal decomposition of 2,3-diazabicyclo[2.1.1]hexene
Moon Ho Chang and Dennis A. Dougherty
pp 1131 - 1132; DOI:
10.1021/ja00368a053
PDF
Total synthesis of (-)-sarracenin by photoannelation
S. W. Baldwin and M. T. Crimmins
pp 1132 - 1134; DOI:
10.1021/ja00368a054
PDF
Synthesis and interconversions of dinuclear iron complexes with .mu.-methyl, .mu.-methylene, and .mu.-methylidyne ligands
Charles P. Casey, Paul J. Fagan, and William H. Miles
pp 1134 - 1136; DOI:
10.1021/ja00368a055
PDF
Thermodynamics of acid-base reactions in water. A comment on the Eigen mechanism
Michael Jesse Blandamer, Ross Elmore Robertson, and John Marshall William Scott
pp 1136 - 1138; DOI:
10.1021/ja00368a056
PDF
Preparation and properties of sterically unhindered cis and trans dihydrides of platinum(II)
Ralph S. Paonessa and William C. Trogler
pp 1138 - 1140; DOI:
10.1021/ja00368a057
PDF
Indole-2,3-quinodimethan route to Aspidosperma alkaloids: synthesis of dl-aspidospermidine
Timothy Gallagher, Philip Magnus, and John Huffman
pp 1140 - 1141; DOI:
10.1021/ja00368a058
PDF
Highly reduced organometallics. 6. Synthesis and chemistry of tricarbonylphosphineferrates(2-), Fe(CO)3PR32-
Yu Sen Chen and John E. Ellis
pp 1141 - 1143; DOI:
10.1021/ja00368a059
PDF
Geometrics of the radical anions of ethylene, fluoroethylene, 1,1-difluoroethylene, and tetrafluoroethylene
Michael N. Paddon-Row, Nelson G. Rondan, K. N. Houk, and K. D. Jordan
pp 1143 - 1145; DOI:
10.1021/ja00368a060
PDF
Chirality due to oxygen-18 substitution. Synthesis and chiroptical properties of (1S)-2,4-adamantanedione-4-18O
E. W. Meijer and Hans Wynberg
pp 1145 - 1146; DOI:
10.1021/ja00368a061
PDF
Aluminophosphate molecular sieves: a new class of microporous crystalline inorganic solids
Stephen T. Wilson, Brent M. Lok, Celeste A. Messina, Thomas R. Cannan, and Edith M. Flanigen
pp 1146 - 1147; DOI:
10.1021/ja00368a062
PDF
An unusual ground-state di-.pi.-methane rearrangement in the thermal isomerization of homoazulene
Lawrence T. Scott and Ihsan Erden
pp 1147 - 1149; DOI:
10.1021/ja00368a063
PDF
Silylene to silene thermal rearrangement. Generation and rearrangement of cyclopropylsilylene and vinylsilylene
Thomas J. Barton, Gary T. Burns, William F. Goure, and William D. Wulff
pp 1149 - 1150; DOI:
10.1021/ja00368a064
PDF
Cyclotrisilane (R2Si)3 and disilene (R2Si:SiR2) system: synthesis and characterization
Satoru Masamune, Yuji Hanzawa, Shu Murakami, Thomas Bally, and John F. Blount
pp 1150 - 1153; DOI:
10.1021/ja00368a065
PDF
Total synthesis of racemic chorismic acid
Donald A. McGowan and Glenn A. Berchtold
pp 1153 - 1154; DOI:
10.1021/ja00368a066
PDF
Hexamethylenetetratellurafulvalene
F. Wudl and E. Aharon-Shalom
pp 1154 - 1156; DOI:
10.1021/ja00368a067
PDF
Total Synthesis of (+-)Daunomucinone: Regiospecific Preparations of (+-) -7,9-Dideoxydaunomycinone and 6,11-Dihydroxy-4-methoxy-7,8,9,10-tetrahydronaphthacene-5,9,12-trione - Correction
Frank M. Hauser, and Subbarao Prasanna
pp 1156 - 1156; DOI:
10.1021/ja00368a600
PDF
Carbon-14 Kinetic Isotope Effects in the Menschutkin-Type Reaction of Benzyl Benzenesulfonates with N,N-Dimethylanilines. Variation of the Effects with Substituents - Correction
Hiroshi Yamataka, and Takashi Ando
pp 1156 - 1156; DOI:
10.1021/ja00368a601
PDF
Catalysis of Ester Aminolysis by Divalent Metal Ions - Correction
R.M. Propst, and L.S. Trzupek
pp 1156 - 1156; DOI:
10.1021/ja00368a602
PDF
Facile Reduction of Carbon Dioxide by Anionic Group 6B Metal Hydrides. Chemistry Relevant to Catalysis of the Water-Gas Shift Reaction - Correction
Donald J. Darnesbourg, Andrzej Rokicki, and Marcetta Y. Darensbourg
pp 1156 - 1156; DOI:
10.1021/ja00368a603
PDF
Optically Detected Magnetic Resonance Evidence for Carcinogen-Nucleic Acid Interaction in the Tetrahydro-9,10-epoxybenzo[e]pyrene-DNA Adduct - Correction
Steven M. Lefkowitz, and Henry C. Brenner
pp 1156 - 1156; DOI:
10.1021/ja00368a604
PDF
Transition-Metal Complexes of Vitamin B6 Related Compounds.3. X-ray, Mossbauer, and Magnetic Properties of a Binuclear Iron (III). Complex Containing an Unusual Pyridoxal Derivative - Correction
Gary J. Long, James T. Wrobleski, Raju V. Thundathil, Don M. Sparlin, and E.O. Schlemper
pp 1156 - 1156; DOI:
10.1021/ja00368a605
PDF
Structure of Palytoxin - Correction
Richard E. Moore, and Giovanni Bartolini
pp 1156 - 1156; DOI:
10.1021/ja00368a606
PDF
Ortho Ester Hydrolysis: Direct Evidence for a Three-Stage Reaction Mechanism - Correction
M. Ahmed, R.G. Bergstrom, M.J. Cashen, Y. Chiang, A.J. Kresge, R.A. McClelland, and M.F. Powell
pp 1156 - 1157; DOI:
10.1021/ja00368a607
PDF
Additions and Corrections - Thermolysis of 2-Methoxy-2,5,5-trimethyl-Δ3-1,3,4-oxadiazoline. Carbenes from Thermal Fragmentation of a Carbonyl Ylide Intermediate
Michel Bekhazi, and John Warkentin
pp 1157 - 1157; DOI:
10.1021/ja00368a608
PDF
Additions and Corrections - Silicon-Directed Baeyer-Villager Reactions. Stereospecific Synthesis of Olefinic Acids and Esters.
Paul F. Hudrlik, Anne M. Hudrlik, Golpalpur Nagendrappa, Tilahun Yimeni, Edward T. Zellers, and Evelyn Chin
pp 1157 - 1157; DOI:
10.1021/ja00368a609
PDF
Book Reviews

pp 1157 - 1160; DOI:
10.1021/ja00368a610
PDF

Issue 5


An ab initio molecular orbital study of the rearrangement of .alpha.-disulfoxide to thiosulfonate
Fillmore Freeman, Christos N. Angeletakis, William J. Pietro, and Warren J. Hehre
pp 1161 - 1165; DOI:
10.1021/ja00369a001
PDF
Aluminum atom-ethylene and aluminum atom-acetylene complexes: matrix isolation electron spin resonance study
Paul H. Kasai
pp 1165 - 1172; DOI:
10.1021/ja00369a002
PDF
Deuterium nuclear quadrupole resonance spectra of nonlinear hydrogen bonds
Theodore L. Brown, Leslie G. Butler, David Y. Curtin, Yukio Hiyama, Iain C. Paul, and Roxy B. Wilson
pp 1172 - 1177; DOI:
10.1021/ja00369a003
PDF
Pyranose benzoates: an additivity relation in the amplitudes of exciton-split CD curves
Hung Wen Liu and Koji Nakanishi
pp 1178 - 1185; DOI:
10.1021/ja00369a004
PDF
Oxidation of mandelic acid by Fenton's reagent
Cheves Walling and Kalyani Amarnath
pp 1185 - 1189; DOI:
10.1021/ja00369a005
PDF
Stereospecific alkyl group effects on amine lone-pair ionization potentials: photoelectron spectra of alkylpiperidines
Melvin D. Rozeboom and K. N. Houk
pp 1189 - 1191; DOI:
10.1021/ja00369a006
PDF
Acid-base and tautomeric equilibriums in the solid state: nitrogen-15 NMR spectroscopy of histidine and imidazole
M. Munowitz, W. W. Bachovchin, J. Herzfeld, C. M. Dobson, and R. G. Griffin
pp 1192 - 1196; DOI:
10.1021/ja00369a007
PDF
Origins of inhomogeneous broadening in the vibronic spectra of visual chromophores and visual pigments
Robert R. Birge, David F. Bocian, and Lynn M. Hubbard
pp 1196 - 1207; DOI:
10.1021/ja00369a008
PDF
Photodissociation study of C6H6O+.cntdot. ions in an ion cyclotron resonance spectrometer
P. N. T. Van Velzen, W. J. Van der Hart, J. Van der Greef, N. M. M. Nibbering, and M. L. Gross
pp 1208 - 1212; DOI:
10.1021/ja00369a009
PDF
Secondary ion mass spectrometry of metal halides. 2. Evidence for structure in alkali iodide clusters
T. M. Barlak, J. R. Wyatt, R. J. Colton, J. J. DeCorpo, and J. E. Campana
pp 1212 - 1215; DOI:
10.1021/ja00369a010
PDF
Ab initio calculations of the relative energies of triplet 2,4-dimethylenecyclobutane-1,3-diyl and singlet 2,4-dimethylenebicyclo[1.1.0]butane
David Feller, Ernest R. Davidson, and Weston Thatcher Borden
pp 1216 - 1218; DOI:
10.1021/ja00369a011
PDF
The state of lithium tetraphenylborate, lithium picrate, and sodium picrate dissolved in 1,2-dichloroethane containing one of several phase-transfer catalysts
W. R. Gilkerson and M. D. Jackson
pp 1218 - 1223; DOI:
10.1021/ja00369a012
PDF
Direct reduction of acetylene at molybdenum modified polymeric sulfur nitride, (SN)x, electrodes
Judith F. Rubinson, Thomas D. Behymer, and Harry B. Mark
pp 1224 - 1229; DOI:
10.1021/ja00369a013
PDF
Reactions of aluminum(+) and magnesium(+) ions with alcohols and organic halides in the gas phase
Jack S. Uppal and Ralph H. Staley
pp 1229 - 1234; DOI:
10.1021/ja00369a014
PDF
Relative binding energies of organic molecules to aluminum(+) ion in the gas phase
Jack S. Uppal and Ralph H. Staley
pp 1235 - 1238; DOI:
10.1021/ja00369a015
PDF
Relative binding energies of organic molecules to manganese(+) ion in the gas phase
Jack S. Uppal and Ralph H. Staley
pp 1238 - 1243; DOI:
10.1021/ja00369a016
PDF
Oxidation of substituted alkyl radicals by hexachloroiridate(2-), hexacyanoferrate(3-), and permanganate ions in aqueous solution. Electron transfer versus chlorine transfer from hexachloroiridate(2-) ion
S. Steenken and P. Neta
pp 1244 - 1248; DOI:
10.1021/ja00369a017
PDF
Homolysis and acidolysis reactions of (.alpha.-hydroxyalkyl)- and (.alpha.-alkoxyalkyl)chromium(III) complexes: kinetics, steric effects, and bond energies
Garry W. Kirker, Andreja Bakac, and James H. Espenson
pp 1249 - 1255; DOI:
10.1021/ja00369a018
PDF
Kinetic and thermodynamic acidity of hydrido transition-metal complexes. 1. Periodic trends in Group VI complexes and substituent effects in osmium complexes
Richard F. Jordan and Jack R. Norton
pp 1255 - 1263; DOI:
10.1021/ja00369a019
PDF
Higher coordinate cyanide and isocyanide complexes. 15. Reductive coupling of coordinated alkyl isocyanides in seven-coordinate molybdenum(II) and tungsten(II) complexes. Removal of the coupled ligand as an oxamide
Christen M. Giandomenico, Chiu T. Lam, and Stephen J. Lippard
pp 1263 - 1271; DOI:
10.1021/ja00369a020
PDF
N,N'-Bridged porphyrins. Novel synthesis, metal complexes, and conversion into N-monosubstituted porphyrins. Crystal structure of [N,N'-[(benzyloxy)methylene]tetraphenylporphyrin-N'',N''']dibromopalladium(II)
H. J. Callot, J. Fischer, and R. Weiss
pp 1272 - 1276; DOI:
10.1021/ja00369a021
PDF
The effects of solvent on axial ligation constants of a cobalt(II) porphyrin
D. Paul Rillema, C. M. Wicker, R. D. Morgan, L. F. Barringer, and L. A. Scism
pp 1276 - 1281; DOI:
10.1021/ja00369a022
PDF
Preparation and molecular and electronic structures of cyclo-1.lambda.5-phospha-3,5-dithia-2,4,6-triazenes and their norbornadiene adducts
N. Burford, T. Chivers, A. W. Cordes, W. G. Laidlaw, M. C. Noble, R. T. Oakley, and P. N. Swepston
pp 1282 - 1290; DOI:
10.1021/ja00369a023
PDF
Fe2(.mu.2-E2)(CO)6 (E = sulfur, selenium, and tellurium) as reagents for the preparation of mixed-metal chalcogenide clusters
Victor W. Day, David A. Lesch, and Thomas B. Rauchfuss
pp 1290 - 1295; DOI:
10.1021/ja00369a024
PDF
Proton-induced disproportionation of superoxide ion in aprotic media
Der Hang Chin, Glaico Chiericato, Edward J. Nanni, and Donald T. Sawyer
pp 1296 - 1299; DOI:
10.1021/ja00369a025
PDF
Ligand additivity: applications to the electrochemistry and photoelectron spectroscopy of d6 octahedral complexes
Bruce E. Bursten
pp 1299 - 1304; DOI:
10.1021/ja00369a026
PDF
Direct determination of rate constants of slow dynamic processes by two-dimensional "accordion" spectroscopy in nuclear magnetic resonance
Geoffrey Bodenhausen and R. R. Ernst
pp 1304 - 1309; DOI:
10.1021/ja00369a027
PDF
Regiocontrolled coupling of (.pi.-allylic)palladium complexes with organozirconium species
James S. Temple, Martin Riediker, and Jeffrey Schwartz
pp 1310 - 1315; DOI:
10.1021/ja00369a028
PDF
Transient protection: efficient one-flask syntheses of protected deoxynucleosides
G. S. Ti, B. L. Gaffney, and R. A. Jones
pp 1316 - 1319; DOI:
10.1021/ja00369a029
PDF
Oxidation-reduction mechanisms. Inner-sphere and outer-sphere electron transfer in the reduction of iron(III), ruthenium(III), and osmium(III) complexes by alkyl radicals
K. L. Rollick and J. K. Kochi
pp 1319 - 1330; DOI:
10.1021/ja00369a030
PDF
Generation of 2-(trimethylsiloxy)allyl cations and their reactions with 1,3-dienes. Change in mechanism of 3 + 4 .fwdarw. 7 cycloaddition with solvent
Nobujiro Shimizu, Masayuki Tanaka, and Yuho Tsuno
pp 1330 - 1340; DOI:
10.1021/ja00369a031
PDF
Thiamin catalysis. 2. Kinetics and mechanism of the generation of the yellow form of thiamin
Rudolf F. W. Hopmann, Gian P. Brugnoni, and Bruno Fol
pp 1341 - 1344; DOI:
10.1021/ja00369a032
PDF
Reactions of the monomeric metaphosphate anion generated from different sources
Fausto Ramirez, James F. Marecek, and Shrishailam S. Yemul
pp 1345 - 1349; DOI:
10.1021/ja00369a033
PDF
Stable carbocations. Part 236. A carbon-13 and silicon-29 NMR spectroscopic study of .alpha.- and .beta.-(trimethylsilyl)-substituted carbocations
George A. Olah, Arthur L. Berrier, Leslie D. Field, and G. K. Surya Prakash
pp 1349 - 1355; DOI:
10.1021/ja00369a034
PDF
Structures of the 1:1 complexes of 18-crown-6 with hydrazinium perchlorate, hydroxylammonium perchlorate, and methylammonium perchlorate
K. N. Trueblood, C. B. Knobler, D. S. Lawrence, and R. V. Stevens
pp 1355 - 1362; DOI:
10.1021/ja00369a035
PDF
Complete kinetic analysis of the thermal stereomutations of (+)-(1S,2S,3R)-r-1-cyano-t-2-methyl-1,2,t-3-trideuteriocyclopropane
John E. Baldwin and Charles G. Carter
pp 1362 - 1368; DOI:
10.1021/ja00369a036
PDF
Kinetic and structural studies on the intermediates formed in the reactions of 5'-adenosine monophosphate and 5'-guanosine monophosphate with cis-dichlorodiammineplatinum(II) using proton and platinum-195 magnetic resonance spectroscopy
G. M. Clore and A. M. Gronenborn
pp 1369 - 1375; DOI:
10.1021/ja00369a037
PDF
1,2,5-Thiadiazole 1-oxides. 3. An experimental and theoretical investigation of the inversion barrier
Joseph S. Amato, Sandor Karady, Robert A. Reamer, H. Bernhard Schlegel, James P. Springer, and Leonard M. Weinstock
pp 1375 - 1380; DOI:
10.1021/ja00369a038
PDF
A new thermal rearrangement in the 4-isoxazoline system. Some chemical and stereochemical properties of a benzodiazepine oxide-ethyl propiolate adduct
Jeremiah P. Freeman, David J. Duchamp, Constance G. Chidester, George Slomp, Jacob Szmuszkovicz, and M. Raban
pp 1380 - 1386; DOI:
10.1021/ja00369a039
PDF
Macro rings. 48. Transannular effects of acidity of heteroannularly disubstituted [2.2.] paracyclophane
Merrell G. Siegel, Charles L. Liotta, and Donald J. Cram
pp 1387 - 1391; DOI:
10.1021/ja00369a040
PDF
"Mercaptan-tail" porphyrins: synthetic analogs for the active site of cytochrome P-450
James P. Collman and Susan E. Groh
pp 1391 - 1403; DOI:
10.1021/ja00369a041
PDF
Biosynthesis of the pyrrolidine rings of cocaine and cuscohygrine from [5-14C]-ornithine via a symmetrical intermediate
Edward Leete
pp 1403 - 1408; DOI:
10.1021/ja00369a042
PDF
Role of the protein outside active site on the diffusion-controlled reaction of enzymes
Kuo Chen Chou and Guo Ping Zhou
pp 1409 - 1413; DOI:
10.1021/ja00369a043
PDF
Model studies of terpene biosynthesis. Intermolecular 1'-2 electrophilic condensation of 3-methyl-2-butenyl acetate
Chi Hsin R. King and C. Dale Poulter
pp 1413 - 1420; DOI:
10.1021/ja00369a044
PDF
Model studies of terpene biosynthesis. Stereospecific cyclization of N-methyl-(S)-4-([1'-2H]neryloxy)pyridinium methyl sulfate to .alpha.-terpineol
C. Dale Poulter and Chi Hsin R. King
pp 1420 - 1422; DOI:
10.1021/ja00369a045
PDF
Model studies of terpene biosynthesis. A stepwise mechanism for cyclization of nerol to .alpha.-terpineol
C. Dale Poulter and Chi Hsin R. King
pp 1422 - 1424; DOI:
10.1021/ja00369a046
PDF
Silylene rearrangements in the reactions of recoiling silicon atoms with trimethylsilane
Siu Hong Mo, J. Dewey Holten, Stanislaw Konieczny, Eric C. L. Ma, and Peter P. Gaspar
pp 1424 - 1426; DOI:
10.1021/ja00369a047
PDF
Coronation of ligating acetonitrile by 18-crown-6. X-ray crystal structure of {[trans-Ir(CO) (CH3CN)(PPh3)2]2+.18-crown-6}[PF6]2-.2CH2Cl2
Howard M. Colguhoun, J. Fraser Stoddart, and David J. Williams
pp 1426 - 1428; DOI:
10.1021/ja00369a048
PDF
A Diels-Alder route to pyridone and piperidone derivatives
Francy Sainte, Beatrice Serckx-Poncin, Anne Marie Hesbain-Frisque, and Leon Ghosez
pp 1428 - 1430; DOI:
10.1021/ja00369a049
PDF
New methods for alkaloid synthesis: .alpha.-acylamino radical cyclizations
David J. Hart and Yeun-Min Tsai
pp 1430 - 1432; DOI:
10.1021/ja00369a050
PDF
Design and synthesis of an amphoteric four-stage redox hydrocarbon bearing phenalenyl moieties. 1,2-Bis(phenalen-1-yliden)ethane
Kazuhiro Nakasuji, Keiji Yoshida, and Ichiro Murata
pp 1432 - 1433; DOI:
10.1021/ja00369a051
PDF
Ruthenium-catalyzed oxygenation of catechols to muconic acid anhydrides and 2H-pyran-2-ones. Intradiol and extradiol cleavage of carbon-carbon bond
Masakatsu Matsumoto and Keiko Kuroda
pp 1433 - 1434; DOI:
10.1021/ja00369a052
PDF
"Open-face" macrobicycles as tunable binucleating ligands. Design, synthesis and dicopper(II) complexes
Andrea E. Martin and John E. Bulkowski
pp 1434 - 1436; DOI:
10.1021/ja00369a053
PDF
Stereocontrolled total synthesis of Antibiotic A-23187 (calcimycin)
Gregory R. Martinez, Paul A. Grieco, Eric Williams, Kenichi Kanai, and C. V. Srinivasan
pp 1436 - 1438; DOI:
10.1021/ja00369a054
PDF
Nucleophilic displacements on phosphoric monoesters: stereochemical evidence
Stephen L. Buchwald and Jeremy R. Knowles
pp 1438 - 1440; DOI:
10.1021/ja00369a055
PDF
Theoretical study of the chromium-chromium quadruple bond
Paulo Correa de Mello, W. Daniel Edwards, and Michael C. Zerner
pp 1440 - 1442; DOI:
10.1021/ja00369a056
PDF
Biosynthesis of sulfur compounds. Investigations of the biosynthesis of asparagusic acid
Ronald J. Parry, Anita E. Mizusawa, and Margaritte Ricciardone
pp 1442 - 1443; DOI:
10.1021/ja00369a057
PDF
Reactivities of ruthenium cluster anions: implications for catalysis of the water-gas shift reaction
Jeffery C. Bricker, Colleen C. Nagel, and Sheldon G. Shore
pp 1444 - 1445; DOI:
10.1021/ja00369a058
PDF
Dienophilic thioaldehydes
E. Vedejs, T. H. Eberlein, and D. L. Varie
pp 1445 - 1447; DOI:
10.1021/ja00369a059
PDF
Ionization energies of p-quinodimethan and 2,5-dimethyl-p-quinodimethan
Michael J. S. Dewar
pp 1447 - 1449; DOI:
10.1021/ja00369a060
PDF
One and two electron reduction of oxygen by 1,5-dihydroflavins
Gert Eberlein and Thomas C. Bruice
pp 1449 - 1452; DOI:
10.1021/ja00369a061
PDF
Use of large magnetic fields to probe photoinduced electron-transfer reactions: an example from photosynthetic reaction centers
Steven G. Boxer, Christopher E. D. Chidsey, and Mark G. Roelofs
pp 1452 - 1454; DOI:
10.1021/ja00369a062
PDF
Photooxygenation via electron transfer. 1,1-Dimethylindene
Susan L. Mattes and Samir Farid
pp 1454 - 1456; DOI:
10.1021/ja00369a063
PDF

Issue 6


Structure and energetics of realistic carbynes: (carbohydroxy)carbyne (HOCOC.tplbond.)
Kwang S. Kim, S. P. So, and Henry F. Schaefer
pp 1457 - 1461; DOI:
10.1021/ja00370a001
PDF
Thermodynamics and kinetics of the gas-phase reactions H3O+(H2O)n-1 + water = H3O+(H2O)n
Y. K. Lau, S. Ikuta, and P. Kebarle
pp 1462 - 1469; DOI:
10.1021/ja00370a002
PDF
Energy storage and reaction pathways in the first step of the vision process
Arieh Warshel and Natalia Barboy
pp 1469 - 1476; DOI:
10.1021/ja00370a003
PDF
Molecular orbital constrained electron diffraction studies. 4. Conformational analysis of the methyl ester of glycine
V. J. Klimkowski, J. D. Ewbank, C. Van Alsenoy, J. N. Scarsdale, and Lothar Schaefer
pp 1476 - 1480; DOI:
10.1021/ja00370a004
PDF
Detailed solvation shell geometry of cupric ion in ethanol determined by electron-spin-echo modulation analysis
Tsuneki Ichikawa and Larry Kevan
pp 1481 - 1483; DOI:
10.1021/ja00370a005
PDF
Photodissociation of stilbene radical cation
Robert Gooden and John I. Brauman
pp 1483 - 1486; DOI:
10.1021/ja00370a006
PDF
The rotational spectrum, chlorine nuclear quadrupole coupling constants, and molecular geometry of a hydrogen-bonded dimer of cyclopropane and hydrogen chloride
A. C. Legon, P. D. Aldrich, and W. H. Flygare
pp 1486 - 1490; DOI:
10.1021/ja00370a007
PDF
Electronic structure of metallocene compounds. 3. Comparison of the results of multiple-scattering X.alpha. calculations with various electronic observables of cobaltocene
Jacques Weber, Annick Goursot, Edouard Penigault, John H. Ammeter, and J. Bachmann
pp 1491 - 1506; DOI:
10.1021/ja00370a008
PDF
Desorption ionization mass spectrometry: sample preparation for secondary ion mass spectrometry, laser desorption, and field desorption
K. L. Busch, S. E. Unger, A. Vincze, R. G. Cooks, and T. Keough
pp 1507 - 1511; DOI:
10.1021/ja00370a009
PDF
Picosecond events in magnetic resonance spectroscopy of the bacteriochlorophyll special pair cation
M. K. Bowman and J. R. Norris
pp 1512 - 1515; DOI:
10.1021/ja00370a010
PDF
Resonance Raman spectra and vibrational assignments of "red" and "black" forms of potassium bis(dithiooxalato)nickel(II)
Roman S. Czernuszewicz, Kazuo Nakamoto, and Dennis P. Strommen
pp 1515 - 1521; DOI:
10.1021/ja00370a011
PDF
Interactions of CpM'(CO)3- (M' = chromium, molybdenum, or tungsten) with cations: effects on CO exchange and RX addition reactions
Marcetta Y. Darensbourg, Pedro Jimenez, James R. Sackett, John M. Hanckel, and Robin L. Kump
pp 1521 - 1530; DOI:
10.1021/ja00370a012
PDF
Energy surfaces in the cyclopropane radical ion and the photoelectron spectrum of cyclopropane
J. R. Collins and G. A. Gallup
pp 1530 - 1533; DOI:
10.1021/ja00370a013
PDF
The stereochemistry and dynamics of natural products and biopolymers from proton relaxation spectroscopy: spin-label delineation of inner and outer protons of gramicidin S including hydrogen bonds
Neri Niccolai, Gianni Valensin, Claudio Rossi, and William A. Gibbons
pp 1534 - 1537; DOI:
10.1021/ja00370a014
PDF
Diazoalkane complexes of molybdenum and tungsten
Gregory L. Hillhouse and Barry L. Haymore
pp 1537 - 1548; DOI:
10.1021/ja00370a015
PDF
Covalently bound paramagnetic shift reagents. 1. A versatile lithium reagent derived from bis[(4-bromophenyl)tris(1-pyrazolyl)borato]cobalt(II)
David L. White and J. W. Faller
pp 1548 - 1552; DOI:
10.1021/ja00370a016
PDF
Hybrid organometallic/enzymic catalyst systems: regeneration of NADH using dihydrogen
Obsidiana Abril and George M. Whitesides
pp 1552 - 1554; DOI:
10.1021/ja00370a017
PDF
o-Benzosemiquinone and its metal chelates. Electron spin resonance investigation of radicals from the photolysis of catechol in the presence of complexing metal ions
Christopher C. Felix and Roger C. Sealy
pp 1555 - 1560; DOI:
10.1021/ja00370a018
PDF
Stereoselective cyanation of vinyl halides catalyzed by tetracyanocobaltate(I)
Takuzo Funabiki, Hiroaki Hosomi, Satohiro Yoshida, and Kimio Tarama
pp 1560 - 1568; DOI:
10.1021/ja00370a019
PDF
Models of the cytochromes b. 2. Effect of unsymmetrical phenyl substitution on pyrrole proton shifts of a series of low-spin (tetraphenylporphinato)iron(III) bis(N-methylimidazole) complexes
F. Ann Walker, Virginia L. Balke, and Gregory A. McDermott
pp 1569 - 1574; DOI:
10.1021/ja00370a020
PDF
Direct measurement of electron self-exchange rates of cobalt porphyrins. 1. Outer-sphere exchange
Robert D. Chapman and Everly B. Fleischer
pp 1575 - 1582; DOI:
10.1021/ja00370a021
PDF
Direct measurement of electron self-exchange rates of cobalt porphyrins. 2. Inner-sphere exchange
Robert D. Chapman and Everly B. Fleischer
pp 1582 - 1587; DOI:
10.1021/ja00370a022
PDF
Studies on vitamin B12 and related compounds. 53. Synthesis and reactions of organocobalamins relevant to the mechanism of the methylmalonyl-CoA-succinyl-CoA mutase enzyme
John H. Grate, Jay W. Grate, and Gerhard N. Schrauzer
pp 1588 - 1594; DOI:
10.1021/ja00370a023
PDF
Twisted carbon-carbon double bonds. Crystal and molecular structure of 4,5-di-tert-butyl-1,1,2,2-tetrafluoro-1,2-disilacyclohexa-3,5-diene
Tzong Hsiung Hseu, Yun Chi, and Chao Shiuan Liu
pp 1594 - 1598; DOI:
10.1021/ja00370a024
PDF
Why do all spirobenzylisoquinoline alkaloids incorporate a methylenedioxy substituent on ring D?
Gabor Blasko, S. Fazal Hussain, and Maurice Shamma
pp 1599 - 1602; DOI:
10.1021/ja00370a025
PDF
Synthesis, conformation, and complexation behavior of 2,9,18,25-tetraoxa-33,34,35,36-tetrakis(acyloxymethyl)[8.8](1,4)naphthalenophanes
Steven P. Adams and Howard W. Whitlock
pp 1602 - 1611; DOI:
10.1021/ja00370a026
PDF
Mechanisms of buffer catalysis in the iodine oxidation of N-acetylmethionine methyl ester
Paul R. Young and Li Shan Hsieh
pp 1612 - 1616; DOI:
10.1021/ja00370a027
PDF
On the rotation-inversion controversy on photoisomerization of azobenzenes. Experimental proof of inversion
Hermann Rau and Erik Lueddecke
pp 1616 - 1620; DOI:
10.1021/ja00370a028
PDF
10-Nor-9,11-secoprostaglandins. Synthesis, structure, and biology of endoperoxide analogs
Chiu Hong Lin, David L. Alexander, Constance G. Chidester, Robert R. Gorman, and Roy A. Johnson
pp 1621 - 1628; DOI:
10.1021/ja00370a029
PDF
Stable carbocations. Part 239. Preparation and carbon-13 and nitrogen-15 NMR spectroscopic study of cyanocarbenium ions. Substituent effects on the extent of mesomeric nitrenium ion character in cyanodiphenylmethyl cations. The search for related stable .alpha.-cyanocarbenium ions
George A. Olah, Massoud Arvanaghi, and G. K. Surya Prakash
pp 1628 - 1631; DOI:
10.1021/ja00370a030
PDF
Temperature dependence of the lanthanide-induced shifts, structure, and dynamics of adducts of quinuclidine and Ln(fod)3 chelates as studied by variable-temperature NMR shift and relaxation measurements
W. M. M. J. Bovee, J. H. Alberts, J. A. Peters, and J. Smidt
pp 1632 - 1636; DOI:
10.1021/ja00370a031
PDF
Reaction of (9-anthryl)arylmethyl chlorides with Grignard and lithium reagents
Masato Takagi, Masatomo Nojima, and Shigekazu Kusabayashi
pp 1636 - 1643; DOI:
10.1021/ja00370a032
PDF
Extended ElcB mechanism for ester hydrolysis: allylic substitution via carbanion in ester hydrolysis
Masashi Inoue and Thomas C. Bruice
pp 1644 - 1653; DOI:
10.1021/ja00370a033
PDF
Cupric ion catalyzed ester hydrolysis of O-acetyl-2-pyridinecarboxaldoxime. Nucleophilic attack by metal-bound water
Junghun Suh, Minsek Cheong, and Myunghyun Paik Suh
pp 1654 - 1657; DOI:
10.1021/ja00370a034
PDF
Vinyl epoxide hydrolysis reactions
Angela M. Ross, Terese M. Pohl, Kathryn Piazza, Michael Thomas, Bonnie Fox, and Dale L. Whalen
pp 1658 - 1665; DOI:
10.1021/ja00370a035
PDF
Reactive species produced by the 5-methylphenazinium methyl sulfate/reduced .beta.-nicotinamide adenine dinucleotide/oxygen system in the hydroxylation of benzoic acid
Helen W. Richter, Melanie A. Fetrow, Rachel E. Lewis, and Walter H. Waddell
pp 1666 - 1671; DOI:
10.1021/ja00370a036
PDF
Molecular recognition. Selective ammonium cryptates of synthetic receptor molecules possessing a tetrahedral recognition site
Ernest Graf, Jean Pierre Kintzinger, Jean Marie Lehn, and Jacques LeMoigne
pp 1672 - 1678; DOI:
10.1021/ja00370a037
PDF
Quenching and radical formation in the reaction of photoexcited benzophenone with thiols and thio ethers (sulfides). Nanosecond flash studies
Shai Inbar, Henry Linschitz, and Saul G. Cohen
pp 1679 - 1682; DOI:
10.1021/ja00370a038
PDF
The dissociative stereoisomerization of persulfuranes via 10-S-5 persulfonium salts. Geometrical isomers of octahedral 12-S-6 species
Ronald S. Michalak and J. C. Martin
pp 1683 - 1692; DOI:
10.1021/ja00370a039
PDF
On the solvolysis of 2-cyclohexenyl 3,5-dinitrobenzoate and p-nitrobenzoate in aqueous acetone. Introduction of acyl-oxygen cleavage by basic buffer systems
Steven S. Kantner, Kresimir Humski, and Harlan L. Goering
pp 1693 - 1697; DOI:
10.1021/ja00370a040
PDF
Barriers to decomposition of ground and excited state 1-pyrazolines
Paul S. Engel, Luis R. Soltero, Sharon A. Baughman, Christopher J. Nalepa, Paul A. Cahill, and Bruce R. Weisman
pp 1698 - 1700; DOI:
10.1021/ja00370a041
PDF
Evaluation of addition rates of thiyl radicals to vinyl monomers by flash photolysis. 5. Polar effects in addition reactions of benzenethiyl radicals to substituted styrenes and .alpha.-methylstyrenes determined by flash photolysis
Osamu Ito and Minoru Matsuda
pp 1701 - 1703; DOI:
10.1021/ja00370a042
PDF
Transient phenomena in the pulse radiolysis of retinyl polyenes. 2. Protonation kinetics
K. Bobrowski and P. K. Das
pp 1704 - 1709; DOI:
10.1021/ja00370a043
PDF
.alpha.-Hydride elimination: the first observable equilibriums between alkylidene complexes and alkylidyne hydride complexes
Melvyn Rowen Churchill, Harvey J. Wasserman, Howard W. Turner, and Richard R. Schrock
pp 1710 - 1716; DOI:
10.1021/ja00370a044
PDF
The pH dependence of metal ion binding to the native zinc site of bovine erythrocuprein (superoxide dismutase)
Michael W. Pantoliano, Joan S. Valentine, Robert J. Mammone, and Diane M. Scholler
pp 1717 - 1723; DOI:
10.1021/ja00370a045
PDF
Rates of cytidine amino mercuration by methylmercury(II) determined by proton NMR saturation recovery
Bruce McConnell
pp 1723 - 1727; DOI:
10.1021/ja00370a046
PDF
Linear stereocooligopeptides with alternating D and L residues. 3. Nature and relative stability of monomeric and dimeric species of the D,L-alternating octapeptide Boc-(L-Val-D-Val)4-OMe in cyclohexane or chloroform solution
Gian Paolo Lorenzi, Hans Jaeckle, Lera Tomasic, Vincenzo Rizzo, and Carlo Pedone
pp 1728 - 1733; DOI:
10.1021/ja00370a047
PDF
Correlation of the rate of thermal cis-trans isomerization of p-nitro-p'-(dialkylamino)azobenzenes with solvent Z value applied to study polarity in aqueous surfactant solutions
Kirk S. Schanze, T. Fleming Mattox, and David G. Whitten
pp 1733 - 1735; DOI:
10.1021/ja00370a048
PDF
High diastereoselection in the alkylation of siloxy-substituted methyl cyclopropanecarboxylates: consequence of a pyramidal ester enolate anion?
Hans Ulrich Reissig and Ingrid Boehm
pp 1735 - 1737; DOI:
10.1021/ja00370a049
PDF
Asymmetric alkylation reactions of chiral imide enolates. A practical approach to the enantioselective synthesis of .alpha.-substituted carboxylic acid derivatives
D. A. Evans, M. D. Ennis, and D. J. Mathre
pp 1737 - 1739; DOI:
10.1021/ja00370a050
PDF
Multiple metal-carbon bonds. 25. Preparation and structure of tungsten neopentylidene hydride, neopentylidene carbonyl, and neopentylidene ethylene complexes
J. H. Wengrovius, R. R. Schrock, M. R. Churchill, and H. J. Wasserman
pp 1739 - 1740; DOI:
10.1021/ja00370a051
PDF
Photoelectron spectroscopic measurement of the relative charge on carbyne fragments bound to polynuclear cobalt carbonyl clusters
Prabodh Deshmukh, T. K. Dutta, J. L. S. Hwang, C. E. Housecroft, and T. P. Fehlner
pp 1740 - 1742; DOI:
10.1021/ja00370a052
PDF
High optical yields in a photochemical cycloaddition. Lack of cooperativity as a clue to mechanism
Laren M. Tolbert and Mahfuza B. Ali
pp 1742 - 1744; DOI:
10.1021/ja00370a053
PDF
Synthesis, structure, and properties of [Co8S6(SC6H5)8]4-, containing an octanuclear Co8S6 rhombic dodecahedron related to that of cobalt pentlandite
G. Christou, K. S. Hagen, and R. H. Holm
pp 1744 - 1745; DOI:
10.1021/ja00370a054
PDF
Fungal xanthone biosynthesis. Distribution of acetate-derived oxygens in ravenelin
J. Gordon Hill, Thomas T. Nakashima, and John C. Vederas
pp 1745 - 1748; DOI:
10.1021/ja00370a055
PDF
Nocardicin A biosynthesis: stereochemical course of monocyclic .beta.-lactam formation
Craig A. Townsend and Alethia M. Brown
pp 1748 - 1750; DOI:
10.1021/ja00370a056
PDF
Irreversible inhibition of the enzymic oxidation of arachidonic acid to 15-hydroperoxy-5,8,11-Z,13-E-eicosatetraenoic acid (15-HPETE) by 14,15-dehydroarachidonic acid
E. J. Corey and Hokoon Park
pp 1750 - 1752; DOI:
10.1021/ja00370a057
PDF
Irreversible inhibition of prostaglandin and leukotriene biosynthesis from arachidonic acid by 11,12-dehydro- and 5,6-dehydroarachidonic acids, respectively
E. J. Corey and John E. Munroe
pp 1752 - 1754; DOI:
10.1021/ja00370a058
PDF
Temperature dependence of the cycloaddition of phenylchlorocarbene to alkenes. Observation of negative activation energies
Nicholas J. Turro, Gary F. Lehr, Jared A. Butcher, Robert A. Moss, and Wenjeng Guo
pp 1754 - 1756; DOI:
10.1021/ja00370a059
PDF
Synthesis and structural investigation of [mesityl(diphenylmethylene)phosphine]bis(triphenylphosphine)platinum(0)
T. A. Van der Knaap, F. Bickelhaupt, H. Van der Poel, G. Van Koten, and C. H. Stam
pp 1756 - 1757; DOI:
10.1021/ja00370a060
PDF
Interactions of ions with the surface receptor of the azobenzene-containing bilayer membrane. Discrimination, transduction, and amplification of chemical signals
M. Shimomura and T. Kunitake
pp 1757 - 1759; DOI:
10.1021/ja00370a061
PDF
Strategy for nitrogen NMR analysis of biopolymers
T. A. Cross, J. A. DiVerdi, and S. J. Opella
pp 1759 - 1761; DOI:
10.1021/ja00370a062
PDF
Nitrogen-hydrogen bond lengths in DNA
J. A. DiVerdi and S. J. Opella
pp 1761 - 1762; DOI:
10.1021/ja00370a063
PDF
Modeling heterogeneous catalysts with homogeneous catalysts. 2. Modeling catalytic hydrodenitrogenation
Richard M. Laine, David W. Thomas, and Lewis W. Cary
pp 1763 - 1765; DOI:
10.1021/ja00370a064
PDF
Synthesis and crystal structure of (.eta.5-C5Me5)2Cr2S5 containing an unusual bridging disulfur ligand .eta.1-(.mu.-S,S)
Henri Brunner, Joachim Wachter, Ernst Guggolz, and Manfred L. Ziegler
pp 1765 - 1766; DOI:
10.1021/ja00370a065
PDF
Effect of reagent rotation on the cross section for the reaction lithium + hydrogen fluoride .fwdarw. lithium fluoride + hydrogen
I. NoorBatcha and N. Sathyamurthy
pp 1766 - 1767; DOI:
10.1021/ja00370a066
PDF
Total synthesis of (.+-.)-pleuromutilin
E. Grant Gibbons
pp 1767 - 1769; DOI:
10.1021/ja00370a067
PDF
Oxidation of ketals to orthocarbonates: a double Baeyer-Villiger reaction
William F. Bailey and Mei Jue Shih
pp 1769 - 1771; DOI:
10.1021/ja00370a068
PDF
Chemical reactivity of the new amino acid .beta.-carboxyaspartic acid (Asa)
M. Robert Christy and Tad H. Koch
pp 1771 - 1772; DOI:
10.1021/ja00370a069
PDF
Preparation and crystal structure of bis[bis(pentamethylcyclopentadienyl)ytterbium(III)] undecacarbonyltriferrate, [(C5Me5)2Yb]2 [Fe3(CO)11]; a compound with four isocarbonyl (iron-carbonyl-ytterbium) interactions
T. Don Tilley and Richard Andersen
pp 1772 - 1774; DOI:
10.1021/ja00370a070
PDF
Stereospecific synthesis of the C30-C43 segment of palytoxin by macrocyclically controlled remote asymmetric induction
W. Clark Still and Igor Galynker
pp 1774 - 1776; DOI:
10.1021/ja00370a071
PDF
Biomimetic synthesis of dibromophakellin
Louise H. Foley and George Buechi
pp 1776 - 1777; DOI:
10.1021/ja00370a072
PDF
Additions of -oxo dianions to sterically congested carbonyls
Conrad J. Kowalski and Kevin W. Fields
pp 1777 - 1779; DOI:
10.1021/ja00370a073
PDF
1,2,4,6-Cycloheptatetraene
Paul R. West, Orville L. Chapman, and Jean Pierre LeRoux
pp 1779 - 1782; DOI:
10.1021/ja00370a074
PDF
Chemistry of heterocyclic compounds. Part 78. Acute bonding deviation in square planar d8-palladium(II) complexes
George R. Newkome, Frank R. Fronczek, V. K. Gupta, Wallace E. Puckett, Daniel C. Pantaleo, and Garry E. Kiefer
pp 1782 - 1783; DOI:
10.1021/ja00370a075
PDF
Facile, palladium(II)-mediated synthesis of bridged and spirocyclic bicycloalkenones
Andrew S. Kende, Bruce Roth, and Pauline J. Sanfilippo
pp 1784 - 1785; DOI:
10.1021/ja00370a076
PDF
Biogenetic-type total synthesis of (.+-.)-triptonide and (.+-.)-triptolide
E. E. Van Tamelen and T. M. Leiden
pp 1785 - 1786; DOI:
10.1021/ja00370a077
PDF
Book Reviews

pp 1786 - 1788; DOI:
10.1021/ja00370a600
PDF

Issue 7


Analysis of static and dynamic host-guest associations of detergents with cyclodextrins via photoluminescence methods
Nicholas J. Turro, Tsuneo Okubo, and Chao Jen Chung
pp 1789 - 1794; DOI:
10.1021/ja00371a001
PDF
Proton affinity and ion-molecule reactions of a simple silyl enol ether
Monica L. Hendewerk, David A. Weil, Tanni L. Stone, Mark R. Ellenberger, William E. Farneth, and David A. Dixon
pp 1794 - 1799; DOI:
10.1021/ja00371a002
PDF
Fluorescence quenching by neutral molecules in sodium decyl sulfate micelles
M. Van der Auweraer, C. Dederen, C. Palmans-Windels, and F. C. De Schryver
pp 1800 - 1804; DOI:
10.1021/ja00371a003
PDF
Transient intermediates in the photo-Fries isomerization of phenyl acetate via spontaneous Raman spectroscopy
S. M. Beck and L. E. Brus
pp 1805 - 1808; DOI:
10.1021/ja00371a004
PDF
Model calculations of kinetic isotope effects for the solvolysis of neopentyl arenesulfonates
Hiroshi Yamataka and Takashi Ando
pp 1808 - 1813; DOI:
10.1021/ja00371a005
PDF
Relative bond dissociation energies for two-ligand complexes of nickel(+) with organic molecules in the gas phase
Manfred M. Kappes and Ralph H. Staley
pp 1813 - 1819; DOI:
10.1021/ja00371a006
PDF
Relative bond dissociation energies for two-ligand complexes of bromoiron(+) (FeBr+) with organic molecules in the gas phase
Manfred M. Kappes and Ralph H. Staley
pp 1819 - 1823; DOI:
10.1021/ja00371a007
PDF
Spectroscopic studies of intramolecular hydrogen bonding in gramicidin S
Eric M. Krauss and Sunney I. Chan
pp 1824 - 1830; DOI:
10.1021/ja00371a008
PDF
Multiphoton ionization. Time-of-flight mass spectrometry of transition metal complexes: dimanganese decacarbonyl and dirhenium decacarbonyl
D. A. Lichtin, R. B. Bernstein, and V. Vaida
pp 1830 - 1834; DOI:
10.1021/ja00371a009
PDF
Secondary ion mass spectrometry of small-molecule solids at cryogenic temperatures. 3. Nitrogen oxides
Robert G. Orth, Harry T. Jonkman, and Josef Michl
pp 1834 - 1842; DOI:
10.1021/ja00371a010
PDF
Fast reaction studies of rhenium carbonyl complexes: the pentacarbonylrhenium(0) radical
Wilma K. Meckstroth, R. Tom Walters, William L. Waltz, Andrew Wojcicki, and Leon M. Dorfman
pp 1842 - 1846; DOI:
10.1021/ja00371a011
PDF
Hydrogenation of alkylzirconium(IV) complexes: heterolytic activation of hydrogen by a homogeneous metal alkyl
Kerrie I. Gell, Barry Posin, Jeffrey Schwartz, and Gregory M. Williams
pp 1846 - 1855; DOI:
10.1021/ja00371a012
PDF
Stereochemically nonrigid silanes, germanes, and stannanes. 9. Chiral silylcyclopentadienes and related compounds: mechanistic and stereochemical definition of fluxional behavior
Alan Bonny, Rupert D. Holmes-Smith, Geoffrey Hunter, and Stephen R. Stobart
pp 1855 - 1859; DOI:
10.1021/ja00371a013
PDF
Mechanistic study of photoinduced .beta.-hydride elimination. The facile photochemical synthesis of low-valent thorium and uranium organometallics
Joseph W. Bruno, Dale G. Kalina, Eric A. Mintz, and Tobin J. Marks
pp 1860 - 1869; DOI:
10.1021/ja00371a014
PDF
Stable precursors of transition-metal carbene complexes. Simplified preparation and crystal structure of (.eta.5-cyclopentadienyl)[(dimethylsulfonium)methyl]dicarbonyliron(II) fluorosulfonate
Edward J. O'Connor and Paul Helquist
pp 1869 - 1874; DOI:
10.1021/ja00371a015
PDF
Synthesis, molecular structure, and reactions of bis(tetraphenylphosphonium) hexakis(.mu.-thiophenolato)-tetrachlorotetraferrate(II), (Ph4P)2[Fe4(SPh)6Cl4]. Its reactions with dibenzyl trisulfide and the synthesis of the [Fe4S4Cl4]2- and [Fe4S4(Cl)2(SC6H5)2]2- "Cubane"-type clusters
D. Coucouvanis, M. Kanatzidis, E. Simhon, and N. C. Baenziger
pp 1874 - 1882; DOI:
10.1021/ja00371a016
PDF
Syntheses and electronic structures of decamethylmetallocenes
J. L. Robbins, N. Edelstein, B. Spencer, and J. C. Smart
pp 1882 - 1893; DOI:
10.1021/ja00371a017
PDF
Synthesis and conformational properties of 3,8-phosphonanedione 1-oxides
Louis D. Quin, Eric D. Middlemas, Nandakumar S. Rao, Richard W. Miller, and Andrew T. McPhail
pp 1893 - 1900; DOI:
10.1021/ja00371a018
PDF
Synthesis of aromatic carbonyl compounds via thallation-carbonylation of arenes
Richard C. Larock and Constance A. Fellows
pp 1900 - 1907; DOI:
10.1021/ja00371a019
PDF
Synthesis of sesquiterpene antitumor lactones. 9. The hydronaphthalene route to pseudoguaianes. Total synthesis of (.+-.)-confertin
Clayton H. Heathcock, Eric G. DelMar, and Samuel Lindsay Graham
pp 1907 - 1917; DOI:
10.1021/ja00371a020
PDF
Titanium-promoted synthesis of a carbohydrazido ligand from carbon monoxide and diphenyldiazomethane: diazoalkane coordination and activation by dicyclopentadienyltitanium(II) and -vanadium(II) complexes
Sandro Gambarotta, Carlo Floriani, Angiola Chiesi-Villa, and Carlo Guastini
pp 1918 - 1924; DOI:
10.1021/ja00371a021
PDF
Photochemical addition of tertiary amines to stilbene. Free-radical and electron-transfer mechanisms for amine oxidation
Frederick D. Lewis, Tong Ing Ho, and J. Thomas Simpson
pp 1924 - 1929; DOI:
10.1021/ja00371a022
PDF
Stereoselective and regioselective Lewis acid catalyzed ene reactions of .alpha.-substituted acrylate esters
John V. Duncia, Peter T. Lansbury, Timothy Miller, and Barry B. Snider
pp 1930 - 1936; DOI:
10.1021/ja00371a023
PDF
General base catalysis, structure-reactivity interactions, and merging of mechanisms for elimination reactions of (2-arylethyl)quinuclidinium ions
Joseph R. Gandler and William P. Jencks
pp 1937 - 1951; DOI:
10.1021/ja00371a024
PDF
Benzoquinone quenching of diporphyrin excited states: Kinetic evidence for distinguishing electron transfer photoproducts from (.pi.,.pi.*) states
T. L. Netzel, M. A. Bergkamp, and C. K. Chang
pp 1952 - 1957; DOI:
10.1021/ja00371a025
PDF
Definition of the protonation equilibria of weak organic bases
V. Lucchini, G. Modena, G. Scorrano, R. A. Cox, and K. Yates
pp 1958 - 1959; DOI:
10.1021/ja00371a026
PDF
Photoresponsive crown ethers. 4. Influence of alkali metal cations on photoisomerization and thermal isomerization of azobis(benzocrown ethers)
Seiji Shinkai, Toshiyuki Ogawa, Yumiko Kusano, Osamu Manabe, Kiyoshi Kikukawa, Tokio Goto, and Tsutomu Matsuda
pp 1960 - 1967; DOI:
10.1021/ja00371a027
PDF
Photoresponsive crown ethers. 5. Light-driven ion transport by crown ethers with a photoresponsive anionic cap
Seiji Shinkai, Takahide Minami, Yumiko Kusano, and Osamu Manabe
pp 1967 - 1972; DOI:
10.1021/ja00371a028
PDF
Conformational effects in the hydrolyses of rigid benzylic epoxides: implications for diol epoxides of polycyclic hydrocarbons
J. M. Sayer, H. Yagi, J. V. Silverton, S. L. Friedman, D. L. Whalen, and D. M. Jerina
pp 1972 - 1978; DOI:
10.1021/ja00371a029
PDF
Hydrogen atom transfer oxidation of primary and secondary alcoholates into aldehydes and ketones by aromatic halides in liquid ammonia. A new electrochemically induceable reaction
Christian Amatore, Janine Badoz-Lambling, Claudine Bonnel-Huyghes, Jean Pinson, Jean Michel Saveant, and Andre Thiebault
pp 1979 - 1986; DOI:
10.1021/ja00371a030
PDF
Phosphonosulfates. Metal ion catalysis in the hydrolysis of 2-pyridyl- and 2-pyridylmethyl phosphonosulfate
Toshio Eiki, Tetsuo Horiguchi, Michimasa Ono, Shuji Kawada, and Waichiro Tagaki
pp 1986 - 1991; DOI:
10.1021/ja00371a031
PDF
Studies of hydrogen-bonded 5'-guanosine monophosphate self-associates using low-frequency Raman scattering
O. Faurskov Nielsen, P. A. Lund, and Steffen B. Petersen
pp 1991 - 1995; DOI:
10.1021/ja00371a032
PDF
l-Canavanine, a paradigm for the structures of substituted guanidines
Alan Boyar and Richard E. Marsh
pp 1995 - 1998; DOI:
10.1021/ja00371a033
PDF
A new family of clathrochelate complexes produced by a ligand rearrangement reaction
Norman Herron, Joseph J. Grzybowski, Naohide Matsumoto, L. Lawrence Zimmer, Gary G. Christoph, and Daryle H. Busch
pp 1999 - 2007; DOI:
10.1021/ja00371a034
PDF
Organolanthanide hydride chemistry. 1. Synthesis and x-ray crystallographic characterization of dimeric organolanthanide and organoyttrium hydride complexes
William J. Evans, James H. Meadows, Andrea L. Wayda, William E. Hunter, and Jerry L. Atwood
pp 2008 - 2014; DOI:
10.1021/ja00371a035
PDF
Organolanthanide hydride chemistry. 2. Synthesis and x-ray crystallographic characterization of a trimetallic organolanthanide polyhydride complex
William J. Evans, James H. Meadows, Andrea L. Wayda, William E. Hunter, and Jerry L. Atwood
pp 2015 - 2017; DOI:
10.1021/ja00371a036
PDF
Unsymmetrical introduction of two functional groups into cyclodextrin. Combination specificity by use of N-benzyl-N-methylaniline N-oxide cap
Iwao Tabushi, Tatsuya Nabeshima, Hiroshi Kitaguchi, and Kazuo Yamamura
pp 2017 - 2019; DOI:
10.1021/ja00371a037
PDF
Metal-formaldehyde chemistry: coordination, disproportionation and Lewis acid-promoted transformation to oxymethylene derivatives
S. Gambarotta, C. Floriani, A. Chiesi-Villa, and C. Guastini
pp 2019 - 2020; DOI:
10.1021/ja00371a038
PDF
The modes of .beta.-silyl involvement in solvolysis
Joseph B. Lambert and Rodney B. Finzel
pp 2020 - 2022; DOI:
10.1021/ja00371a039
PDF
Migrating-group orientation in carbene rearrangements
Alex Nickon and June K. Bronfenbrenner
pp 2022 - 2023; DOI:
10.1021/ja00371a040
PDF
Ruthenium(II) catalyzed reaction of 1,4-epiperoxides
M. Suzuki, R. Noyori, and N. Hamanaka
pp 2024 - 2025; DOI:
10.1021/ja00371a041
PDF
Square and butterfly, 12-electron molybdenum (Mo4) clusters formed by coupling molybdenum-molybdenum triple bonds
M. H. Chisholm, R. J. Errington, K. Folting, and J. C. Huffman
pp 2025 - 2027; DOI:
10.1021/ja00371a042
PDF
Carbohydrates in organic synthesis. Synthesis of 16-membered-ring macrolide antibiotics. 5. Total synthesis of O-mycinosyltylonolide: synthesis of key intermediates
K. C. Nicolaou, M. R. Pavia, and S. P. Seitz
pp 2027 - 2029; DOI:
10.1021/ja00371a043
PDF
Carbohydrates in organic synthesis. Synthesis of 16-membered-ring macrolide antibiotics. 6. Total synthesis of O-mycinosyltylonolide: coupling of key intermediates and macrocyclization
K. C. Nicolaou, S. P. Seitz, and M. R. Pavia
pp 2030 - 2031; DOI:
10.1021/ja00371a044
PDF
Synthesis and characterization of a new surface derivatizing reagent to promote the adhesion of polypyrrole films to N-type silicon photoanodes: N-(3-(trimethoxysilyl)propyl)pyrrole
Richard A. Simon, Antonio J. Ricco, and Mark S. Wrighton
pp 2031 - 2034; DOI:
10.1021/ja00371a045
PDF
Pyridine coordination chemistry of nickel and platinum surfaces
Ronald M. Wexler, Min Chi Tsai, C. M. Friend, and E. L. Muetterties
pp 2034 - 2036; DOI:
10.1021/ja00371a046
PDF
Orbital rotation in the lowest triplet state of benzophenone
K. P. Dinse and D. W. Pratt
pp 2036 - 2038; DOI:
10.1021/ja00371a047
PDF
Luminescence of a series of pentacarbonyl(pyridino)molybdenum(0) complexes in fluid solution
Alistair J. Lees
pp 2038 - 2039; DOI:
10.1021/ja00371a048
PDF
Karachine: an unusual protoberberine alkaloid
Gabor Blasko, Natesan Murugesan, Alan J. Freyer, Maurice Shamma, Akber Ali Ansari, and Atta-ur-Rahman
pp 2039 - 2041; DOI:
10.1021/ja00371a049
PDF
Quadruply bonded dimolybdenum compounds of the type Mo2(O2CR)2X2(PR3)2: evidence for kinetic and structural trans effects
Gregory S. Girolami, Vera V. Mainz, and Richard A. Andersen
pp 2041 - 2042; DOI:
10.1021/ja00371a050
PDF
Characterization of several novel iron nitrosyl porphyrins
L. W. Olson, D. Schaeper, D. Lancon, and K. M. Kadish
pp 2042 - 2044; DOI:
10.1021/ja00371a051
PDF
Time-resolved resonance Raman investigation of photostimulated electron transfer from amines to trans-stilbene
Walter Hub, Siegfried Schneider, Friedrich Doerr, J. Thomas Simpson, Joe D. Oxman, and Frederick D. Lewis
pp 2044 - 2045; DOI:
10.1021/ja00371a052
PDF
Catalytic multiple template-directed steroid chlorinations
Ronald Breslow and Dennis Heyer
pp 2045 - 2046; DOI:
10.1021/ja00371a053
PDF
Studies in macrolide synthesis: lactones by sulfur to oxygen acyl transfer of hydroxyalkyl thiollactones
E. Vedejs and D. W. Powell
pp 2046 - 2048; DOI:
10.1021/ja00371a054
PDF
Suicidal inactivation of cytochrome P-450 by cyclopropylamines. Evidence for cation-radical intermediates
Robert P. Hanzlik and Robert H. Tullman
pp 2048 - 2050; DOI:
10.1021/ja00371a055
PDF
Mechanism of cytochrome P-450 inhibition by cyclopropylamines
Timothy L. Macdonald, Karimullah Zirvi, Leo T. Burka, Pamela Peyman, and F. Peter Guengerich
pp 2050 - 2052; DOI:
10.1021/ja00371a056
PDF
An explanation for the observed stoichiometry of carbon monoxide binding to hemocyanin
Thomas N. Sorrell and Donald L. Jameson
pp 2053 - 2054; DOI:
10.1021/ja00371a057
PDF
Mercury(1+) (6s1) ions in potassium dihydrogen phosphate and ammonium dihydrogen phosphate: new paramagnetic probes of cationic dynamics near phase transitions in hydrogen-bonded ferroelectrics and antiferroelectrics
N. S. Dalal, D. Nettar, and P. Grandinetti
pp 2054 - 2056; DOI:
10.1021/ja00371a058
PDF
[2.2.1]Propellane
Frederick H. Walker, Kenneth B. Wiberg, and Josef Michl
pp 2056 - 2057; DOI:
10.1021/ja00371a059
PDF
Triplet ESR spectrum of the copper porphyrin cation radical
S. Konishi, M. Hoshino, and M. Imamura
pp 2057 - 2059; DOI:
10.1021/ja00371a060
PDF
An unusually facile thioallylic rearrangement - stereochemical evidence for a free radical chain mechanism
Alan P. Kozikowski, Edward Huie, and James P. Springer
pp 2059 - 2060; DOI:
10.1021/ja00371a061
PDF
Direct sterol synthesis by the nonenzymic cyclization of an acarbocyclic monosubstituted epoxide
E. E. Van Tamelen and T. M. Leiden
pp 2061 - 2062; DOI:
10.1021/ja00371a062
PDF
Delocalized .pi. radical cations of acetals
Larry D. Snow, Jih Tzong Wang, and Ffrancon Williams
pp 2062 - 2064; DOI:
10.1021/ja00371a063
PDF
Triphase catalytic cyclization. Efficacious macrolide synthesis
Steven L. Regen and Yoshikazu Kimura
pp 2064 - 2065; DOI:
10.1021/ja00371a064
PDF
Lifetime of singlet oxygen in solution directly determined by laser spectroscopy
John R. Hurst, J. D. McDonald, and Gary B. Schuster
pp 2065 - 2067; DOI:
10.1021/ja00371a065
PDF
Optical determination of the collisional lifetime of singlet molecular oxygen [O2(1.DELTA.g)] in acetone and deuterated acetone
J. G. Parker and W. D. Stanbro
pp 2067 - 2069; DOI:
10.1021/ja00371a066
PDF
Chemistry of singlet oxygen. 36. Singlet molecular oxygen (1.DELTA.g) luminescence in solution following pulsed laser excitation. Solvent deuterium isotope effects on the lifetime of singlet oxygen
Peter R. Ogilby and Christopher S. Foote
pp 2069 - 2070; DOI:
10.1021/ja00371a067
PDF
Protonation of 11-methylene-1,6-methano[10]annulene
Koop Lammertsma
pp 2070 - 2072; DOI:
10.1021/ja00371a068
PDF
Preparation and structure of the phenylcopper ([Cu5(C6H5)6]-) anion
Peter G. Edwards, Robert W. Gellert, Melodye W. Marks, and Robert Bau
pp 2072 - 2073; DOI:
10.1021/ja00371a069
PDF
Initial fluorescence depolarization of tyrosines in proteins
Ronald M. Levy and Attila Szabo
pp 2073 - 2075; DOI:
10.1021/ja00371a070
PDF
Use of "enantiopolar" directions in centrosymmetric crystals for direct assignment of absolute configuration of chiral molecules: application to the system serine/threonine
L. Addadi, Z. Berkovitch-Yellin, I. Weissbuch, M. Lahav, L. Leiserowitz, and S. Weinstein
pp 2075 - 2077; DOI:
10.1021/ja00371a071
PDF
Thermal tetramerization of 1-phenyl-3,4-dimethylphosphole. An access to 2,2'-biphospholes and to 2,2'-diphosphafulvalene complexes
Francois Mathey, Francois Mercier, Francois Nief, Jean Fischer, and Andre Mitschler
pp 2077 - 2079; DOI:
10.1021/ja00371a072
PDF
A new design for chiral induction: a highly regioselective differentiation between two identical groups in an acyclic compound having a prochiral center
Yoshimitsu Nagao, Takao Ikeda, Masahiro Yagi, Eiichi Fujita, and Motoo Shiro
pp 2079 - 2081; DOI:
10.1021/ja00371a073
PDF
Remarkably high regioselective deprotonation and alkylation of unsymmetrical imines at the more substituted .alpha.-carbon atom
Akira Hosomi, Yoshitaka Araki, and Hideki Sakurai
pp 2081 - 2083; DOI:
10.1021/ja00371a074
PDF
Additions and Corrections - Oxotrimolybdenum(IV) Alkoxides, Mo33·O)(μ3·OR)(μ2·OR)3(OR)6 (R = CH(CH3)2 and CH2C(CH3)3). Synthetic Considerations
M. H. Chisholm, K. Folting, J. C. Huffman, and C. C. Kirkpatrick
pp 2084 - 2084; DOI:
10.1021/ja00371a600
PDF
Additions and Corrections - Biosynthesis of Retronecine
Gunnar Grue-Sørensen, and Ian D. Spenser
pp 2084 - 2084; DOI:
10.1021/ja00371a601
PDF
Book Reviews

pp 2084 - 2084; DOI:
10.1021/ja00371a602
PDF

Issue 8


Free energies, enthalpies, and entropies of solution of gaseous nonpolar nonelectrolytes in water and nonaqueous solvents. The hydrophobic effect
Michael H. Abraham
pp 2085 - 2094; DOI:
10.1021/ja00372a001
PDF
Photochromic forms of 6-nitrobenzospiropyran. Emission spectroscopic and ODMR investigations
M. Gehrtz, C. Braeuchle, and J. Voitlaender
pp 2094 - 2101; DOI:
10.1021/ja00372a002
PDF
Ligand, oxygen, and carbon monoxide affinities of iron(II) modified "capped" porphyrins
Toshiaki Hashimoto, Jack E. Baldwin, Fred Basolo, Robert L. Dyer, and Maxwell J. Crossley
pp 2101 - 2109; DOI:
10.1021/ja00372a003
PDF
Stereochemically nonrigid silanes, germanes, and stannanes. 10. Diastereoisomerism and metallotropic behavior in polyindenyl derivatives of germanium and tin. Facile stereomutation
A. D. McMaster and Stephen R. Stobart
pp 2109 - 2112; DOI:
10.1021/ja00372a004
PDF
Labilization of carbon monoxide dissociation from metal clusters: an investigation of the substitution reactions of monosubstituted derivatives of tetrairidium, Ir4(CO)11L (L = PBu3, PPh3, AsPh3, and P(OPh)3)
David C. Sonnenberger and Jim D. Atwood
pp 2113 - 2116; DOI:
10.1021/ja00372a005
PDF
Structural characterization and fluxional behavior of cyclohexenylmanganese tricarbonyl. Intramolecular carbon-hydrogen bond activation via a 2-electron, 3-center manganese...hydrogen...carbon interaction
M. Brookhart, W. Lamanna, and M. Beth Humphrey
pp 2117 - 2126; DOI:
10.1021/ja00372a006
PDF
Pentacoordinated molecules. 44. Crystal structures of two phenyl spiroarsoranes. The first truly rectangular-pyramidal arsenic(V) compound
Roberta O. Day, Joan M. Holmes, Arjun C. Sau, Robert R. Holmes, Joan A. Deiters, and Jean R. Devillers
pp 2127 - 2132; DOI:
10.1021/ja00372a007
PDF
Vibrational fine structure in the valence ionizations of transition metal hexacarbonyls: new experimental indication of metal-to-carbonyl .pi. bonding
John L. Hubbard and Dennis L. Lichtenberger
pp 2132 - 2138; DOI:
10.1021/ja00372a008
PDF
Reactions of metal-metal multiple bonds. 8. Forming molybdenum-molybdenum quadruple bonds by reductive elimination (alkyl group disproportionation) in the reactions of 1,2-Mo2R2(NMe2)4 compounds (M.tplbond.M) with carbon dioxide and 1,3-diaryltriazines
M. J. Chetcuti, M. H. Chisholm, K. Folting, D. A. Haitko, and J. C. Huffman
pp 2138 - 2146; DOI:
10.1021/ja00372a009
PDF
Synthesis, structure, and electrochemistry of platinum(II) metallacyclobutanes
R. J. Klingler, J. C. Huffman, and J. K. Kochi
pp 2147 - 2157; DOI:
10.1021/ja00372a010
PDF
Synthesis and reactivity of new polyhydride compounds of tantalum(V)
James M. Mayer and John E. Bercaw
pp 2157 - 2165; DOI:
10.1021/ja00372a011
PDF
Synthesis, crystal structure and molecular conformations, and magnetic properties of a copper-vanadyl (CuII-VOII) heterobinuclear complex: interaction between orthogonal magnetic orbitals
O. Kahn, J. Galy, Y. Journaux, J. Jaud, and I. Morgenstern-Badarau
pp 2165 - 2176; DOI:
10.1021/ja00372a012
PDF
Kinetic acidity of diastereotopic protons in sulfonium ions. 2. Thiolanium cations. X-ray molecular structure of 8-methyl-8-thioniabicyclo[4.3.0]nonane tetrafluoroborate and quantitative perturbational molecular orbital analysis of diastereomeric model sulfonium ylides
Giovanni Dario Andreetti, Fernando Bernardi, Andrea Bottoni, and Antonino Fava
pp 2176 - 2183; DOI:
10.1021/ja00372a013
PDF
The oxidation of amines with sulfonyl peroxides. 6. Transition-state structures of base-promoted, imine-forming eliminations from N-benzyl-O-(arylsulfonyl)hydroxylamines
Robert V. Hoffman and Edward L. Belfoure
pp 2183 - 2189; DOI:
10.1021/ja00372a014
PDF
Prostaglandins. 2. Synthesis of prostaglandin F2.alpha. in optically active form from chiral precursors
Francis Johnson, K. G. Paul, Duccio Favara, Romeo Ciabatti, and Umberto Guzzi
pp 2190 - 2198; DOI:
10.1021/ja00372a015
PDF
Stereoselective total synthesis of (.+-.)-gymnomitrol via reduction-alkylation of .alpha.-cyano ketones
Robert M. Coates, Shrenik K. Shah, and Robert W. Mason
pp 2198 - 2208; DOI:
10.1021/ja00372a016
PDF
Synthesis and thermolysis of 5-alkylidenebicyclo[2.1.0]pentanes. Generation and dimerization of trimethylenemethane triplet biradicals by bond rupture of strained hydrocarbons
Mark Rule, James A. Mondo, and Jerome A. Berson
pp 2209 - 2216; DOI:
10.1021/ja00372a017
PDF
Formal kinetic proof of reversible unimolecular transformation to a biradical as an obligatory first step in the mechanism of cycloaddition of 5-isopropylidenebicyclo[2.1.0]pentane to olefins
Mark R. Mazur and Jerome A. Berson
pp 2217 - 2222; DOI:
10.1021/ja00372a018
PDF
Chemistry of bicyclo[3.1.0]hex-1-enes contrasted with that of 2-alkylidenecyclopentane-1,3-diyls
Mark Rule, Richard F. Salinaro, Dexter R. Pratt, and Jerome A. Berson
pp 2223 - 2228; DOI:
10.1021/ja00372a019
PDF
Implication of a common trimethylenemethane intermediate in dimer formation and structural methylenecyclopropane rearrangement of a bicyclo[3.1.0]hex-1-ene to a 5-alkylidenebicyclo[2.1.0]pentane
Richard F. Salinaro and Jerome A. Berson
pp 2228 - 2232; DOI:
10.1021/ja00372a020
PDF
Observation of two characteristic methylenecyclopropane stereomutations in a system that also forms trimethylenemethane dimers. An experimental connection between putative and directly observed biradicals
Michael G. Lazzara, James J. Harrison, Mark Rule, Edwin F. Hilinski, and Jerome A. Berson
pp 2233 - 2243; DOI:
10.1021/ja00372a021
PDF
A synthesis of (.+-.)-yohimbine
Ernest Wenkert, Jan S. Pyrek, Shinichi Uesato, and Yashwant D. Vankar
pp 2244 - 2246; DOI:
10.1021/ja00372a022
PDF
Barriers to rotation of methyl groups in methyltriptycenes
Fumio Imashiro, Kiyonori Takegoshi, Takehiko Terao, and A. Saika
pp 2247 - 2251; DOI:
10.1021/ja00372a023
PDF
Effects of divalent metal ions on hydrolysis of esters of 2-(hydroxymethyl)picolinic acid. Metal ion catalysis of the carboxyl, hydroxide ion, and water reactions
Thomas H. Fife and Theodore J. Przystas
pp 2251 - 2257; DOI:
10.1021/ja00372a024
PDF
Alkylation of nitriles with gaseous carbenium ions. The Ritter reaction in the dilute gas state
Fulvio Cacace, Giovanna Ciranni, and Pierluigi Giacomello
pp 2258 - 2261; DOI:
10.1021/ja00372a025
PDF
A comparison between the stereoselective thermal-induced and ionization-induced elimination of acetic acid from 2-butyl acetate
Mark M. Green, Richard J. McCluskey, and Juergen Vogt
pp 2262 - 2269; DOI:
10.1021/ja00372a026
PDF
Stereochemical aspects of the intramolecular Diels-Alder reactions of deca-2,7,9-trienoate esters. 3. Thermal, Lewis acid catalyzed, and asymmetric cyclizations
William R. Roush, Herbert R. Gillis, and Albert I. Ko
pp 2269 - 2283; DOI:
10.1021/ja00372a027
PDF
Dioxygen transfer from 4a-hydroperoxyflavin anion. 4. Dioxygen transfer to phenolate anion as a means of aromatic hydroxylation
Shigeaki Muto and Thomas C. Bruice
pp 2284 - 2290; DOI:
10.1021/ja00372a028
PDF
High-pressure NMR study of dynamical effects on conformational isomerization of cyclohexane
D. L. Hasha, T. Eguchi, and J. Jonas
pp 2290 - 2296; DOI:
10.1021/ja00372a029
PDF
Relative bond-dissociation energies for two-ligand complexes of copper(+) with organic molecules in the gas phase
Roger W. Jones and Ralph H. Staley
pp 2296 - 2300; DOI:
10.1021/ja00372a030
PDF
Steric course of hydroxylation at primary carbon atoms. Biosynthesis of 1-octanol from (1R)- and (1S)-[1-3H,2H,1H; 1-14C]octane by rat liver microsomes
Stuart Shapiro, James U. Piper, and Eliahu Caspi
pp 2301 - 2305; DOI:
10.1021/ja00372a031
PDF
Chemistry of higher order mixed organocuprates. 2. Reactions of epoxides
Bruce H. Lipshutz, Joseph Kozlowski, and Robert S. Wilhelm
pp 2305 - 2307; DOI:
10.1021/ja00372a032
PDF
Ion-molecule complexes in decompositions of gaseous cations: 130 nm photolysis of 4-pyridyl ethers
H. W. Biermann, William P. Freeman, and Thomas Hellman Morton
pp 2307 - 2308; DOI:
10.1021/ja00372a033
PDF
Natural product synthesis via allylsilanes. 1. Synthesis and reactions of (1E,3E)-4-acetoxy-1-(trimethylsilyl)-1,3-butadiene and its use in the total synthesis of (.+-.)-shikimic acid
Masato Koreeda and Marco A. Ciufolini
pp 2308 - 2310; DOI:
10.1021/ja00372a034
PDF
Photosubstitution of pentaamminechlororuthenium(III) hexacyanoruthenate(II) following outer-sphere intervalence excitation
Arnd Vogler and Josef Kisslinger
pp 2311 - 2312; DOI:
10.1021/ja00372a035
PDF
Bimetallic acyl complexes. Use of transition organometallic Lewis acids in promoting migratory carbonyl insertion
Stephen J. LaCroce and Alan R. Cutler
pp 2312 - 2314; DOI:
10.1021/ja00372a036
PDF
Synthetic approaches to coordinatively unsaturated heterobimetallic complexes
Debra A. Wrobleski and Thomas B. Rauchfuss
pp 2314 - 2316; DOI:
10.1021/ja00372a037
PDF
Synthesis and molecular structure of a transition-metal cyclamphosphoranide. A pentacyclic structure with the metal bridging a phosphorus-nitrogen bond
Jean Marc Dupart, Andre Grand, Simonne Pace, and Jean G. Riess
pp 2316 - 2318; DOI:
10.1021/ja00372a038
PDF
Applications of ESR spectroscopy to problems of structure and conformation. 34. Dithiaethylene radical cations and anions
Glen A. Russell and Mary Zaleta
pp 2318 - 2318; DOI:
10.1021/ja00372a039
PDF
Could one have five? The synthesis and structure of Re2H4(PMe2Ph)4[P(OCH2)3CEt]2 and its conjugate acid
Mark A. Green, John C. Huffman, and Kenneth G. Caulton
pp 2319 - 2320; DOI:
10.1021/ja00372a040
PDF
Generation of titanocene and rhodocene cations in the gas phase by a novel metal-switching reaction
D. B. Jacobson, G. D. Byrd, and B. S. Freiser
pp 2320 - 2321; DOI:
10.1021/ja00372a041
PDF
Cyclization of vinyl radicals: a versatile method for the construction of five- and six-membered rings
G. Stork and Neil H. Baine
pp 2321 - 2323; DOI:
10.1021/ja00372a042
PDF
The metal effect on aldol type stereoselection. Erythro-selective condensations with aldehydes via .alpha.-mercurio ketones
Yoshinori Yamamoto and Kazuhiro Maruyama
pp 2323 - 2325; DOI:
10.1021/ja00372a043
PDF
Nitrogen to nitrogen proton transfer. The significance of large negative entropies of activation
Charles L. Perrin and Wei Hsien Wang
pp 2325 - 2326; DOI:
10.1021/ja00372a044
PDF
Di-tert-butylcarbene: the low temperature photochemistry of di-tert-butyldiazomethane
James E. Gano, Richard H. Wettach, Matthew S. Platz, and V. P. Senthilnathan
pp 2326 - 2327; DOI:
10.1021/ja00372a045
PDF
Anodic oxidation of heterocumulenes in acetonitrile
James Y. Becker and B. Zinger
pp 2327 - 2329; DOI:
10.1021/ja00372a046
PDF
Mixed-metal clusters of isocyanide containing a mercury atom in the center of a trigonal-prismatic platinum framework. Hg[Pt3(2,6-Me2C6H3NC)6]2
Yasuhiro Yamamoto, Hiroshi Yamazaki, and Toshio Sakurai
pp 2329 - 2330; DOI:
10.1021/ja00372a047
PDF
Enantioselective allylborane condensations
M. Mark Midland and S. B. Preston
pp 2330 - 2331; DOI:
10.1021/ja00372a048
PDF
Polymerization of ethylene by an alkylidene hydride catalyst
Howard W. Turner and Richard R. Schrock
pp 2331 - 2333; DOI:
10.1021/ja00372a049
PDF
Photochemistry of 2,3-diazabicyclo[2.1.1]hex-2-ene. .beta. Carbon-carbon cleavage to a stereorandom triplet biradical
Moon Ho Chang and Dennis A. Dougherty
pp 2333 - 2334; DOI:
10.1021/ja00372a050
PDF
Book Reviews

pp 2335 - 2336; DOI:
10.1021/ja00372a600
PDF

Issue 9


Fragmentation mechanism and energetics of some alkyl halide ions
H. M. Rosenstock, R. Buff, M. A. A. Ferreira, S. G. Lias, A. C. Parr, R. L. Stockbauer, and J. L. Holmes
pp 2337 - 2345; DOI:
10.1021/ja00373a001
PDF
Quantum mechanical studies of the photodissociation of carbonylheme complexes
Ahmad Waleh and Gilda H. Loew
pp 2346 - 2351; DOI:
10.1021/ja00373a002
PDF
Quantum mechanical studies of the photodissociation of oxyheme complexes
Ahmad Waleh and Gilda H. Loew
pp 2352 - 2356; DOI:
10.1021/ja00373a003
PDF
Mechanism of cobalt(III)-promoted hydrolysis of triphosphate ion
Paul R. Norman and Richard D. Cornelius
pp 2356 - 2361; DOI:
10.1021/ja00373a004
PDF
Dealkylation of zirconium(IV) by borane: the intimate mechanism of an alkyl transfer reaction
John A. Marsella and Kenneth G. Caulton
pp 2361 - 2365; DOI:
10.1021/ja00373a005
PDF
Onium ions. 23. Structure of oxonium ions: an x-ray crystallographic study of triethyloxonium hexafluorophosphate and triphenyloxonium tetraphenylborate
Michael I. Watkins, Wai Man Ip, George A. Olah, and Robert Bau
pp 2365 - 2372; DOI:
10.1021/ja00373a006
PDF
Onium ions. 24. Oxygen-17 NMR spectroscopic study of oxonium and carboxonium ions
George A. Olah, Arthur L. Berrier, and G. K. Surya Prakash
pp 2373 - 2376; DOI:
10.1021/ja00373a007
PDF
Crystal and molecular structure of 2,2,8,8,12,13,17,18-octamethylisobacteriochlorin
W. B. T. Cruse, P. J. Harrison, and Olga Kennard
pp 2376 - 2380; DOI:
10.1021/ja00373a008
PDF
Electron exchange between bis(.eta.6-arene)chromium(I) and bis(.eta.6-arene)chromium(0). Comparisons between experimental and calculated kinetic parameters
Tomi T. T. Li, Michael J. Weaver, and Carl H. Brubaker
pp 2381 - 2386; DOI:
10.1021/ja00373a009
PDF
Coordination modes of histidine. 3. Stereochemistry of copper(II) complexes related to pyridoxal catalysis
Luigi Casella, Michele Gullotti, and Gianfranco Pacchioni
pp 2386 - 2396; DOI:
10.1021/ja00373a010
PDF
Organophosphazenes. 15. Reactions of hexafluorocyclotriphosphazene with tert- and n-butyllithium reagents
Kolikkara Ramachandran and Christopher W. Allen
pp 2396 - 2399; DOI:
10.1021/ja00373a011
PDF
EPR studies of the electronic structure and dynamic Jahn-Teller effect in iron(I) sandwich compounds
M. V. Rajasekharan, S. Giezynski, J. H. Ammeter, N. Oswald, J. R. Hamon, D. Astruc, and P. Michaud
pp 2400 - 2407; DOI:
10.1021/ja00373a012
PDF
Coordination behavior of L-aspartic acid: ternary nickel(II) complexes with imidazoles. Crystal and molecular structure of (L-aspartate)tris(imidazole)nickel(II)
L. P. Battaglia, A. Bonamartini Corradi, L. Antolini, G. Marcotrigiano, L. Menabue, and G. C. Pellacani
pp 2407 - 2411; DOI:
10.1021/ja00373a013
PDF
Photoelectrochemical cells based on amorphous hydrogenated silicon thin film electrodes and the behavior of photoconductor electrode materials
Gary S. Calabrese, Mou Shiung Lin, Joseph Dresner, and Mark S. Wrighton
pp 2412 - 2417; DOI:
10.1021/ja00373a014
PDF
Synthesis and x-ray structure of cis-tetracarbonyl[(Z)-(.eta.2-allylamino)(p-tolyl)carbene]tungsten(0), a stable metal-carbene-alkene complex
Charles P. Casey, Alan J. Shusterman, Nicholas W. Vollendorf, and Kenneth J. Haller
pp 2417 - 2423; DOI:
10.1021/ja00373a015
PDF
Effects of pH on anionic inhibition of carbonic anhydrase activities
Y. Pocker and Thomas L. Deits
pp 2424 - 2434; DOI:
10.1021/ja00373a016
PDF
Cryptand exchange kinetics
B. G. Cox, J. Garcia-Rosas, and H. Schneider
pp 2434 - 2437; DOI:
10.1021/ja00373a017
PDF
Linear oligopeptides. 81. Solid-state and solution conformation of homooligo(.alpha.-aminoisobutyric acids) from tripeptide to pentapeptide: evidence for a 310 helix
Ettore Benedetti, Alfonso Bavoso, Benedetto Di Blasio, Vincenzo Pavone, Carlo Pedone, Marco Crisma, Gian Maria Bonora, and Claudio Toniolo
pp 2437 - 2444; DOI:
10.1021/ja00373a018
PDF
Palladium-catalyzed cyclization of .omega.-olefinic tosamides. Synthesis of nonaromatic nitrogen heterocycles
Louis S. Hegedus and James M. McKearin
pp 2444 - 2451; DOI:
10.1021/ja00373a019
PDF
Structure of the 2-hydroxyhomotropylium cation. Unequivocal evidence for homoaromatic delocalization
Ronald F. Childs, Aravamuthan Varadarajan, Colin J. L. Lock, Romolo Faggiani, Colin A. Fyfe, and Roderick E. Wasylishen
pp 2452 - 2456; DOI:
10.1021/ja00373a020
PDF
Singlet-triplet reactivity of a .beta.,.gamma.-unsaturated ketone: mechanistic studies in photochemistry
Richard S. Givens, Woo Ki Chae, and Bogdan Matuszewski
pp 2456 - 2466; DOI:
10.1021/ja00373a021
PDF
Structure and reactivity of bicyclo[3.2.1]octa-2,6-dien-4-ylidene and bicyclo[3.2.1]oct-2-en-4-ylidene. Nucleophilicity of vinylcarbenes
Shunichi Murahashi, Kazuo Okumura, Takeshi Naota, and Shigeru Nagase
pp 2466 - 2475; DOI:
10.1021/ja00373a022
PDF
Super-charged polycyclic .pi. systems: pyrene and perylene tetraanions
Abraham Minsky, Amatzya Y. Meyer, and Mordecai Rabinovitz
pp 2475 - 2482; DOI:
10.1021/ja00373a023
PDF
Reactions of bi(cyclophosphazenes) with sodium alkoxides or aryl oxides
Harry R. Allcock, Mark S. Connolly, and Paul J. Harris
pp 2482 - 2490; DOI:
10.1021/ja00373a024
PDF
Decarbonylation of tetrahydrofuran-2-carboxylic acids and tetrahydropyran-2-carboxylic acids in concentrated sulfuric acid: formation of oxonium ions
Hans Aaron Bates
pp 2490 - 2493; DOI:
10.1021/ja00373a025
PDF
Thermal [1,3] sigmatropic rearrangements of 2,2-difluoro-1-vinylcyclopropanes
William R. Dolbier and Simon F. Sellers
pp 2494 - 2497; DOI:
10.1021/ja00373a026
PDF
Intramolecular oxidative cyclization reactions of trivalent phosphorus and carbonyl functions
S. D. Harper and Anthony J. Arduengo
pp 2497 - 2501; DOI:
10.1021/ja00373a027
PDF
Benzidine rearrangements. 16. The use of heavy-atom kinetic isotope effects in solving the mechanism of the acid-catalyzed rearrangement of hydrazobenzene. The concerted pathway to benzidine and the nonconcerted pathway to diphenyline
Henry J. Shine, Henryk Zmuda, Koon Ha Park, Harold Kwart, Ann Gaffney Horgan, and Martin Brechbiel
pp 2501 - 2509; DOI:
10.1021/ja00373a028
PDF
Photohydration of aromatic alkenes and alkynes
Peter Wan, Stephen Culshaw, and Keith Yates
pp 2509 - 2515; DOI:
10.1021/ja00373a029
PDF
Acid catalyzed hydration of .alpha.-cyano and .alpha.-(trifluoromethyl) vinyl ethers. Additivity of strongly activating and strongly deactivating substituent effects
Annette D. Allen, Fereidoon Shahidi, and Thomas T. Tidwell
pp 2516 - 2518; DOI:
10.1021/ja00373a030
PDF
Two-photon spectroscopy of all-trans-retinal. Nature of the low-lying singlet states
Robert R. Birge, James A. Bennett, Lynn M. Hubbard, Howard L. Fang, Brian M. Pierce, David S. Kliger, and George E. Leroi
pp 2519 - 2525; DOI:
10.1021/ja00373a031
PDF
Production of acrylonitrile and other unsaturated nitriles from alkenes and alkynes
Neil B. H. Henis and Larry L. Miller
pp 2526 - 2529; DOI:
10.1021/ja00373a032
PDF
Effect of buffer viscosity on the fluorescence of bilirubin bound to human serum albumin
Angelo A. Lamola and Jorge Flores
pp 2530 - 2534; DOI:
10.1021/ja00373a033
PDF
Platinum metal surface chemistry of benzene and toluene
Min Chi Tsai and E. L. Muetterties
pp 2534 - 2539; DOI:
10.1021/ja00373a034
PDF
Dehydrogenation processes on nickel and platinum surfaces. Conversion of cyclohexane, cyclohexene, and cyclohexadiene to benzene
Min Chi Tsai, C. M. Friend, and E. L. Muetterties
pp 2539 - 2543; DOI:
10.1021/ja00373a035
PDF
Benzannelated annulenes. 6. Toward the understanding of benzannelated annulenes: synthesis and properties of [a]-ring monobenzannelated dihydropyrenes
Reginald H. Mitchell, Robert J. Carruthers, Ludvik Mazuch, and Thomas W. Dingle
pp 2544 - 2551; DOI:
10.1021/ja00373a036
PDF
Benzannelated annulenes. 7. Toward the understanding of benzannelated annulenes: synthesis and properties of an [e]-ring monobenzannelated dihydropyrene
Reginald H. Mitchell, Joseph S. H. Yan, and Thomas W. Dingle
pp 2551 - 2559; DOI:
10.1021/ja00373a037
PDF
Benzannelated annulenes. 8. Toward the understanding of benzannelated annulenes: synthesis and properties of [a,h]- and [a,i]-ring dibenzannelated dihydropyrenes
Reginald H. Mitchell, Richard Vaughan Williams, and Thomas W. Dingle
pp 2560 - 2571; DOI:
10.1021/ja00373a038
PDF
Benzannulated annulenes. 9. Toward the understanding of benzannulated annulenes: a simple correlation of the diatropicity of several benzannulated dihydropyrenes in terms of bond order deviations with predictions for other benzannulenes
Reginald H. Mitchell, Richard Vaughan Williams, Ramanathan Mahadevan, Yee Hing Lai, and Thomas W. Dingle
pp 2571 - 2578; DOI:
10.1021/ja00373a039
PDF
ESR study of the attack of photolytically produced hydroxyl radicals on .alpha.-methyl-D-glucopyranoside in aqueous solution
Keith P. Madden and R. W. Fessenden
pp 2578 - 2581; DOI:
10.1021/ja00373a040
PDF
Reaction of thiols with phenylglyoxal to give thiol esters of mandelic acid. II. Intramolecular general-base catalysis and change in rate-determining step
Tadashi Okuyama, Shinji Komoguchi, and Takayuki Fueno
pp 2582 - 2587; DOI:
10.1021/ja00373a041
PDF
New five- and six-coordinate imidazole and imidazolate complexes of ferric tetraphenylporphyrin
Robert Quinn, Mario Nappa, and Joan S. Valentine
pp 2588 - 2595; DOI:
10.1021/ja00373a042
PDF
Long-range intervalence electron tunneling through fully saturated systems
C. A. Stein, Nita A. Lewis, and Gunther Seitz
pp 2596 - 2599; DOI:
10.1021/ja00373a043
PDF
Nortricyclylcarbinyl carbocations. Structural hybrides of cyclopropylcarbinyl and bridged 2-norbornyl carbocations
Lawrence R. Schmitz and Ted S. Sorensen
pp 2600 - 2604; DOI:
10.1021/ja00373a044
PDF
Methyl-substituted cyclopropylcarbinyl (alias vinyl-bridged ethylene) carbocations. Molecular orbital calculations and criteria for structure representation-nomenclature decisions
Lawrence R. Schmitz and Ted S. Sorensen
pp 2605 - 2612; DOI:
10.1021/ja00373a045
PDF
Defined dimensional alterations in enzyme substrates. Synthesis and enzymic evaluation of some lin-naphthopurines
Kenneth P. Moder and Nelson J. Leonard
pp 2613 - 2624; DOI:
10.1021/ja00373a046
PDF
Foreshortened nucleotide analogs as potential base-pairing complements for lin-benzoadenosine
Anthony W. Czarnik and Nelson J. Leonard
pp 2624 - 2631; DOI:
10.1021/ja00373a047
PDF
On the migration of a carboxyl group in a Wagner-Meerwein rearrangement in superacid solution: proof by double labeling with carbon-13.
Daniel Berner, D. Phillip Cox, and Hans Dahn
pp 2631 - 2632; DOI:
10.1021/ja00373a048
PDF
Specific peptide sequences for metal ion coordination. 1. Solid-phase synthesis of cyclo-(Gly-His)3
Stephan S. Isied, Christa G. Kuehn, John M. Lyon, and R. B. Merrifield
pp 2632 - 2634; DOI:
10.1021/ja00373a049
PDF
Liquid crystalline catalysis: reactivity induced by smectic solvents
Bruno Samori and Lorenzo Fiocco
pp 2634 - 2636; DOI:
10.1021/ja00373a050
PDF
Phosphine functionalized macrocycles. A new type of bridging ligand for the synthesis of heterometallic complexes
John Powell and Christopher J. May
pp 2636 - 2637; DOI:
10.1021/ja00373a051
PDF
Characterization of the vapor species of dilithiomethane by flash vaporization mass spectroscopy and the Ziegler synthesis of dilithiomethane
John A. Gurak, John W. Chinn, and Richard J. Lagow
pp 2637 - 2639; DOI:
10.1021/ja00373a052
PDF
Electron transfer from nitrogen in microsomal oxidation of amine and amide. Simulation of microsomal oxidation by anodic oxidation
Tatsuya Shono, Toshiki Toda, and Nozomu Oshino
pp 2639 - 2641; DOI:
10.1021/ja00373a053
PDF
Electrogenerated chemiluminescence. 40. A chemiluminescent polymer based on the tris(4-vinyl-4'-methyl-2,2'-bipyridyl)ruthenium(II) system
Hector D. Abruna and Allen J. Bard
pp 2641 - 2642; DOI:
10.1021/ja00373a054
PDF
Silicon-directed Nazarov cyclization
S. E. Denmark and T. K. Jones
pp 2642 - 2645; DOI:
10.1021/ja00373a055
PDF
An ESR study of olefin iron carbonyl radical anions
Paul J. Krusic and Joseph San Filippo
pp 2645 - 2647; DOI:
10.1021/ja00373a056
PDF
A reassessment of nitrobenzene valence bond structures
Kenneth B. Lipkowitz and C. P. Chang
pp 2647 - 2648; DOI:
10.1021/ja00373a057
PDF
Heats of formation of ionic and neutral enols of acetaldehyde and acetone
J. L. Holmes and F. P. Lossing
pp 2648 - 2649; DOI:
10.1021/ja00373a058
PDF
Use of D-[13C6]glucose together with carbon-13-depleted glucose and homonuclear carbon-13 decoupling to identify the labeling pattern by this precursor of the "m-C7N" unit of geldanamycin
Kenneth L. Rinehart, Maria Potgieter, and David A. Wright
pp 2649 - 2652; DOI:
10.1021/ja00373a059
PDF
Calixarenes. 6. Synthesis of a functionalizable calix[4]arene in a conformationally rigid cone conformation
C. David Gutsche and Jeffrey A. Levine
pp 2652 - 2653; DOI:
10.1021/ja00373a060
PDF
Abnormally high nucleophilicity of micellar-bound azide ion
Clifford A. Bunton, John R. Moffatt, and Elvira Rodenas
pp 2653 - 2655; DOI:
10.1021/ja00373a061
PDF
(Glutathiomethyl)glyoxal: mirror-image catalysis by glyoxalase I
John W. Kozarich and Ravi V. J. Chari
pp 2655 - 2657; DOI:
10.1021/ja00373a062
PDF
Systematic design of chemical oscillators. 10. Minimal bromate oscillator: bromate-bromide-catalyst
Miklos Orban, Patrick De Kepper, and Irving R. Epstein
pp 2657 - 2658; DOI:
10.1021/ja00373a063
PDF
A new method for the identification of the origin of natural products. Quantitative deuterium NMR at the natural abundance level applied to the characterization of anetholes
G. J. Martin, M. L. Martin, F. Mabon, and J. Bricout
pp 2658 - 2659; DOI:
10.1021/ja00373a064
PDF
Total synthesis of (.+-.)-mycorrhizin A and (.+-.)-dechloromycorrhizin A
Emil R. Koft and Amos B. Smith
pp 2659 - 2661; DOI:
10.1021/ja00373a065
PDF
A dinuclear rhodium complex with an octahedral rhodium(III) and a square-planar rhodium(I) center
Eric B. Meier, R. R. Burch, E. L. Muetterties, and V. W. Day
pp 2661 - 2663; DOI:
10.1021/ja00373a066
PDF
Temperature regulated release of alkali metal salts from novel polymeric crown ether complexes
Abraham Warshawsky and Nava Kahana
pp 2663 - 2664; DOI:
10.1021/ja00373a067
PDF
Intrastrand crosslinking of the guanines of the deoxytrinucleotide d(G-C-G) via cis-diammineplatinum dichloride
Antonius T. M. Marcelis, Jeroen H. J. Den Hartog, and Jan Reedijk
pp 2664 - 2665; DOI:
10.1021/ja00373a068
PDF
Selectivity profile of the cation radical Diels-Alder reaction
Dennis J. Bellville and Nathan L. Bauld
pp 2665 - 2667; DOI:
10.1021/ja00373a069
PDF
Evidence by gel filtration at subzero temperatures for the covalent reaction intermediate of carboxypeptidase A in ester hydrolysis
Marvin W. Makinen, James M. Fukuyama, and Lawrence C. Kuo
pp 2667 - 2669; DOI:
10.1021/ja00373a070
PDF
Dilithium semibullvalenide: an unusual organolithium compound extends the scope of homoaromaticity
M. J. Goldstein, T. T. Wenzel, G. Whittaker, and S. F. Yates
pp 2669 - 2671; DOI:
10.1021/ja00373a071
PDF
A trimeric iron(III)heme-copper(II) complex: support for an alternate explanation of the "EPR silent" iron-copper pair in cytochrome c oxidase
C. Michael Elliott and Kozo Akabori
pp 2671 - 2674; DOI:
10.1021/ja00373a072
PDF
Dependence of the yield of a radical-pair reaction in the solid state on orientation in a magnetic field
Steven G. Boxer, Christopher E. D. Chidsey, and Mark G. Roelofs
pp 2674 - 2675; DOI:
10.1021/ja00373a073
PDF
Anionic telomerization of acrylonitrile initiated by -CH2CN in the gas phase
Richard N. McDonald and A. Kasem Chowdhury
pp 2675 - 2676; DOI:
10.1021/ja00373a074
PDF
Additions and Corrections - 13C NMR Studies on Arsenic(III) and Antimony(III) Dihydroxydicarboxylate Complexes
Dragoslav Marcovich, and Robert E. Tapscott
pp 2677 - 2677; DOI:
10.1021/ja00373a600
PDF
Additions and Corrections - Classical Electrical Contributions to Solvent Polarity Scales
S. Ehrenson
pp 2677 - 2677; DOI:
10.1021/ja00373a601
PDF
Additions and Corrections - The Automerization of C11H11 Chlorides and the Stability of Their Cations
M. J. Goldstein, S. Tomoda, E. J. Pressman, and J. A. Dodd
pp 2677 - 2677; DOI:
10.1021/ja00373a602
PDF
Additions and Corrections - Thermal Rearrangement of an Allenic Diazoalkane and Intermolecular Capture of a Diazoethene by a Cyclopropene To Give a Common Dihydropyridazine Product
Paul M. Lahti, and Jerome A. Berson
pp 2677 - 2677; DOI:
10.1021/ja00373a603
PDF
Additions and Corrections - Base Catalysis in a Photochemical Smiles Rearrangement. A Case of General Base Catalysis of a Photoreaction.
Gene G. Wubbels, and Daniel W. Celander
pp 2677 - 2677; DOI:
10.1021/ja00373a604
PDF
Additions and Corrections - Studies on Spin-Trapped Radicals in γ-Irradiated Aqueous Solutions of L-Alanylglycine and L-Alanyl-L-alanine by High-Performance Liquid Chromatography and ESR Spectroscopy
Fumio Moriya, Keisuke Makino, Nobuhiro Suzuki, Souji Rokushika, and Hiroyuki Hatano
pp 2677 - 2677; DOI:
10.1021/ja00373a605
PDF
Additions and Corrections - Nuclear Magnetic Resonance Investigation of the Spontaneous Decarboxylation of 2-Oxalopropionic Acid. 2. Species in Solution.
G. Kubala, and A. E. Martell
pp 2677 - 2677; DOI:
10.1021/ja00373a606
PDF
Book Reviews

pp 2677 - 2682; DOI:
10.1021/ja00373a607
PDF

Issue 10


Permeation of electroactive solutes through ultrathin polymeric films on electrode surfaces
T. Ikeda, R. Schmehl, P. Denisevich, K. Willman, and R. W. Murray
pp 2683 - 2691; DOI:
10.1021/ja00374a001
PDF
Electronic structure of naphtho[1,8-cd:4,5-c'd']bis[1,2,6]thia- and -selenadiazines. Ab initio calculations and photoelectron spectra
J. P. Boutique, J. Riga, J. J. Verbist, J. Delhalle, J. G. Fripiat, J. M. Andre, R. C. Haddon, and M. L. Kaplan
pp 2691 - 2697; DOI:
10.1021/ja00374a002
PDF
Cadmium-113 NMR T1 and nuclear Overhauser enhancement measurements on cadmium cyclohexanediaminetetraacetate
Charles C. Bryden and Charles N. Reilley
pp 2697 - 2699; DOI:
10.1021/ja00374a003
PDF
Electronic structure of organometallic compounds. 18. Electronic structure of bis(pentadienyl)iron. Semiempirical calculations and photoelectron spectra
Michael C. Boehm, Mirjana Eckert-Maksic, Richard D. Ernst, David R. Wilson, and Rolf Gleiter
pp 2699 - 2707; DOI:
10.1021/ja00374a004
PDF
SN2 reactivity of CH3X derivatives. A valence bond approach
Sason S. Shaik and Addy Pross
pp 2708 - 2719; DOI:
10.1021/ja00374a005
PDF
Ab initio studies of the structures of peroxides and peroxy radicals
Raymond A. Bair and William A. Goddard
pp 2719 - 2724; DOI:
10.1021/ja00374a006
PDF
Electron nuclear double resonance (ENDOR) from heme and histidine nitrogens in single crystals of aquometmyoglobin
Charles P. Scholes, Aviva Lapidot, Rita Mascarenhas, Toshiro Inubushi, Roger A. Isaacson, and George Feher
pp 2724 - 2735; DOI:
10.1021/ja00374a007
PDF
Determination of the orientation of adsorbed molecules at solid-liquid interfaces by thin-layer electrochemistry: aromatic compounds at platinum electrodes
Manuel P. Soriaga and Arthur T. Hubbard
pp 2735 - 2742; DOI:
10.1021/ja00374a008
PDF
Determination of the orientation of aromatic molecules adsorbed on platinum electrodes: the influence of iodide, a surface-active anion
Manuel P. Soriaga and Arthur T. Hubbard
pp 2742 - 2747; DOI:
10.1021/ja00374a009
PDF
Paramagnetic carbon-13 shifts induced by the free radical 2,2,6,6-tetramethylpiperidinyl-1-oxy. 1. Simple aromatic and paraffinic hydrocarbons
Zu Wen Qiu, David M. Grant, and Ronald J. Pugmire
pp 2747 - 2753; DOI:
10.1021/ja00374a010
PDF
Ab initio studies of donor-acceptor complexes between water and various atoms
John Bentley
pp 2754 - 2759; DOI:
10.1021/ja00374a011
PDF
Elementary reconstitution of the water splitting light reaction in photosynthesis. 1. Time-resolved fluorescence and electron spin resonance studies of chlorophyll a dihydrate photoreaction with water in nonpolar solutions
F. K. Fong, M. Kusunoki, L. Galloway, T. G. Matthews, F. E. Lytle, A. J. Hoff, and F. A. Brinkman
pp 2759 - 2767; DOI:
10.1021/ja00374a012
PDF
Elementary reconstitution of the water splitting light reaction in photosynthesis. 2. Optical double resonance study of (Chl a.2H2O)n two-photon interactions in nonpolar solutions
A. J. Alfano and F. K. Fong
pp 2767 - 2773; DOI:
10.1021/ja00374a013
PDF
Elementary reconstitution of the water splitting light reaction in photosynthesis. 3. Photooxidative properties of chlorophyll dihydrate on metal as catalyst for water photolysis
Michael S. Showell and Francis K. Fong
pp 2773 - 2781; DOI:
10.1021/ja00374a014
PDF
The relationship between energy additivity and the equivalent group
Joseph R. Murdoch and Douglas E. Magnoli
pp 2782 - 2789; DOI:
10.1021/ja00374a015
PDF
Catecholate and phenolate iron complexes as models for the dioxygenases
Robert H. Heistand, Randall B. Lauffer, Erol Fikrig, and Lawrence Que
pp 2789 - 2796; DOI:
10.1021/ja00374a016
PDF
Self-consistent molecular-orbital methods. 22. Small split-valence basis sets for second-row elements
Mark S. Gordon, J. Stephen Binkley, John A. Pople, William J. Pietro, and Warren J. Hehre
pp 2797 - 2803; DOI:
10.1021/ja00374a017
PDF
Heteroatomic polyanions of the post-transition metals. The synthesis and structure of a compound containing thallium nonastannide(3-) (TlSn93-) and thallium octastannide(3-) (TlSn83-) with a novel structural disorder
Robert C. Burns and John D. Corbett
pp 2804 - 2810; DOI:
10.1021/ja00374a018
PDF
Stepwise reduction of coordinated carbon monoxide
James R. Sweet and William A. G. Graham
pp 2811 - 2815; DOI:
10.1021/ja00374a019
PDF
Synthesis, chemistry, and structure of a new .pi.-arene complex of iron(0), (.eta.6-toluene)(2,2'-bipyridine)iron(0). Structural evidence for extensive .pi. back-bonding to 2,2'-bipyridine
L. J. Radonovich, M. W. Eyring, T. J. Groshens, and K. J. Klabunde
pp 2816 - 2819; DOI:
10.1021/ja00374a020
PDF
Electron-transfer series of MoFe3S4 double-cubane clusters: electronic properties of components and the structure of [(C2H5)4N]5[Mo2Fe6S8(SC6H5)9]
G. Christou, P. K. Mascharak, W. H. Armstrong, G. C. Papaefthymiou, R. B. Frankel, and R. H. Holm
pp 2820 - 2831; DOI:
10.1021/ja00374a021
PDF
Reaction of trimethyl- and triphenylstannate, (CH3)3Sn- and Ph3Sn-, with optically active 2-octyl bromide, chloride, and tosylate
Joseph San Filippo and Joseph Silbermann
pp 2831 - 2836; DOI:
10.1021/ja00374a022
PDF
Synthesis and thermal rearrangement of 7-(1,2-butadien-1-yl)bicyclo[2.2.1]hept-2-ene [7-(3-methylallenyl)norbornene]
James A. Duncan, D. Scott Bohle, Charles A. Blanchard, Mark L. Bosse, Terry W. Noland, Carla M. Ford, Mark A. Powell, Michael C. Sutton, Amy C. Eggleston, and et al.
pp 2837 - 2839; DOI:
10.1021/ja00374a023
PDF
A critical test of the theory of stereoelectronic control
Charles L. Perrin and Gloria Meichia L. Arrhenius
pp 2839 - 2842; DOI:
10.1021/ja00374a024
PDF
Structure and conformation of dihydroaromatic compounds. 1-Alkyl-1,4-dihydrobenzenes, 1-alkyl-1,4-dihydronaphthalenes, and 9-alkyl-9,10-dihydroanthracenes
Douglas J. Raber, Linda E. Hardee, Peter W. Rabideau, and Kenny B. Lipkowitz
pp 2843 - 2847; DOI:
10.1021/ja00374a025
PDF
Oxygen-17 NMR spectral properties of simple phosphate esters and adenine nucleotides
John A. Gerlt, Peter C. Demou, and Shujaath Mehdi
pp 2848 - 2856; DOI:
10.1021/ja00374a026
PDF
Stereochemistry of thermal [1,5] carbon shifts in norcaradienes: complete kinetic analysis of the degenerate thermal isomerization of (+)-2-deuterio-3,7-dimethyl-7-(methoxymethyl)cycloheptatriene
John E. Baldwin and Bruce M. Broline
pp 2857 - 2865; DOI:
10.1021/ja00374a027
PDF
Interconversion of dipoles by the flash vacuum pyrolysis of oxadiazolinones
Albert Padwa, Thomas Caruso, Steven Nahm, and Augusto Rodriguez
pp 2865 - 2871; DOI:
10.1021/ja00374a028
PDF
Photolysis of organopolysilanes. Photochemical behavior of phenylethynyldisilanes
Mitsuo Ishikawa, Hiroshi Sugisawa, Takamasa Fuchikami, Makoto Kumada, Tokio Yamabe, Hiroshi Kawakami, Kenichi Fukui, Yutaka Ueki, and Haruo Shizuka
pp 2872 - 2878; DOI:
10.1021/ja00374a029
PDF
Isomerization of alkane molecular ions
John L. Holmes, Peter C. Burgers, M. Yousuf A. Mollah, and Peder Wolkoff
pp 2879 - 2884; DOI:
10.1021/ja00374a030
PDF
Chemistry of the tert-butyl radical: polar character, .rho. value for reaction with toluenes, and the effect of radical polarity on the ratio of benzylic hydrogen abstraction to addition to aromatic rings
William A. Pryor, Felicia Y. Tang, Robert H. Tang, and Daniel F. Church
pp 2885 - 2891; DOI:
10.1021/ja00374a031
PDF
Carboxylic acid participation in amide hydrolysis. Evidence that separation of a nonbonded complex can be rate determining
Ronald Kluger and Jik Chin
pp 2891 - 2897; DOI:
10.1021/ja00374a032
PDF
Structural studies and chemistry of bacterial capsular polysaccharides. Investigations of phosphodiester-linked capsular polysaccharides isolated from Haemophilus influenzae types a, b, c, and f: NMR spectroscopic identification and chemical modification of end groups and the nature of base-catalyzed hydrolytic depolymerization
William Egan, Rachel Schneerson, Kathleen E. Werner, and Gerald Zon
pp 2898 - 2910; DOI:
10.1021/ja00374a033
PDF
Proton-nuclear spin relaxation and molecular dynamics in the lysozyme-water system
William M. Shirley and Robert G. Bryant
pp 2910 - 2918; DOI:
10.1021/ja00374a034
PDF
Facile synthesis of a pentacoordinated diphosphorane
Herbert W. Roesky, D. Amirzadeh-Asl, and William S. Sheldrick
pp 2919 - 2920; DOI:
10.1021/ja00374a035
PDF
Models for asymmetric [2+2] cycloadditions
C. Houge, A. M. Frisque-Hesbain, A. Mockel, L. Ghosez, J. P. Declercq, G. Germain, and M. Van Meerssche
pp 2920 - 2921; DOI:
10.1021/ja00374a036
PDF
Intersystem crossing in styrene and styrene derivatives
Roland Bonneau
pp 2921 - 2923; DOI:
10.1021/ja00374a037
PDF
Preparation and reactions of 1-(phenylthio)-2-(trimethylsilyloxy)-1,3-butadienes. A one-pot synthesis of sulfur-substituted 7-hydroxybicyclo[2.2.1]heptanones - coupling of the Diels-Alder reaction with the aldol process
Alan P. Kozikowski and Edward M. Huie
pp 2923 - 2925; DOI:
10.1021/ja00374a038
PDF
Study of plasma-initiated polymerization. 5. Plasma-exposed reduction of solid and solvated viologens
Yoshihito Osada and Yu. Iriyama
pp 2925 - 2926; DOI:
10.1021/ja00374a039
PDF
Thermal rearrangements of encumbered methylenecyclobutanes. 1. 6-Methylenebicyclo[3.2.0]heptane
Richard W. Holder and Phyllis A. Leber
pp 2926 - 2927; DOI:
10.1021/ja00374a040
PDF
Photochemistry of ketones in solution. 64. Reactivity of n,.pi.* and .pi.,.pi.* triplet excited states of 4a-methyl-4,4a,9,10-tetrahydro-2(3H)-phenanthrone
Chung B. Chan and David I. Schuster
pp 2928 - 2929; DOI:
10.1021/ja00374a041
PDF
Methylenoxonium radical cation (CH2OH2+.bul.): a surprisingly stable isomer of the methanol radical cation
Willem J. Bouma, Ross H. Nobes, and Leo Radom
pp 2929 - 2930; DOI:
10.1021/ja00374a042
PDF
Experimental evidence for the existence of a stable isomer of CH3OH+.cntdot.: the methylenoxonium radical cation, CH2OH2+.cntdot.
Willem J. Bouma, John K. MacLeod, and Leo Radom
pp 2930 - 2931; DOI:
10.1021/ja00374a043
PDF
The radical cation [CH2OH2]+.cntdot. and related stable gas-phase ion-dipole complexes
J. L. Holmes, F. P. Lossing, J. K. Terlouw, and P. C. Burgers
pp 2931 - 2932; DOI:
10.1021/ja00374a044
PDF
Photoresponsive complexation of metal cations with an azobenzene-crown-azobenzene bridge immobilized in polymer supports
Seiji Shinkai, Hidefumi Kinda, and Osamu Manabe
pp 2933 - 2934; DOI:
10.1021/ja00374a045
PDF
Generation and rearrangement of the 2-oxobicyclo[2.2.1]heptane-6,7-diyl diradical via nitrogen extrusion from the azoalkane 2,3-diazatricyclo[4.3.0.04,9]non-2-en-8-one
Waldemar Adam, Ottorino De Lucchi, and Karlheinz Hill
pp 2934 - 2936; DOI:
10.1021/ja00374a046
PDF
Organoselenium chemistry. Characterization of reactive intermediates in the selenoxide syn elimination: selenenic acids and selenolseleninate esters
Hans J. Reich, Carl A. Hoeger, and William W. Willis
pp 2936 - 2937; DOI:
10.1021/ja00374a047
PDF
Remarkably enhanced charge-transfer interaction in stable single-compartment vesicles
Yukito Murakami, Yasuhiro Aoyama, Junichi Kikuchi, Koji Nishida, and Akio Nakano
pp 2937 - 2940; DOI:
10.1021/ja00374a048
PDF
Complexity in the reductive reaction of cobalt(II) chloride in the presence of phosphites. Isolation of stable, noninterconvertible Co[P(OCH3)3]4 and Co2[P(OCH3)3]8 molecules
E. L. Muetterties, J. R. Bleeke, Z. Y. Yang, and V. W. Day
pp 2940 - 2942; DOI:
10.1021/ja00374a049
PDF
Stereochemical consequence of the interaction of alkylaluminums with titanacyclobutanes and its relationship to the olefin metathesis reaction
Kevin C. Ott, J. Bosco Lee, and Robert H. Grubbs
pp 2942 - 2944; DOI:
10.1021/ja00374a050
PDF
Mechanism of the photochemical disproportionation reactions of (.eta.5-C5H5)2M2(CO)6 (M = Cr, Mo, W)
Albert E. Stiegman and David R. Tyler
pp 2944 - 2945; DOI:
10.1021/ja00374a051
PDF
Stereoselective total synthesis of 1.alpha.,25-dihydroxycholecalciferol
Enrico G. Baggiolini, Jerome A. Iacobelli, Bernard M. Hennessy, and Milan R. Uskokovic
pp 2945 - 2948; DOI:
10.1021/ja00374a052
PDF
Iodine-127-plasma desorption mass spectrometry of insulin
P. Haakansson, I. Kamensky, B. Sundqvist, J. Fohlman, P. Peterson, C. J. McNeal, and R. D. Macfarlane
pp 2948 - 2949; DOI:
10.1021/ja00374a053
PDF
Book Reviews

pp 2949 - 2950; DOI:
10.1021/ja00374a600
PDF

Issue 11


Hydrogenation of nitroxides on silica gel-supported platinum
Tadashi Kawai, Milad Jarjoui, and Robert L. Burwell
pp 2951 - 2956; DOI:
10.1021/ja00375a001
PDF
A theoretical study of the acetaldehyde-derived radical
Earl S. Huyser, David Feller, Weston T. Borden, and Ernest R. Davidson
pp 2956 - 2959; DOI:
10.1021/ja00375a002
PDF
Stereochemistry in trivalent nitrogen compounds. 38. Theoretical investigation of the hyperconjugation effect on nitrogen inversion barriers in aziridines
Daniel Kost and Morton Raban
pp 2960 - 2967; DOI:
10.1021/ja00375a003
PDF
An electrochemical investigation of the effect of macrocycle ring size on the binding of di- and trivalent lanthanide cations by 12-crown-4, 15-crown-5, 4-tert-butylbenzo-15-crown-5, and dibenzo-30-crown-10 in propylene carbonate
Jean Massaux and Jean F. Desreux
pp 2967 - 2972; DOI:
10.1021/ja00375a004
PDF
Liquid-crystalline solvents as mechanistic probes. 8. Dynamic quenching of pyrene fluorescence by pyrene in the liquid crystalline and isotropic phases of a cholesteric solvent
Valerie C. Anderson, Bruce B. Craig, and Richard G. Weiss
pp 2972 - 2977; DOI:
10.1021/ja00375a005
PDF
Dynamics of interfacial electron-transfer processes in colloidal semiconductor systems
Duonghong Dung, Jeremy Ramsden, and Michael Graetzel
pp 2977 - 2985; DOI:
10.1021/ja00375a006
PDF
Microscopic environment of poly(styrenesulfonate) macroanions. Emission and absorption spectra, lifetime, and depolarization measurements of a cationic fluorescence probe under high pressure
Nicholas J. Turro and Tsuneo Okubo
pp 2985 - 2988; DOI:
10.1021/ja00375a007
PDF
On the connection between the photochemistry and the Jahn-Teller effect of the excited doublets in octahedral chromium(III) complexes
A. Ceulemans, D. Beyens, and L. G. Vanquickenborne
pp 2988 - 2993; DOI:
10.1021/ja00375a008
PDF
Structure of glycolic acid determined by microwave spectroscopy
C. E. Blom and A. Bauder
pp 2993 - 2996; DOI:
10.1021/ja00375a009
PDF
Visible light induced water cleavage in colloidal solutions of chromium-doped titanium dioxide particles
Enrico Borgarello, John Kiwi, Michael Graetzel, Ezio Pelizzetti, and Mario Visca
pp 2996 - 3002; DOI:
10.1021/ja00375a010
PDF
Ground and excited state conformational differences between diastereomeric dipeptides
Chieu D. Tran, Godfrey S. Beddard, Rose McConnell, Charles F. Hoyng, and Janos H. Fendler
pp 3002 - 3007; DOI:
10.1021/ja00375a011
PDF
Sign determination of electron-spin distributions in iminoxy radical analogs
Graham R. Underwood and Karam El Bayoumy
pp 3007 - 3013; DOI:
10.1021/ja00375a012
PDF
Time lags and V-V' steady states in the infrared laser induced decomposition of chlorodifluoromethane and chlorodifluoromethane-d1 under collisional conditions
Ernest Grunwald, Shu Huei Liu, and Charles M. Lonzetta
pp 3014 - 3021; DOI:
10.1021/ja00375a013
PDF
A valence bond effective Hamiltonian for neutral states of .pi. systems. 1. Method
J. P. Malrieu and D. Maynau
pp 3021 - 3029; DOI:
10.1021/ja00375a014
PDF
A valence bond effective Hamiltonian for the neutral states of .pi. systems. 2. Results
Daniel Maynau and Jean Paul Malrieu
pp 3029 - 3034; DOI:
10.1021/ja00375a015
PDF
Electron-transfer catalysis. Radical chain mechanism for the ligand substitution of metal carbonyls
J. W. Hershberger, R. J. Klingler, and J. K. Kochi
pp 3034 - 3043; DOI:
10.1021/ja00375a016
PDF
Matrix infrared spectrum of the ammonia-hydrogen fluoride hydrogen-bonded complex
Gary Johnson and Lester Andrews
pp 3043 - 3047; DOI:
10.1021/ja00375a017
PDF
Hexacyclen complexes of inorganic anions: bonding forces, structure, and selectivity
Joanne Cullinane, Robert I. Gelb, T. N. Margulis, and Leverett J. Zompa
pp 3048 - 3053; DOI:
10.1021/ja00375a018
PDF
Experimental analysis of the antibonding trimetal character of the HOMO in the paramagnetic Fischer-Palm Ni3(.eta.5-C5H5)3(.mu.3-CO)2 cluster: synthesis and stereochemical characterization of the electronically equivalent [(.eta.5-C5Me5)CoNi2(.eta.5-C5H5)2(.mu.3-CO)2]- monoanion and neutral Ni3(.eta.5-C5Me5)3(.mu.3-CO)2 analog and of the [Ni3(.eta.5-C5H5)3(.mu.3-CO)2]- monoanion
Joseph J. Maj, A. David Rae, and Lawrence F. Dahl
pp 3054 - 3063; DOI:
10.1021/ja00375a019
PDF
Intramolecular electron transfer from pentacyanoferrate(II) to pentaamminecobalt(III): linkage isomers of 3- and 4-cyanopyridine as bridging ligands
Alek P. Szecsy and Albert Haim
pp 3063 - 3069; DOI:
10.1021/ja00375a020
PDF
X-ray structures of two unexpected complexes isolated during carbonyl substitutions by phosphine ligands in dinuclear bridged d8 metal complexes
Philippe Kalck, Jean Jacques Bonnet, and Rene Poilblanc
pp 3069 - 3077; DOI:
10.1021/ja00375a021
PDF
Preparation of organoimido and .mu.-dinitrogen complexes of tantalum and niobium from neopentylidene complexes
Scott M. Rocklage and Richard R. Schrock
pp 3077 - 3081; DOI:
10.1021/ja00375a022
PDF
Binuclear tantalum hydride complexes
Patricia A. Belmonte, Richard R. Schrock, and Cynthia S. Day
pp 3082 - 3089; DOI:
10.1021/ja00375a023
PDF
Synthesis and crystal structure of an analog of 2-(.alpha.-lactyl)thiamin, racemic methyl 2-hydroxy-2-(2-thiamin)ethylphosphonate chloride trihydrate. A conformation for a least-motion, maximum-overlap mechanism for thiamin catalysis
August Turano, William Furey, James Pletcher, Martin Sax, David Pike, and Ronald Kluger
pp 3089 - 3095; DOI:
10.1021/ja00375a024
PDF
Microbial iron chelators: total synthesis of aerobactin and its constituent amino acid, N6-acetyl-N6-hydroxylysine
Peter J. Maurer and Marvin J. Miller
pp 3096 - 3101; DOI:
10.1021/ja00375a025
PDF
Guanosine 5'-monophosphate-catalyzed hydrolysis of diastereomeric benzo[a]pyrene-7,8-diol 9,10-epoxides
Satish C. Gupta, Terese M. Pohl, Steven L. Friedman, Dale L. Whalen, H. Yagi, and Donald M. Jerina
pp 3101 - 3104; DOI:
10.1021/ja00375a026
PDF
Reagents for organic synthesis. Tin-assisted sulfuration: a highly potent new method for the conversion of carbonyl units into their corresponding thiocarbonyl analogs
K. Steliou and Mohamed Mrani
pp 3104 - 3106; DOI:
10.1021/ja00375a027
PDF
Carbon-phosphorus heterocycles. Synthesis of substituted 1,1'-(.alpha.,.omega.-alkanediyl)bis(1,2,3,4-tetrahydrophosphinolinium) salts. A single-crystal x-ray diffraction analysis of meso-1,1'-(1,2-ethanediyl)bis(1,2,3,4-tetrahydro-4,4-dimethyl-1-phenylphosphinolinium) diperchlorate
Narayanasamy Gurusamy, K. Darrell Berlin, Dick Van der Helm, and M. Bilayet Hossain
pp 3107 - 3114; DOI:
10.1021/ja00375a028
PDF
Carbon-phosphorus heterocycles. Synthesis, separation and resolution of stereoisomers of 1,1'-(1,2-ethanediyl)bis(1,2,3,4-tetrahydro-4,4-dimethyl-1-phenylphosphinolinium) diperchlorate. The use of phosphorus-31 NMR analysis to monitor the resolution
Narayanasamy Gurusamy and K. Darrell Berlin
pp 3114 - 3119; DOI:
10.1021/ja00375a029
PDF
Flash vacuum pyrolysis studies. 9. Photoelectron spectra and molecular properties. 101. Synthesis and thermal decomposition of 1,3-dithietane and its S-oxides
E. Block, E. R. Corey, R. E. Penn, T. L. Renken, P. F. Sherwin, H. Bock, T. Hirabayashi, S. Mohmand, and B. Solouki
pp 3119 - 3130; DOI:
10.1021/ja00375a030
PDF
The efficiency of benzil-sensitized photoepoxidation: a correction
Paul D. Bartlett, Antonius A. M. Roof, and Nobujiro Shimizu
pp 3130 - 3131; DOI:
10.1021/ja00375a031
PDF
Reactivities of norbornene-type double bonds in propellane derivatives and their precursors; furan as a diene
Paul D. Bartlett, Gerald L. Combs, Ai Xuan Thi Le, William H. Watson, Jean Galloy, and Michio Kimura
pp 3131 - 3138; DOI:
10.1021/ja00375a032
PDF
o-Carboranylcarbene and m-carboranylcarbene
Sarangan L. Chari, Sheau Hwa Chiang, and Maitland Jones
pp 3138 - 3145; DOI:
10.1021/ja00375a033
PDF
Alkene reactivities in trifluoroacetic acid. A comparison of norbornene and protoadamantene in trifluoroacetic acid and aqueous acid
Annette D. Allen and Thomas T. Tidwell
pp 3145 - 3149; DOI:
10.1021/ja00375a034
PDF
Pressure effects on the rates of aromatization of hexamethyl(dewar benzene) and dewar benzene. Volume as a factor in crowded molecules
W. J. Le Noble, K. R. Brower, C. Brower, and Shoumo Chang
pp 3150 - 3152; DOI:
10.1021/ja00375a035
PDF
The effect of pressure on the rate of alkaline fading of Malachite Green. A reinvestigation
W. J. Le Noble, Elzbita Gebicka, and Sushil Srivastava
pp 3153 - 3156; DOI:
10.1021/ja00375a036
PDF
Carbene in a rigid matrix. XII. Temperature and substituent effects on regioselectivity in the insertion of arylcarbene into alcohols
Hideo Tomioka, Shinji Suzuki, and Yasuji Izawa
pp 3156 - 3162; DOI:
10.1021/ja00375a037
PDF
Studies of the tautomerism of purine and the protonation of purine, and its 7- and 9-methyl derivatives, by nitrogen-15 nuclear magnetic resonance spectroscopy
Nina C. Gonnella and John D. Roberts
pp 3162 - 3164; DOI:
10.1021/ja00375a038
PDF
Stereospecific umpolung .alpha.' substitution of ketones via reactions of organocuprates with enol ethers of .alpha.,.beta.-epoxycyclohexanones
J. P. Marino and Juan Carlos Jaen
pp 3165 - 3172; DOI:
10.1021/ja00375a039
PDF
Motion at the active site of tosylchymotrypsin
M. E. Ando, J. T. Gerig, and E. F. Weigand
pp 3172 - 3178; DOI:
10.1021/ja00375a040
PDF
Resonance Raman and 500-MHz proton NMR studies of tyrosine modification in hen egg white lysozyme
Geraldine E. Izzo, Frank Jordan, and Richard Mendelsohn
pp 3178 - 3182; DOI:
10.1021/ja00375a041
PDF
Macromonocyclic polyamines as biological polyanion complexons. 2. Ion-pair association with phosphate and nucleotides
Eiichi Kimura, Mutsuo Kodama, and Takashi Yatsunami
pp 3182 - 3187; DOI:
10.1021/ja00375a042
PDF
Carbonic anhydrase models. 4. [Tris[(4,5-dimethyl-2-imidazolyl)methyl]phosphine oxide]cobalt(2+), a small-molecule mimic of the spectroscopic properties of cobalt(II) carbonic anhydrase
R. S. Brown, D. Salmon, N. J. Curtis, and S. Kusuma
pp 3188 - 3194; DOI:
10.1021/ja00375a043
PDF
Electron delocalization in mixed-valence molybdenum polyanions
C. Sanchez, J. Livage, J. P. Launay, M. Fournier, and Y. Jeannin
pp 3194 - 3202; DOI:
10.1021/ja00375a044
PDF
Methylase models: studies on general-base vs. nucleophilic catalysis in the intramolecular alkylation of phenols
Jay O. Knipe, Peter J. Vasquez, and James K. Coward
pp 3202 - 3209; DOI:
10.1021/ja00375a045
PDF
Molecular structures of nucleosides and nucleotides. 2. Orthogonal coordinates for standard nucleic acid base residues
Robin Taylor and Olga Kennard
pp 3209 - 3212; DOI:
10.1021/ja00375a046
PDF
Studies related to antitumor antibiotics. 28. Structure and function of the antitumor antibiotic carzinophillin A: the first natural intercalative bisalkylator
J. William Lown and Christopher Hanstock
pp 3213 - 3214; DOI:
10.1021/ja00375a047
PDF
Synthesis and binding studies of a photoaffinity label for bovine rhodopsin
Ranjan Sen, John D. Carriker, Valeria Balogh-Nair, and Koji Nakanishi
pp 3214 - 3216; DOI:
10.1021/ja00375a048
PDF
Stereocontrol in the intramolecular Diels-Alder reaction. 3. A potentially general method for the synthesis of cis-hydrindenes by use of (Z)-diene units
R. K. Boeckman and Thomas R. Alessi
pp 3216 - 3217; DOI:
10.1021/ja00375a049
PDF
Biosynthesis of sulfur compounds. Elucidation of the stereochemistry of the conversion of 3-(methylthio)propylglucosinolate into allylglucosinolate (sinigrin)
Ronald J. Parry and M. V. Naidu
pp 3217 - 3219; DOI:
10.1021/ja00375a050
PDF
Total synthesis of the first molecular Moebius strip
David M. Walba, Rodney M. Richards, and R. Curtis Haltiwanger
pp 3219 - 3221; DOI:
10.1021/ja00375a051
PDF
Picosecond study of the photodissociation of a model hemoprotein compared to hemoglobin
J. A. Hutchinson, T. G. Traylor, and L. J. Noe
pp 3221 - 3223; DOI:
10.1021/ja00375a052
PDF
Oxygen chiral phosphodiesters. 7. Stereochemical course of a reaction catalyzed by staphylococcal nuclease
Shujaath Mehdi and John A. Gerlt
pp 3223 - 3225; DOI:
10.1021/ja00375a053
PDF
Nucleophilic attack on olefins initiated by dimethyl(methylthio)sulfonium fluoroborate (DMTSF). Azasulfenylation
Barry M. Trost and Tohru Shibata
pp 3225 - 3228; DOI:
10.1021/ja00375a054
PDF
Nucleophilic attack on olefins initiated by dimethylmethylthiosulfonium fluoroborate (DMTSF). Cyanosulfenylation and oxy- and oxosulfenylation
Barry M. Trost, Tohru Shibata, and Steven J. Martin
pp 3228 - 3230; DOI:
10.1021/ja00375a055
PDF
Thioammonium ions. Azasulfenylation reactions
Marjorie C. Caserio and Jhong K. Kim
pp 3231 - 3233; DOI:
10.1021/ja00375a056
PDF
A new .beta.-lactam synthesis
Alan J. Biloski, Richard D. Wood, and Bruce Ganem
pp 3233 - 3235; DOI:
10.1021/ja00375a057
PDF
Utilization of enolpyruvate by the carboxybiotin form of transcarboxylase: evidence for a nonconcerted mechanism
Donald J. Kuo and Irwin A. Rose
pp 3235 - 3236; DOI:
10.1021/ja00375a058
PDF
Evidence for two types of binding sites in cadmium metallothionein determined by perturbed angular correlation of .gamma.-rays
Milan Vasak and Rogert Bauer
pp 3236 - 3238; DOI:
10.1021/ja00375a059
PDF
Reactions of excited triplet diphenylcarbene studied with picosecond lasers
Y. Wang, E. V. Sitzmann, F. Novak, C. Dupuy, and K. B. Eisenthal
pp 3238 - 3239; DOI:
10.1021/ja00375a060
PDF
Reaction of stannocene and plumbocene with phosphenium ions: oxidative addition of carbon-hydrogen bonds to low-coordination number main group species
A. H. Cowley, R. A. Kemp, and C. A. Stewart
pp 3239 - 3240; DOI:
10.1021/ja00375a061
PDF
Advantages of FT NMR for measuring long-range nitrogen-14 hyperfine couplings and its application to 2,2-diphenyl-1-picrylhydrazyl (DPPH)
N. S. Dalal, J. A. Ripmeester, and A. H. Reddoch
pp 3241 - 3242; DOI:
10.1021/ja00375a062
PDF
Isomeric .sigma. and .pi. radicals from carboxylic acids and amides
Michael J. S. Dewar, Ali H. Pakiari, and Adriana B. Pierini
pp 3242 - 3244; DOI:
10.1021/ja00375a063
PDF
Tritium migration in tritiated anisole
Michael J. S. Dewar and Charles H. Reynolds
pp 3244 - 3246; DOI:
10.1021/ja00375a064
PDF
Solid-state carbon-13 NMR characterization of the bonding mode of the thiocyanate ion in copper(I) complexes
N. Zumbulyadis and H. J. Gysling
pp 3246 - 3247; DOI:
10.1021/ja00375a065
PDF
Book Reviews

pp 3248 - 3248; DOI:
10.1021/ja00375a600
PDF

Issue 12


A molecular-mechanics study of 18-crown-6 and its alkali complexes: an analysis of structural flexibility, ligand specificity, and the macrocyclic effect
Georges Wipff, Paul Weiner, and Peter Kollman
pp 3249 - 3258; DOI:
10.1021/ja00376a001
PDF
Complete theoretical structures for the classical and nonclassical forms of the 2-norbornyl cation and for edge-protonated nortricyclene
John D. Goddard, Yoshihiro Osamura, and Henry F. Schaefer
pp 3258 - 3262; DOI:
10.1021/ja00376a002
PDF
Isotopic mapping of transition-state structural features associated with enzymic catalysis of methyl transfer
James Rodgers, Douglas A. Femec, and Richard L. Schowen
pp 3263 - 3268; DOI:
10.1021/ja00376a003
PDF
Electronic structure calculations on active site models for 4-Fe,4-S iron-sulfur proteins
Arie Aizman and David A. Case
pp 3269 - 3279; DOI:
10.1021/ja00376a004
PDF
Energetics and mechanisms for reactions involving nitrosamide, hydroxydiazenes, and diimide N-oxides
Carla J. Casewit and William A. Goddard
pp 3280 - 3287; DOI:
10.1021/ja00376a005
PDF
Hydrocarbon oxidation by high-valent Group VI oxides
Anthony K. Rappe and William A. Goddard
pp 3287 - 3294; DOI:
10.1021/ja00376a006
PDF
Symmetry and tunneling in the intramolecular proton exchange in naphthazarin, methylnaphthazarin, and dimethylnaphthazarins
Jose R. De la Vega, Jan H. Busch, J. Herman Schauble, Kathryn L. Kunze, and Brian E. Haggert
pp 3295 - 3299; DOI:
10.1021/ja00376a007
PDF
Surface tension of a ternary polymeric solution
J. D. Pandey and N. Pant
pp 3299 - 3302; DOI:
10.1021/ja00376a008
PDF
Interproton coupling over five bonds 5J(H-C.alpha.-C(O)-N-C.alpha.-H) in the peptide moiety: the importance of specific association effects
M. Barfield, F. A. Al-Obeidi, V. J. Hruby, and S. R. Walter
pp 3302 - 3306; DOI:
10.1021/ja00376a009
PDF
Self-structured guanosine 5'-monophosphate. A carbon-13 and proton magnetic resonance study
Cherie L. Fisk, Edwin D. Becker, H. Todd Miles, and T. J. Pinnavaia
pp 3307 - 3314; DOI:
10.1021/ja00376a010
PDF
Design of an antenna system for the collection of singlet excitation energy. Exciton diffusion among concentrated 9,10-diphenylanthracene centers in polystyrene
Clifford L. Renschler and Larry R. Faulkner
pp 3315 - 3320; DOI:
10.1021/ja00376a011
PDF
Diradicalar or ionic twisted excited states in the singlet cis-trans isomerization of polyenes?
Ignacio Nebot-Gil and Jean Paul Malrieu
pp 3320 - 3325; DOI:
10.1021/ja00376a012
PDF
Semiconductor interface characterization in photoelectrochemical solar cells: the p-indium phosphide (111)A face
H. J. Lewerenz, D. E. Aspnes, B. Miller, D. L. Malm, and A. Heller
pp 3325 - 3329; DOI:
10.1021/ja00376a013
PDF
Vibrational circular dichroism in amino acids and peptides. 4. Vibrational analysis, assignments, and solution-phase Raman spectra of deuterated isotopomers of alanine
Max Diem, Prasad L. Polavarapu, Mohammedreza Oboodi, and Laurence A. Nafie
pp 3329 - 3336; DOI:
10.1021/ja00376a014
PDF
Vibrational circular dichroism in amino acids and peptides. 5. Carbon-hydrogen, stretching vibrational circular dichroism and fixed partial charge calculations for deuterated isotopomers of alanine
Brij B. Lal, Max Diem, Prasad L. Polavarapu, Mohammedreza Oboodi, Teresa B. Freedman, and Laurence A. Nafie
pp 3336 - 3342; DOI:
10.1021/ja00376a015
PDF
Vibrational circular dichroism in amino acids and peptides. 6. Localized molecular orbital calculations of the carbon-hydrogen stretching vibrational circular dichroism in deuterated isotopomers of alanine
Teresa B. Freedman, Max Diem, Prasad L. Polavarapu, and Laurence A. Nafie
pp 3343 - 3349; DOI:
10.1021/ja00376a016
PDF
Mass spectrometry of nucleic acid constituents. Electron ionization spectra of selectively labeled adenines
Satinder Sethi, S. P. Gupta, E. E. Jenkins, C. W. Whitehead, Leroy B. Townsend, and James A. McCloskey
pp 3349 - 3353; DOI:
10.1021/ja00376a017
PDF
Aliphatic semidiones. 42. The cis-trans equilibriums in alphatic semidiones
Glen A. Russell and C. E. Osuch
pp 3353 - 3358; DOI:
10.1021/ja00376a018
PDF
Conformational analysis and dipole moments of tetra-O-methyl-(+)-catechin and tetra-O-methyl-(-)-epicatechin
Wayne L. Mattice, Fred L. Tobiason, Karl Houglum, and Armen Shanafelt
pp 3359 - 3362; DOI:
10.1021/ja00376a019
PDF
Kinetics and mechanism of the forward and reverse reactions between N,N'-dimethyl-4,4'-bipyridinium and hexacyanoferrate(II)
Luiz Antonio Andrade de Oliveira and Albert Haim
pp 3363 - 3366; DOI:
10.1021/ja00376a020
PDF
Preparation and molecular stereochemistry of six-coordinate (isothiocyanato)(pyridine)(porphinato)iron(III) complexes. (Isothiocyanato)(meso-tetraphenylporphinato)(pyridine)iron(III), a low-spin complex with a nonlinear FeNCS group, and (isothiocyanato)(octaethylporphinato)(pyridine)iron(III), a high-spin complex with nonequivalent axial ligands
W. Robert Scheidt, Young Ja Lee, David K. Geiger, Karen Taylor, and Keiichiro Hatano
pp 3367 - 3374; DOI:
10.1021/ja00376a021
PDF
Adduct-mediated photochemistry. Evidence for excited-state reordering in (acetophenone)tricarbonylchromium(O) upon adduct formation with tris(6,6,7,7,8,8,8-heptafluoro-2,2-dimethyl-3,5-octanedionato)europium(III)
Rodney Schreiner and Arthur B. Ellis
pp 3374 - 3381; DOI:
10.1021/ja00376a022
PDF
A new oxygen-sulfur anion: preparation and structure of potassium .mu.-(thiosulfito-(S,S))-decacyanodicobaltate(III)
Frank R. Fronczek, Richard E. Marsh, and William P. Schaefer
pp 3382 - 3385; DOI:
10.1021/ja00376a023
PDF
Resonance Raman and infrared spectra of molecular oxygen adducts of N,N'-ethylenebis(2,2-diacetylethylideneaminato)cobalt(II)
K. Nakamoto, Y. Nonaka, Ishiguro, M. W. Urban, M. Suzuki, M. Kozuka, Y. Nishida, and S. Kida
pp 3386 - 3391; DOI:
10.1021/ja00376a024
PDF
Mechanism of nitrosyl transfer. Dissociation of nitric oxide from cobalt nitrosyls
Michael P. Doyle, Ruth A. Pickering, Russell L. Dykstra, and Bruce R. Cook
pp 3392 - 3397; DOI:
10.1021/ja00376a025
PDF
Crystal and molecular structure of cyclic adenosine 3',5'-monophosphate sodium salt, monoclinic form
Kottayil I. Varughese, Chia T. Lu, and Gopinath Kartha
pp 3398 - 3401; DOI:
10.1021/ja00376a026
PDF
Crystal and molecular structure of the quinoxaline antibiotic analog TANDEM (des-N-tetramethyltriostin A)
M. B. Hossain, Dick Van der Helm, Richard K. Olsen, Peter G. Jones, George M. Sheldrick, Ernst Egert, Olga Kennard, Michael J. Waring, and M. A. Viswamitra
pp 3401 - 3408; DOI:
10.1021/ja00376a027
PDF
Synthesis and stereochemical analysis of the [Fe4(NO)4(.mu.3-S)4]n series (n = 0, -1) which possesses a cubanelike Fe4S4 core: direct evidence for the antibonding tetrametal character of the unpaired electron upon a one-electron reduction of a completely bonding tetrahedral metal cluster
Cynthia Ting-Wah Chu, Frederick Yip-Kwai Lo, and Lawrence F. Dahl
pp 3409 - 3422; DOI:
10.1021/ja00376a028
PDF
Photopolymerization in chiral crystals. 4. Engineering of chiral crystals for asymmetric (2.pi. + 2.pi.) photopolymerization. Execution of an "absolute" asymmetric synthesis with quantitative enantiomeric yield
Lia Addadi, J. Van Mil, and Meir Lahav
pp 3422 - 3429; DOI:
10.1021/ja00376a029
PDF
Useful impurities for optical resolution. 4. Attempted amplification of optical activity by crystallization of chiral crystals of photopolymerizing dienes in the presence of their topochemical products
J. Van Mil, Lia Addadi, E. Gati, and Meir Lahav
pp 3429 - 3434; DOI:
10.1021/ja00376a030
PDF
Effects of structure on rates and quantum yields in photoreduction of fluorenone by amines. Catalysis and inhibition by thiols
Paul G. Stone and Saul G. Cohen
pp 3435 - 3440; DOI:
10.1021/ja00376a031
PDF
Kinetics of the pyridoxal-catalyzed dealdolation and .beta. elimination of some aromatic .beta.-hydroxy .alpha.-amino acids
Joseph A. Marcello and Arthur E. Martell
pp 3441 - 3447; DOI:
10.1021/ja00376a032
PDF
Photoelectron spectroscopy of N-aryl cyclic amines. Variable conformations and relationships to gas- and solution-phase basicities
Melvin D. Rozeboom, K. N. Houk, Scott Searles, and S. Ebrahim Seyedrezai
pp 3448 - 3453; DOI:
10.1021/ja00376a033
PDF
Stereochemistry of the antitumor agent 4,4'-(1,2-propanediyl)bis(4-piperazine-2,6-dione): crystal and molecular structures of the racemate (ICRF-159) and a soluble enantiomer (ICRF-187)
Andrew Hempel, Norman Camerman, and Arthur Camerman
pp 3453 - 3456; DOI:
10.1021/ja00376a034
PDF
Stereochemistry of conformationally restricted analogs of the antitumor agent ICRF-159: crystal and molecular structures of cis- and trans-cyclopropylbis(dioxopiperazine)
Andrew Hempel, Norman Camerman, and Arthur Camerman
pp 3456 - 3458; DOI:
10.1021/ja00376a035
PDF
When is intramolecular proton transfer between carbon and nitrogen or oxygen observable?
Claude F. Bernasconi, Sharon A. Hibdon, and Susan E. McMurry
pp 3459 - 3471; DOI:
10.1021/ja00376a036
PDF
SN2 substitution with inversion at a cyclopropyl carbon atom: formation of 9-oxatetracyclo[6.2.1.01,6.06,10]undecane
L. A. M. Turkenburg, W. H. De Wolf, F. Bickelhaupt, C. H. Stam, and M. Konijn
pp 3471 - 3476; DOI:
10.1021/ja00376a037
PDF
Synthesis of chiral [18O]phosphorothioate analogs of adenine nucleotides
John P. Richard and Perry A. Frey
pp 3476 - 3481; DOI:
10.1021/ja00376a038
PDF
The Barbier synthesis: a one-slip Grignard reaction?
Gerard Molle and Pierre Bauer
pp 3481 - 3487; DOI:
10.1021/ja00376a039
PDF
Methylal hydrolysis: reversal reactions under dilatometric conditions and invalidity of the dilatometric method
W. M. Schubert and Darrell W. Brownawell
pp 3487 - 3490; DOI:
10.1021/ja00376a040
PDF
Cation-anion combination reactions. 21. Reactions of thiolate ions, cyanide ion, and amines with cations and carbonyl compounds in dimethyl sulfoxide solution
Calvin D. Ritchie, J. E. VanVerth, and P. O. I. Virtanen
pp 3491 - 3497; DOI:
10.1021/ja00376a041
PDF
Prostaglandin endoperoxides. 12. Carboxylate catalysis and the effects of proton donors on the decomposition of 2,3-dioxabicyclo[2.2.1]heptane
Michael G. Zagorski and Robert G. Salomon
pp 3498 - 3503; DOI:
10.1021/ja00376a042
PDF
Arylation and vinylation of iron porphyrins. Double electrochemical induction of a nucleophilic substitution
Doris Lexa and Jean Michel Saveant
pp 3503 - 3504; DOI:
10.1021/ja00376a043
PDF
Chemiluminescence from a phenoxide-substituted 1,2-dioxetane: a model for firefly bioluminescence
A. Paul Schaap and Steven D. Gagnon
pp 3504 - 3506; DOI:
10.1021/ja00376a044
PDF
Stereochemistry of casbene biosynthesis
William J. Guilford and Robert M. Coates
pp 3506 - 3508; DOI:
10.1021/ja00376a045
PDF
Stereoselective induction of biomimetic polyene cyclizations by remote chiral centers. Effect of a pro-C-7 substituent in a substrate leading to steroidal products
William S. Johnson, Daniel Berner, Donald J. Dumas, Pieter J. R. Nederlof, and John Welch
pp 3508 - 3510; DOI:
10.1021/ja00376a046
PDF
Total synthesis of dl-spironolactone and dl-19-norspironolactone by biomimetic polyene cyclization methodology
William S. Johnson, Donald J. Dumas, and Daniel Berner
pp 3510 - 3511; DOI:
10.1021/ja00376a047
PDF
Total synthesis of (-)-domoic acid. A revision of the original structure
Yasufumi Ohfune and Masako Tomita
pp 3511 - 3513; DOI:
10.1021/ja00376a048
PDF
Calculated triplet state energies of carbonylheme complexes: relevance to photodissociation and postulated paramagnetic component
Ahmad Waleh and Gilda H. Loew
pp 3513 - 3515; DOI:
10.1021/ja00376a049
PDF
Synthesis of saccharides and related polyhydroxylated natural products. 3. Efficient conversion of 2,3-erythro-aldoses to 2,3-threo-aldoses
Albert W. M. Lee, Victor S. Martin, Satoru Masamune, K. Barry Sharpless, and Frederick J. Walker
pp 3515 - 3516; DOI:
10.1021/ja00376a050
PDF
Planar cis-[10]annulene and azulene revisited
Robert C. Haddon and Krishnan Raghavachari
pp 3516 - 3518; DOI:
10.1021/ja00376a051
PDF
Interconversions among the C3H4 hydrocarbons: the photoisomerization of allenes to cyclopropenes and methylacetylenes
Mark G. Steinmetz, Richard T. Mayes, and Ji Charng Yang
pp 3518 - 3520; DOI:
10.1021/ja00376a052
PDF
Novel palladium(II)-catalyzed copolymerization of carbon monoxide with olefins
Ayusman Sen and Ta Wang Lai
pp 3520 - 3522; DOI:
10.1021/ja00376a053
PDF
Stabilities of carbocations in solution. 13. A leaving-group and solvent effect on the thermodynamics of carbocation formation in superacidic media
Edward M. Arnett and Thomas C. Hofelich
pp 3522 - 3524; DOI:
10.1021/ja00376a054
PDF
Liquid-crystalline cation-radical charge-transfer systems
F. D. Saeva, G. A. Reynolds, and L. Kaszczuk
pp 3524 - 3525; DOI:
10.1021/ja00376a055
PDF
Anion receptor molecules. Chain length dependent selective binding of organic and biological dicarboxylate anions by ditopic polyammonium macrocycles
M. W. Hosseini and J. M. Lehn
pp 3525 - 3527; DOI:
10.1021/ja00376a056
PDF
Remarkable dependency of regioselectivity on the catalyst metal species in the hydroformylation of trifluoropropene and pentafluorostyrene
Takamasa Fuchikami and Iwao Ojima
pp 3527 - 3529; DOI:
10.1021/ja00376a057
PDF
Solvent-dependent reactions of carbon dioxide with a platinum(II) dihydride. Reversible formation of a platinum(II) formatohydride and a cationic platinum(II) dimer, [Pt2H3(PEt3)4][HCO2]
Ralph S. Paonessa and William C. Trogler
pp 3529 - 3530; DOI:
10.1021/ja00376a058
PDF
[2 + 2] Cycloaddition reactions of homoazulene. A new synthesis of the homoheptalene ring system
Lawrence T. Scott and Mark A. Kirms
pp 3530 - 3531; DOI:
10.1021/ja00376a059
PDF
Reactions of aliphatic radicals and benzyl(aqua)cobaloxime: kinetics of coupling reactions as studied by novel kinetic competition methods
R. C. McHatton, James H. Espenson, and Andreja Bakac
pp 3531 - 3533; DOI:
10.1021/ja00376a060
PDF
Chemistry of cyclic olefins and polyenes on nickel and platinum surfaces
Min Chi Tsai, Judith Stein, Cynthia M. Friend, and E. L. Muetterties
pp 3533 - 3534; DOI:
10.1021/ja00376a061
PDF
Direct carbon-13 NMR evidence for a tetrahedral intermediate in the binding of a pepstatin analog to porcine pepsin
Daniel H. Rich, Michael S. Bernatowicz, and Paul G. Schmidt
pp 3535 - 3536; DOI:
10.1021/ja00376a062
PDF
Picosecond dynamics of solution-phase photofragmentation of dimanganese decacarbonyl [Mn2(CO)10]
Lewis J. Rothberg, N. John Cooper, Kevin S. Peters, and Veronica Vaida
pp 3536 - 3537; DOI:
10.1021/ja00376a063
PDF
Chemical effects of ultrasound on aqueous solutions. Evidence for hydroxyl and hydrogen free radicals (.cntdot.OH and .cntdot.H) by spin trapping
Keisuke Makino, Magdi M. Mossoba, and Peter Riesz
pp 3537 - 3539; DOI:
10.1021/ja00376a064
PDF
Reductive cleavage of glycosides
David Rolf and Gary R. Gray
pp 3539 - 3541; DOI:
10.1021/ja00376a065
PDF
On the concept of graph-theoretical individual ring resonance energies
William C. Herndon
pp 3541 - 3542; DOI:
10.1021/ja00376a066
PDF
Enzyme-catalyzed transhydrogenation between nicotinamide cofactors and its application in organic synthesis
Chi Huey Wong and George M. Whitesides
pp 3542 - 3544; DOI:
10.1021/ja00376a067
PDF
Reduction of ferricenium ion by horse heart ferrocytochrome c
Jack R. Pladziewicz and Michael J. Carney
pp 3544 - 3545; DOI:
10.1021/ja00376a068
PDF
Hemoprotein destruction. Iron-nitrogen shift of a phenyl group in a porphyrin complex
Paul R. Ortiz de Montellano, Kent L. Kunze, and Ohara Augusto
pp 3545 - 3546; DOI:
10.1021/ja00376a069
PDF
Agreement between transition-metal orbital populations from x-ray and polarized neutron-scattering experiments
Philip Coppens, Andrea Holladay, and Edwin D. Stevens
pp 3546 - 3547; DOI:
10.1021/ja00376a070
PDF
Book Reviews

pp 3548 - 3548; DOI:
10.1021/ja00376a600
PDF

Issue 13


Nuclear spin-spin coupling via nonbonded interactions. 4. Importance of bridgehead interactions on vicinal carbon-13-fluorine-19 and long-range proton-fluorine-19 coupling constants in 1-fluorobicycloalkanes
Michael Barfield, Ernest W. Della, Paul E. Pigou, and Steven R. Walter
pp 3549 - 3552; DOI:
10.1021/ja00377a001
PDF
Electron spin-echo studies of the solvation structure of superoxide ion (O2-) in water
P. A. Narayana, Darbha Suryanarayana, and Larry Kevan
pp 3552 - 3555; DOI:
10.1021/ja00377a002
PDF
Electron density analysis of substituted carbonyl groups
David L. Grier and Andrew Streitwieser
pp 3556 - 3564; DOI:
10.1021/ja00377a003
PDF
Gas-phase ion-molecule reactions of iron(+) and titanium(+) with alkanes
G. D. Byrd, R. C. Burnier, and B. S. Freiser
pp 3565 - 3569; DOI:
10.1021/ja00377a004
PDF
The mechanism of specific acylation of the active site of .alpha.-chymotrypsin by N-acylimidazoles
Robert L. Kogan, James A. Fee, and Thomas H. Fife
pp 3569 - 3576; DOI:
10.1021/ja00377a005
PDF
Diffusive and nondiffusive time scales in the dissociation and recombination of molecular iodine in linear alkanes
C. A. Langhoff, Brian Moore, and Mark DeMeuse
pp 3576 - 3579; DOI:
10.1021/ja00377a006
PDF
Intramolecular end-to-end excimer formation of bis[(1-pyrenylmethoxy)carbonyl]alkanes. A study of end-to-end collisional frequency on a chain molecule
T. Kanaya, K. Goshiki, M. Yamamoto, and Y. Nishijima
pp 3580 - 3587; DOI:
10.1021/ja00377a007
PDF
Fragmentation of metastable methane radical ions(1+) and isotopic analogs. Kinetic energy release distributions and tunneling through a rotational barrier: experiment and theory
A. J. Illies, M. F. Jarrold, and M. T. Bowers
pp 3587 - 3593; DOI:
10.1021/ja00377a008
PDF
Tautomerization of dimethyl phosphonate
William J. Pietro and Warren J. Hehre
pp 3594 - 3595; DOI:
10.1021/ja00377a009
PDF
Photophysics of aqueous tetracyanoplatinate(2-)
John W. Schindler, Robert C. Fukuda, and Arthur W. Adamson
pp 3596 - 3600; DOI:
10.1021/ja00377a010
PDF
Reductive elimination of a carbon-carbon bond from bis(trialkylphosphine)-3,3-dimethylplatinacyclobutanes produces bis(trialkylphosphine)platinum(0) and 1,1-dimethylcyclopropane
Robert DiCosimo and George M. Whitesides
pp 3601 - 3607; DOI:
10.1021/ja00377a011
PDF
Synthesis and characterization of coordination compounds of chelating ligands containing imidazole groups. The crystal and molecular structures of the dinuclear copper(I) and copper(II) compounds
Hugo M. J. Hendriks, J. M. W. L. Birker, Jacobus Van Rijn, Gerrit C. Verschoor, and Jan Reedijk
pp 3607 - 3617; DOI:
10.1021/ja00377a012
PDF
Poly(pyridine)ruthenium(II)-photoinduced redox reactions of bipyridinium cations, poly(pyridine)rhodium complexes, and osmium ammines
Carol Creutz, Andrew D. Keller, Norman Sutin, and Arden P. Zipp
pp 3618 - 3627; DOI:
10.1021/ja00377a013
PDF
A series of chiral polybrominated biindoles from the marine blue-green alga Rivularia firma. Application of carbon-13 NMR spin-lattice relaxation data and carbon-13-proton coupling constants to structure elucidation
Raymond S. Norton and Robert J. Wells
pp 3628 - 3635; DOI:
10.1021/ja00377a014
PDF
Conformational analysis. 42. Monosubstituted tetrahydropyrans
Ernest L. Eliel, Karl D. Hargrave, K. Michal Pietrusiewicz, and Muthiah Manoharan
pp 3635 - 3643; DOI:
10.1021/ja00377a015
PDF
Porphyrins with multiple crown ether voids: novel systems for cation complexation studies
V. Thanabal and V. Krishnan
pp 3643 - 3650; DOI:
10.1021/ja00377a016
PDF
Remarkable stabilities, geometries, and electronic states of lithium-substituted carbenium ions, CLi3-nHn+ (n = 0-3), and the corresponding radicals
Jayaraman Chandrasekhar, John A. Pople, Rolf Seeger, Ute Seeger, and Paul von Rague Schleyer
pp 3651 - 3655; DOI:
10.1021/ja00377a017
PDF
Heats of formation of some simple alkyl radicals
A. L. Castelhano and D. Griller
pp 3655 - 3659; DOI:
10.1021/ja00377a018
PDF
Competitive [6 + 2], [4 + 2], and [2 + 2] cycloadditions. Experimental classification of two-electron cycloaddends
Lawrence T. Scott, Ihsan Erden, William R. Brunsvold, Thomas H. Schultz, K. N. Houk, and M. N. Paddon-Row
pp 3659 - 3664; DOI:
10.1021/ja00377a019
PDF
Role of cyclohexaamylose C-3 hydroxyls in catalytic hydrolysis
Raymond J. Bergeron and Philip S. Burton
pp 3664 - 3670; DOI:
10.1021/ja00377a020
PDF
Cycloaddition of substituted allenes with 1,1-dichloro-2,2-difluoroethene. A model for the two-step, diradical-intermediate cycloaddition of allenes
Daniel J. Pasto and Steven E. Warren
pp 3670 - 3676; DOI:
10.1021/ja00377a021
PDF
Cycloaddition reactions of allenes with N-phenylmaleimide. A two-step, diradical-intermediate process
Daniel J. Pasto, Peter F. Heid, and Steven E. Warren
pp 3676 - 3685; DOI:
10.1021/ja00377a022
PDF
Hydrolysis of trimethyl orthocyclopropanecarboxylate: a change in rate-determining step
R. A. Burt, Y. Chiang, A. J. Kresge, and M. A. McKinney
pp 3685 - 3687; DOI:
10.1021/ja00377a023
PDF
Hydrolysis of bicyclic ortho esters in the 2,6,7-trioxabicyclo[2.2.1]heptane series. Confirmation of the absence of strain-relief rate acceleration
R. A. Burt, Y. Chiang, H. K. Hall, and A. J. Kresge
pp 3687 - 3690; DOI:
10.1021/ja00377a024
PDF
Mechanisms for the reactions of nitrones with aroyl chlorides
Harold W. Heine, Regina Zibuck, and William J. A. VandenHeuvel
pp 3691 - 3694; DOI:
10.1021/ja00377a025
PDF
A stereoselective synthesis of (.+-.)-H12-histrionicotoxin and related photoaffinity-labeled congeners
David A. Evans, Edward W. Thomas, and Richard E. Cherpeck
pp 3695 - 3700; DOI:
10.1021/ja00377a026
PDF
Metacyclophanes and related compounds. 4. Halogenations of 8,16-dialkyl-anti-5,13-di-tert-butyl[2.2]metacyclophan-1-enes and 2,7-di-tert-butyl-trans-10b,10c-dialkyl-10b,10c-dihydropyrenes
Masashi Tashiro and Takehiko Yamato
pp 3701 - 3707; DOI:
10.1021/ja00377a027
PDF
Metacyclophanes and related compounds. 7. Preparation and reduction of [2.2]metacyclophanequinone
Masashi Tashiro, Keizo Koya, and Takehiko Yamato
pp 3707 - 3710; DOI:
10.1021/ja00377a028
PDF
Monomer-dimer equilibrium of the 1-methyl-2-methoxycarbonylpyridinyl radical in 2-methyltetrahydrofuran solution. Kinetic and thermodynamic studies by electron spin resonance spectroscopy
Shozo Tero-Kubota, Yutaka Sano, and Yusaku Ikegami
pp 3711 - 3714; DOI:
10.1021/ja00377a029
PDF
Structure of the iron(III)-"capped" porphyrin, FeCl(C2-Cap), [5,10,15,20-[pyrromellitoyltetrakis(o-(oxyethoxy)phenyl)]porphyrinato]chloroiron(III)
M. Sabat and James A. Ibers
pp 3715 - 3721; DOI:
10.1021/ja00377a030
PDF
Hydrogen-mediated photolysis of (.eta.-C5Me5)Os(CO)2H: synthesis of (.eta.-C5Me5)Os(CO)H3 and multiply bonded diosmium compounds
James K. Hoyano and William A. G. Graham
pp 3722 - 3723; DOI:
10.1021/ja00377a031
PDF
Oxidative addition of the carbon-hydrogen bonds of neopentane and cyclohexane to a photochemically generated iridium(I) complex
James K. Hoyano and William A. G. Graham
pp 3723 - 3725; DOI:
10.1021/ja00377a032
PDF
Tertiary phosphine complexes of the f-block metals. Crystal structure of Yb[N(SiMe3)2]2[Me2PCH2CH2PMe2]: evidence for a ytterbium-.gamma.-carbon interaction
T. Don Tilley, Richard A. Andersen, and Allan Zalkin
pp 3725 - 3727; DOI:
10.1021/ja00377a033
PDF
Palladium(0)-catalyzed allylic alkylation and amination of allylnitroalkanes
Rui Tamura and Louis S. Hegedus
pp 3727 - 3729; DOI:
10.1021/ja00377a034
PDF
Octalene-[14]annulene conversion: 1,8-dimethyl[14]annulene
Emanuel Vogel, Hans Wilhelm Engels, Walter Huber, Johann Lex, and Klaus Muellen
pp 3729 - 3731; DOI:
10.1021/ja00377a035
PDF
Exploring nuclear spin systems by relayed magnetization transfer
G. Eich, G. Bodenhausen, and R. R. Ernst
pp 3731 - 3732; DOI:
10.1021/ja00377a036
PDF
Potential energy surface of the SN2 reaction in hydrated clusters
Keiji Morokuma
pp 3732 - 3733; DOI:
10.1021/ja00377a037
PDF
An intramolecular carbocyclic [3 + 2] cycloaddition via organopalladium intermediates
Barry M. Trost and Dominic M. T. Chan
pp 3733 - 3735; DOI:
10.1021/ja00377a038
PDF
Synthetic studies of withanolides. 5. Synthesis of jaborosalactone A, B, and D
Masao Hirayama, Keiju Gamoh, and Nobuo Ikekawa
pp 3735 - 3737; DOI:
10.1021/ja00377a039
PDF
Bis(2,4-dimethylpentadienyl)titanium: an open titanocene
Ju Zheng Liu and Richard D. Ernst
pp 3737 - 3739; DOI:
10.1021/ja00377a040
PDF
Evidence for tricarbonyltrihydridocobalt(III). Synthesis from tricarbonylhydridocobalt(I) in matrices
Ray L. Sweany
pp 3739 - 3740; DOI:
10.1021/ja00377a041
PDF
Photochemistry of saturated hydrocarbons. Mechanistic changes as a function of methyl substitution in the photosensitized reactions of the tricyclo[4.1.0.02,7]heptyl system
Paul G. Gassman and Kurt D. Olson
pp 3740 - 3742; DOI:
10.1021/ja00377a042
PDF
Magnification of neighboring group participation in the solvolytic generation of carbocations through the placement of an electron-withdrawing substituent on the incipient cationic center
Paul G. Gassman and Mark M. Doherty
pp 3742 - 3744; DOI:
10.1021/ja00377a043
PDF
Matrix isolation infrared spectra of oxy-tetraphenylporphyrinatoiron(II)
K. Nakamoto, T. Watanabe, T. Ama, and M. W. Urban
pp 3744 - 3745; DOI:
10.1021/ja00377a044
PDF
Conformation of the progesterone side chain: resolution of the apparent conflict between x-ray data and force-field calculations using MM2
Salvatore Profeta, Peter A. Kollman, and Manfred E. Wolff
pp 3745 - 3747; DOI:
10.1021/ja00377a045
PDF
Chirality and structures of bacteriochlorophylls d
Kevin M. Smith, Dane A. Goff, Jack Fajer, and Kathleen M. Barkigia
pp 3747 - 3749; DOI:
10.1021/ja00377a046
PDF
Electronic control of stereoselectivity. 12. Spectroscopic evidence for directed electronic influences within norbornyl frameworks
Leo A. Paquette and Pana Charumilind
pp 3749 - 3751; DOI:
10.1021/ja00377a047
PDF
Electrochemical preparation of a Prussian blue analog: iron-ruthenium cyanide
Kingo Itaya, Tatsuaki Ataka, and Shinobu Toshima
pp 3751 - 3752; DOI:
10.1021/ja00377a048
PDF
Ferric nitrilotriacetate: an active-center analog of pyrocatechase
Michael G. Weller and Ulrich Weser
pp 3752 - 3754; DOI:
10.1021/ja00377a049
PDF
Biosynthesis of riboflavin. Incorporation of D-[1-13C]ribose
A. Bacher, Q. LeVan, M. Buehler, P. J. Keller, V. Eimicke, and H. G. Floss
pp 3754 - 3755; DOI:
10.1021/ja00377a050
PDF
Electron-transfer pathways in the reduction of d6 and d7 organoiron cations by lithium tetrahydroaluminate and sodium tetrahydroborate
Pascal Michaud, Didier Astruc, and John H. Ammeter
pp 3755 - 3757; DOI:
10.1021/ja00377a051
PDF
Efficient de novo construction of the indanepropionic acid precursor of 11-oxo steroids. An improved internal Diels-Alder sequence
Gilbert Stork and David Sherman
pp 3758 - 3759; DOI:
10.1021/ja00377a052
PDF
On the mechanism of hydrogenolysis of linear hydrocarbons and its relationship to the Fischer-Tropsch reaction
William T. Osterloh, M. E. Cornell, and R. Pettit
pp 3759 - 3761; DOI:
10.1021/ja00377a053
PDF
Synthesis of electrophilic (dimethylcarbene)iron complexes
Charles P. Casey, William H. Miles, Hideyuki Tukada, and Joseph M. O'Connor
pp 3761 - 3762; DOI:
10.1021/ja00377a054
PDF
Chemistry of organosilicon compounds. 157. An ESR study of 2-adamantyl and 2-(trimethylsiloxy)-2-adamantyl radicals
Mitsuo Kira, Mieko Watanabe, Michiko Ichinose, and Hideki Sakurai
pp 3762 - 3764; DOI:
10.1021/ja00377a055
PDF
Direct observation of a hydrocarbon singlet 1,3-biradical by picosecond laser-induced fluorescence spectroscopy
David F. Kelley, Mark R. Mazur, P. M. Rentzepis, and Jerome A. Berson
pp 3764 - 3766; DOI:
10.1021/ja00377a056
PDF
The SN2 displacements at 2-norbornyl brosylates
Klaus Banert and Wolfgang Kirmse
pp 3766 - 3767; DOI:
10.1021/ja00377a057
PDF
Stereochemical control of intramolecular conjugate addition. A short, highly stereoselective synthesis of adrenosterone
Gilbert Stork, Jeffrey D. Winkler, and Christopher S. Shiner
pp 3767 - 3768; DOI:
10.1021/ja00377a058
PDF
On the structure of the hypothetical common tetramethylene biradical intermediate
Charles Doubleday, James W. McIver, and Michael Page
pp 3768 - 3770; DOI:
10.1021/ja00377a059
PDF
Generation and reactivity of the acetylacetonyl radical
Yuan L. Chow and Gonzalo E. Buono-Core
pp 3770 - 3771; DOI:
10.1021/ja00377a060
PDF
Carbenium-carbonium structures, H2C+-CH4+, for the ethane dication
Paul Von Rague Schleyer, Alexander J. Kos, John A. Pople, and Alexandru T. Balaban
pp 3771 - 3773; DOI:
10.1021/ja00377a061
PDF
Oxidative addition of unactivated epoxides to iridium(I) complexes. Formation of stable cis-hydridoformylmethyl and -acylmethyl complexes
D. Milstein and J. C. Calabrese
pp 3773 - 3774; DOI:
10.1021/ja00377a062
PDF
General method for determining absolute configuration of acyclic allylic alcohols
Nina C. Gonnella, Koji Nakanishi, Victor S. Martin, and K. Barry Sharpless
pp 3775 - 3776; DOI:
10.1021/ja00377a063
PDF
Absolute stereochemistry of palytoxin
Richard E. Moore, Giovanni Bartolini, Joseph Barchi, Aksel A. Bothner-By, Josef Dadok, and Joseph Ford
pp 3776 - 3779; DOI:
10.1021/ja00377a064
PDF
Ab initio study of silylene insertion into oxygen-hydrogen bonds. Stability of zwitterionic intermediates
Krishnan Raghavachari, Jayaraman Chandrasekhar, and Michael J. Frisch
pp 3779 - 3781; DOI:
10.1021/ja00377a065
PDF
Synthesis of cesium 18-crown-6: the first single-crystal electride?
Dheeb Issa and James L. Dye
pp 3781 - 3782; DOI:
10.1021/ja00377a066
PDF
Additions and Corrections - Heteropolypentatungstobisphosphates. Cyclopentane-Like Pseudorotation of an Oxometalate Structure.
P. R. Sethuraman, M. A. Leparulo, M. T. Pope, F. Zonnevijlle, C. Brevard, and J. Lemerle
pp 3782 - 3782; DOI:
10.1021/ja00377a600
PDF
Additions and Corrections - New Multidentate Ligands. X. Chelating Tendencies of N,N'-Diglycylethylenediamine-N'',N'', N''', N'''--tetraacetic Acid and Ethylenediamine - N, N'-di(acetylglycine)-N,N'-diacetic Acid
R. J. Motekaitis, and A. E. Martell
pp 3782 - 3783; DOI:
10.1021/ja00377a601
PDF
Additions and Corrections - Displacement Stereochemistry and Product-Formation Selectivities in the Solvolysis of Cycloocytl p-Bromobenzenesulfonate
J. Eric Nordlander, Philip O. Owuor, Donna J. Cabral, and Jerome E. Haky
pp 3783 - 3783; DOI:
10.1021/ja00377a602
PDF
Additions and Corrections - Propagation of Redox Reaction through a Quinoid Polymer Film on an Electrode
M. Fukui, A. Kitani, C. Degrand, and L. L. Miller
pp 3783 - 3783; DOI:
10.1021/ja00377a603
PDF
Additions and Corrections - The MNDOC Method, a Correlated Version of the MNDO Model
W. Thiel
pp 3783 - 3783; DOI:
10.1021/ja00377a604
PDF
Additions and Corrections - Oxidation of Ketals to Orthocarbonates: A Double Baeyer-Villiger Reaction
William F. Bailey, and Mei-Jue Shih
pp 3783 - 3783; DOI:
10.1021/ja00377a605
PDF
Additions and Corrections - Oxidation of Mandelic Acid by Fenton's Reagent
Cheves Walling, Kalyani Amarnath, and Curt B. Campbell
pp 3783 - 3783; DOI:
10.1021/ja00377a606
PDF
Book Reviews

pp 3783 - 3784; DOI:
10.1021/ja00377a607
PDF

Issue 14


Theoretical studies of borepin and cycloheptatriene
Jerome M. Schulman, Raymond L. Disch, and Michael L. Sabio
pp 3785 - 3788; DOI:
10.1021/ja00378a001
PDF
Gibbs free energies of transfer of cryptand (2,2,2) and silver (2,2,2) perchlorate from water to acetonitrile-water mixtures
B. G. Cox, C. Guminski, and H. Schneider
pp 3789 - 3792; DOI:
10.1021/ja00378a002
PDF
Kinetic and thermodynamic control in group transfer reactions
Joseph R. Murdoch and Douglas E. Magnoli
pp 3792 - 3800; DOI:
10.1021/ja00378a003
PDF
On the geometric mean principle for electronegativity equalization
Robert G. Parr and Libero J. Bartolotti
pp 3801 - 3803; DOI:
10.1021/ja00378a004
PDF
Photophysics and photochemistry of pentacarbonyl(pyridine)tungsten(0) complexes which luminesce in fluid solution
Alistair J. Lees and Arthur W. Adamson
pp 3804 - 3812; DOI:
10.1021/ja00378a005
PDF
Excitation energies in trimethylenemethane derivatives
Sheila B. Auster, Russell M. Pitzer, and Matthew S. Platz
pp 3812 - 3815; DOI:
10.1021/ja00378a006
PDF
Probing of chemical bonding through two-photon spectroscopy of substituted benzenes
Richard P. Rava and Lionel Goodman
pp 3815 - 3822; DOI:
10.1021/ja00378a007
PDF
Microwave spectra and molecular structure of boranediamine
L. R. Thorne and W. D. Gwinn
pp 3822 - 3827; DOI:
10.1021/ja00378a008
PDF
Electronic structure of the carbyne C-Li and the carbene Li2C
Aristides Mavridis and James F. Harrison
pp 3827 - 3833; DOI:
10.1021/ja00378a009
PDF
Electron transfer to complex ligands. Radical anions and organomagnesium radical complexes of 2,2'-bipyridines and 1,10-phenanthrolines
Wolfgang Kaim
pp 3833 - 3837; DOI:
10.1021/ja00378a010
PDF
Detailed studies of propagating fronts in the iodate oxidation of arsenous acid
Adel Hanna, Alan Saul, and Kenneth Showalter
pp 3838 - 3844; DOI:
10.1021/ja00378a011
PDF
Reductions in aprotic media. 2. Influence of catalytic hydrogen reduction on the course of hydrocarbon reduction
Stanley Pons and S. B. Khoo
pp 3845 - 3849; DOI:
10.1021/ja00378a012
PDF
ESR and ENDOR investigations of spin exchange in mixed galvinoxyl/nitroxide biradicals. Syntheses
B. Kirste, A. Krueger, and H. Kurreck
pp 3850 - 3858; DOI:
10.1021/ja00378a013
PDF
Perpendicular and parallel acetylene complexes
David M. Hoffman, Roald Hoffmann, and C. Richard Fisel
pp 3858 - 3875; DOI:
10.1021/ja00378a014
PDF
Electronic origin of the thermochromic effect in 2,2',5,5'-tetramethylbistibole
Timothy Hughbanks, Roald Hoffmann, Myung Hwan Whangbo, K. R. Stewart, Odile Eisenstein, and Enric Canadell
pp 3876 - 3879; DOI:
10.1021/ja00378a015
PDF
Criteria of maximum overlap and minimum orbital energy in molecular orbital studies of conformations of transition-metal carbene and carbyne complexes
Nenad M. Kostic and Richard F. Fenske
pp 3879 - 3884; DOI:
10.1021/ja00378a016
PDF
Chiral recognition in solution. 1. Directional ion association of optically active cobalt(III) complexes as inferred from nuclear magnetic resonance and difference circular dichroism spectra
Hiroshi Nakazawa, Ushio Sakaguchi, and Hayami Yoneda
pp 3885 - 3891; DOI:
10.1021/ja00378a017
PDF
(Trimethylphosphine)cobalt(I) complexes. 1. Reactivity with ethylene and crystal structure, [Co(MeCN)(C2H4)(PMe3)3]BPh4.MeCN
Brigitte Capelle, Andre L. Beauchamp, Michele Dartiguenave, Yves Dartiguenave, and Hans Friedrich Klein
pp 3891 - 3897; DOI:
10.1021/ja00378a018
PDF
The synthesis, characterization, and reactivity of an unusual, amphoteric (tetrahydroborato)ruthenium hydride complex of a chelating triphosphine, Ru(H)(.eta.2-BH4)(ttp)
John B. Letts, Terry J. Mazanec, and Devon W. Meek
pp 3898 - 3905; DOI:
10.1021/ja00378a019
PDF
Ligand substitution processes in tetranuclear carbonyl clusters. 6. Steric contribution to ligand dissociation in multisubstituted tetrairidium dodecacarbonyl derivatives
Donald J. Darensbourg and Brenda J. Baldwin-Zuschke
pp 3906 - 3910; DOI:
10.1021/ja00378a020
PDF
Peptide formation in the presence of a metal ion protecting group. 4. Synthesis of penta- and hexapeptide sequences with the pentaamminecobalt(III) complex
Stephan S. Isied, Asbed Vassilian, and John M. Lyon
pp 3910 - 3916; DOI:
10.1021/ja00378a021
PDF
Polar radicals. 17. On the mechanism of iodine atom transfer. A 9-I-2 intermediate
Dennis D. Tanner, Darwin W. Reed, and B. P. Setiloane
pp 3917 - 3923; DOI:
10.1021/ja00378a022
PDF
Stereoselective, biogenetically patterned synthesis of (.+-.)-aplysistatin
James D. White, Takeshi Nishiguchi, and Richard W. Skeean
pp 3923 - 3928; DOI:
10.1021/ja00378a023
PDF
Photochemical and thermal rearrangement of oxaziridines. Experimental evidence in support of the stereoelectronic control theory
Armand Lattes, Esther Oliveros, Monique Riviere, Czeslaw Belzeck, Danuta Mostowicz, Wojciech Abramskj, Carla Piccinni-Leopardi, Gabriel Germain, and Maurice Van Meerssche
pp 3929 - 3934; DOI:
10.1021/ja00378a024
PDF
Determination of addition rates of benzenethiyl radicals to alkynes by flash photolysis. Structures of produced vinyl-type radicals
Osamu Ito, Ryoichi Omori, and Minoru Matsuda
pp 3934 - 3937; DOI:
10.1021/ja00378a025
PDF
Determination of the orientation of aromatic molecules adsorbed on platinum electrodes. The effect of solute concentration
Manuel P. Soriaga and Arthur T. Hubbard
pp 3937 - 3945; DOI:
10.1021/ja00378a026
PDF
A nitrogen-15 nuclear magnetic resonance study of the acid-base and tautomeric equilibriums of 4-substituted imidazoles and its relevance to the catalytic mechanism of .alpha.-lytic protease
John D. Roberts, Yu Chun, Cynthia Flanagan, and Teresa R. Birdseye
pp 3945 - 3949; DOI:
10.1021/ja00378a027
PDF
Effect of isocyano group substitution in simple primary, secondary, and tertiary carbanions
J. B. Moffat
pp 3949 - 3951; DOI:
10.1021/ja00378a028
PDF
Stereochemistry of trans-1,4,5,8-tetranitroso-1,4,5,8-tetraazadecalin: an attractive interaction between perinitroso groups
Rodney L. Willer, Donald W. Moore, and Leroy F. Johnson
pp 3951 - 3954; DOI:
10.1021/ja00378a029
PDF
Inclusional association of a fluorescence detergent probe with cyclodextrins. Microscopic environment of the interior of a cyclodextrin cavity
Nicholas J. Turro, Tsuneo Okubo, and Chao Jen Chung
pp 3954 - 3957; DOI:
10.1021/ja00378a030
PDF
Structure and conformation of 8-bromo-9-.beta.-D-xylofuranosyladenine in the solid state and in solution
George I. Birnbaum, Miroslaw Cygler, Irena Ekiel, and David Shugar
pp 3957 - 3964; DOI:
10.1021/ja00378a031
PDF
Isolation, purification, and characterization of high-valent complexes from a manganese porphyrin based catalytic hydrocarbon activation system. Crystal and molecular structure of .mu.-oxo-bis[azido(tetraphenylporphinato)manganese(IV)]
Bruce C. Schardt, John A. Smegal, Frederick J. Hollander, and Craig L. Hill
pp 3964 - 3972; DOI:
10.1021/ja00378a032
PDF
Photochemistry of alkyl halides. 8. Formation of a bridgehead alkene
Paul J. Kropp, Paul R. Worsham, Robert I. Davidson, and Tappey H. Jones
pp 3972 - 3980; DOI:
10.1021/ja00378a033
PDF
Stereospecificity of the oxymetalation of optically active 1,2-cyclononadiene
Robert D. Bach, Joseph W. Holubka, and Carl L. Willis
pp 3980 - 3987; DOI:
10.1021/ja00378a034
PDF
Unusual solvent effects in the Wittig reaction of some ketones indicating initial one-electron transfer
George A. Olah and V. V. Krishnamurthy
pp 3987 - 3990; DOI:
10.1021/ja00378a035
PDF
Sites of photolytic intermolecular crosslinking between fatty acyl chains in phospholipids carrying a photoactivable carbene precursor
Ramachandran Radhakrishnan, Catherine E. Costello, and H. Gobind Khorana
pp 3990 - 3997; DOI:
10.1021/ja00378a036
PDF
Analysis of the oxidation state and oxidation number by ab initio molecular orbital calculations: chlorine and sulfur compounds
Keiko Takano, Haruo Hosoya, and Suehiro Iwata
pp 3998 - 4005; DOI:
10.1021/ja00378a037
PDF
The lipophilic macrocyclic polyether 2,3,9,10-dibenzo-1,4,8,11-tetraoxacyclotetradeca-2,9-diene (dibenzo-14-crown-4): a selective ionophore for lithium ions
Uriel Olsher
pp 4006 - 4007; DOI:
10.1021/ja00378a038
PDF
Direct observation of substitution reactions of tricarbonylbis(phosphine)manganese radicals
Sharon B. McCullen, Howard W. Walker, and Theodore L. Brown
pp 4007 - 4008; DOI:
10.1021/ja00378a039
PDF
Carbon-13 NMR subspectra of a protein based on the number of attached protons. Ferredoxin from Anabaena variabilis
Tze Ming Chan, William M. Westler, Robert E. Santini, and John L. Markley
pp 4008 - 4010; DOI:
10.1021/ja00378a040
PDF
Heteronuclear (proton, carbon-13) two-dimensional chemical shift correlation NMR spectroscopy of a protein. Ferredoxin from Anabaena variabilis
Tze Ming Chan and John L. Markley
pp 4010 - 4011; DOI:
10.1021/ja00378a041
PDF
Total synthesis of (.+-.)-panacene
Ken S. Feldman, C. Crawford Mechem, and Leslie Nader
pp 4011 - 4012; DOI:
10.1021/ja00378a042
PDF
A remarkable fragmentation reaction of a pyrimidyl radical
Jeffery B. Press, Nancy H. Eudy, F. M. Lovell, George O. Morton, and Marshall M. Siegel
pp 4013 - 4014; DOI:
10.1021/ja00378a043
PDF
Identity of cosynthetic factor I of Streptomyces aureofaciens and fragment FO from coenzyme F420 of Methanobacterium species
J. R. D. McCormick and George O. Morton
pp 4014 - 4015; DOI:
10.1021/ja00378a044
PDF
Total synthesis of milbemycin .beta.3
Amos B. Smith, Steven R. Schow, Jonathan D. Bloom, Andrew S. Thompson, and Kevin N. Winzenberg
pp 4015 - 4018; DOI:
10.1021/ja00378a045
PDF
Stereoselective generation of (Z)-secondary thioamide dianion: application to diastereoselective aldol condensations and thio-Claisen rearrangements
Y. Tamaru, Y. Amino, Y. Furukawa, M. Kagotani, and Z. Yoshida
pp 4018 - 4019; DOI:
10.1021/ja00378a046
PDF
Ab initio study of the structure and vibrational frequencies of the Grignard reagent methylmagnesium chloride
Shogo Sakai and K. D. Jordan
pp 4019 - 4021; DOI:
10.1021/ja00378a047
PDF
Sulfoximine-mediated resolutions of ketones
Carl R. Johnson and James R. Zeller
pp 4021 - 4023; DOI:
10.1021/ja00378a048
PDF
The INOC route to carbocyclics: a formal total synthesis of (.+-.)-sarkomycin
Alan P. Kozikowski and Philip D. Stein
pp 4023 - 4024; DOI:
10.1021/ja00378a049
PDF
Reduction of .DELTA.2-isoxazolines: a conceptually different approach to the formation of aldol adducts
Dennis P. Curran
pp 4024 - 4026; DOI:
10.1021/ja00378a050
PDF
Absolute configuration of the trans-9,10-dihydrodiol metabolite of the carcinogen benzo[a]pyrene
Haruhiko Yagi and Donald M. Jerina
pp 4026 - 4027; DOI:
10.1021/ja00378a051
PDF
2,6-Methano-2,6-dehydronorbornane: an exceptionally strained [3.1.1]propellane
V. Vinkovic and Z. Majerski
pp 4027 - 4029; DOI:
10.1021/ja00378a052
PDF
Catalytic oxidation of water by an oxo-bridged ruthenium dimer
Susan W. Gersten, George J. Samuels, and Thomas J. Meyer
pp 4029 - 4030; DOI:
10.1021/ja00378a053
PDF
Alicyclic Claisen rearrangement. A general carbocycle synthesis based on four-atom-ring contractions of lactones
Matthew M. Abelman, Raymond L. Funk, and John D. Munger
pp 4030 - 4032; DOI:
10.1021/ja00378a054
PDF
Mechanism of carbon monoxide substitution in a metal radical: vanadium hexacarbonyl
Qizhen Shi, Thomas G. Richmond, William C. Trogler, and Fred Basolo
pp 4032 - 4034; DOI:
10.1021/ja00378a055
PDF
Unusual cycloaddition reactions with 2-(trifluoromethyl)-3,3-difluorooxaziridine
William Y. Lam and Darryl D. DesMarteau
pp 4034 - 4035; DOI:
10.1021/ja00378a056
PDF
Book Reviews

pp 4035 - 4036; DOI:
10.1021/ja00378a600
PDF

Issue 15


Anomerization of furanose sugars: kinetics of ring-opening reactions by proton and carbon-13 saturation-transfer NMR spectroscopy
Anthony S. Serianni, John Pierce, Shaw Guang Huang, and Robert Barker
pp 4037 - 4044; DOI:
10.1021/ja00379a001
PDF
The concept of Lewis acids and bases applied to surfaces
P. C. Stair
pp 4044 - 4052; DOI:
10.1021/ja00379a002
PDF
Atom-atom potential analysis of the packing characteristics of carboxylic acids. A study based on experimental electron-density distributions
Z. Berkovitch-Yellin and L. Leiserowitz
pp 4052 - 4064; DOI:
10.1021/ja00379a003
PDF
Electronic structures of bent-sandwich compounds of the main group elements; a molecular orbital and UV photoelectron spectroscopic study of bis(cyclopentadienyl)tin and related compounds
S. G. Baxter, A. H. Cowley, J. G. Lasch, M. Lattman, W. P. Sharum, and C. A. Stewart
pp 4064 - 4069; DOI:
10.1021/ja00379a004
PDF
pH-dependent fluorescence spectroscopy. 15. Detection of an unusual excited-state species of 3-hydroxyxanthone
Otto S. Wolfbeis and Eva Fuerlinger
pp 4069 - 4072; DOI:
10.1021/ja00379a005
PDF
Thermodynamic constants of complexes of crown ethers and uncharged molecules and x-ray structure of the 18-crown-6.(MeNO2)2 complex
Jan A. A. De Boer, David N. Reinhoudt, Sybolt Harkema, Gerrit J. Van Hummel, and Feike De Jong
pp 4073 - 4076; DOI:
10.1021/ja00379a006
PDF
Dithizone adsorption at metal electrodes. 4. Voltammetric and surface Raman spectroelectrochemical investigation at a copper electrode
Jeanne E. Pemberton and Richard P. Buck
pp 4076 - 4084; DOI:
10.1021/ja00379a007
PDF
Crystal structure of valinomycin-sodium picrate. Anion effects on valinomycin-cation complexes
L. K. Steinrauf, J. A. Hamilton, and M. N. Sabesan
pp 4085 - 4091; DOI:
10.1021/ja00379a008
PDF
Copper(I)-carbon monoxide chemistry: genesis and chemical and structural properties of copper(I) terminal and bridging carbonyls
M. Pasquali, C. Floriani, G. Venturi, A. Gaetani-Manfredotti, and A. Chiesi-Villa
pp 4092 - 4099; DOI:
10.1021/ja00379a009
PDF
Ternary complexes in solution. 41. Ternary complexes in solution as models for enzyme-metal ion-substrate complexes. Comparison of the coordination tendency of imidazole and ammonia toward the binary complexes of Mn(II), Co(II), Ni(II), Cu(II), Zn(II), or Cd(II) and uridine 5'-triphosphate or adenosine 5'-triphosphate
Nityananda Saha and Helmut Sigel
pp 4100 - 4105; DOI:
10.1021/ja00379a010
PDF
Mechanisms of oxidation of 2-propanol by polypyridyl complexes of ruthenium(III) and ruthenium(IV)
Mark S. Thompson and Thomas J. Meyer
pp 4106 - 4115; DOI:
10.1021/ja00379a011
PDF
Weak metal-metal bonds in an "electron-rich" cluster. The synthesis and x-ray crystallographic characterization of Os4(CO)12(.mu.3-S)2 and Os6(CO)16(.mu.4-S)(.mu.3-S)
Richard D. Adams and Li Wu Yang
pp 4115 - 4117; DOI:
10.1021/ja00379a012
PDF
Substituent effect of chelated cobalt. 5. Acidities of (carboxymethyl)- and (1-carboxyethyl)cobaloximes. A quantitative analysis of the .beta. effect
Kenneth L. Brown and Eva Zahonyi-Budo
pp 4117 - 4124; DOI:
10.1021/ja00379a013
PDF
Reactions of B12r with aliphatic free radicals: a pulse-radiolysis study
William A. Mulac and Dan Meyerstein
pp 4124 - 4128; DOI:
10.1021/ja00379a014
PDF
Structure of scopafungin, a potent nonpolyene antifungal antibiotic
Daniel Samain, J. Carter Cook, and Kenneth L. Rinehart
pp 4129 - 4141; DOI:
10.1021/ja00379a015
PDF
Kinetics and mechanism of bromination of 2-pyridinone and related derivatives in aqueous solution
Oswald S. Tee and Martino Paventi
pp 4142 - 4146; DOI:
10.1021/ja00379a016
PDF
Time-resolved and steady-state fluorescence studies of the excited-state proton transfer in 3-hydroxyflavone and 3-hydroxychromone
Michiya Itoh, Kunihiro Tokumura, Yoshifumi Tanimoto, Yoko Okada, Hiroshi Takeuchi, Kinichi Obi, and Ikuzo Tanaka
pp 4146 - 4150; DOI:
10.1021/ja00379a017
PDF
Properties of .alpha.-keto cations. Facile generation under solvolytic conditions
Xavier Creary and Cristina C. Geiger
pp 4151 - 4162; DOI:
10.1021/ja00379a018
PDF
Photooxidation of vitamin K chromenol derivatives
R. Marshall Wilson, Thomas F. Walsh, and Robert Whittle
pp 4162 - 4166; DOI:
10.1021/ja00379a019
PDF
Carbon-13-proton spin-spin coupling. 9. Purine
Martin Schumacher and Harald Guenther
pp 4167 - 4173; DOI:
10.1021/ja00379a020
PDF
Electronic effects on triplet and singlet excited-state carbonyl formation in the thermolysis of 3-aryl-3-methyl-1,2-dioxetanes
William H. Richardson and Diana L. Stiggall-Estberg
pp 4173 - 4179; DOI:
10.1021/ja00379a021
PDF
Asymmetric induction during organometallic conjugate addition to enantiomerically pure 2-(arylsulfinyl)-2-cyclopentenones
Gary H. Posner, John P. Mallamo, Martin Hulce, and Leah L. Frye
pp 4180 - 4185; DOI:
10.1021/ja00379a022
PDF
Free energy relationship for electron transfer far from equilibrium. Analysis of reversibility in the endergonic region
R. J. Klingler and J. K. Kochi
pp 4186 - 4196; DOI:
10.1021/ja00379a023
PDF
Micellar photochemistry. Photooxidation with intramicellar-generated singlet oxygen
Michael C. Hovey
pp 4196 - 4202; DOI:
10.1021/ja00379a024
PDF
Models for oxygenases that catalyze the cleavage of carbon-carbon bonds: kinetics and mechanism of the decomposition of 2,3-dimethyl-3-peroxyindolenines in aqueous solution
Mark S. Fraser and Gordon A. Hamilton
pp 4203 - 4211; DOI:
10.1021/ja00379a025
PDF
Transmission of substituent effects through the silicon-silicon bond
Gene M. Dubowchik, David W. Gottschall, Michael J. Grossman, Robert L. Norton, and Claude H. Yoder
pp 4211 - 4214; DOI:
10.1021/ja00379a026
PDF
Photochemical reactivity in organized assemblies. 27. Hydrophobic and entropic factors in the solubilization of ionic substrates in micelles: effects of temperature, surfactant chain length, and added surfactants
Joao B. S. Bonilha, Thomas K. Foreman, and David G. Whitten
pp 4215 - 4220; DOI:
10.1021/ja00379a027
PDF
Synthesis with tin templates. A new family of diastereomeric macrocycles
Abraham Shanzer, Jacqueline Libman, Hugo Gottlieb, and Felix Frolow
pp 4220 - 4225; DOI:
10.1021/ja00379a028
PDF
Pseudoguaianolides. 1. Stereospecific total synthesis of the ambrosanolides dl-ambrosin and dl-damsin
Paul A. Grieco, George F. Majetich, and Yasufumi Ohfune
pp 4226 - 4233; DOI:
10.1021/ja00379a029
PDF
Pseudoguaianolides. 2. Stereocontrolled total synthesis of the helenanolide dl-helenalin
Paul A. Grieco, Yasufumi Ohfune, George F. Majetich, and C. L. J. Wang
pp 4233 - 4240; DOI:
10.1021/ja00379a030
PDF
Mechanism of arene carbon-hydrogen bond activation by (C5Me5)Rh(PMe3)(H)Ph. Evidence for arene precoordination
William D. Jones and Frank J. Feher
pp 4240 - 4242; DOI:
10.1021/ja00379a031
PDF
Metallacyclobutane to metallacyclopentane ring-expansion reactions
J. Thomas Burton and Richard J. Puddephatt
pp 4242 - 4244; DOI:
10.1021/ja00379a032
PDF
Structure of an unusual 1:2 carbene-methacrylonitrile adduct. Chemical evidence for nitrile ylide formation
Andrew S. Kende, Paul Hebeisen, Pauline J. Sanfilippo, and Bruce H. Toder
pp 4244 - 4245; DOI:
10.1021/ja00379a033
PDF
Synthesis and electrophilic reactivity of dicarbonyl(cyclohexadienyl)nitrosylmanganese cations
Y. K. Chung, Hyung Soo Choi, D. A. Sweigart, and Neil G. Connelly
pp 4245 - 4247; DOI:
10.1021/ja00379a034
PDF
Equilibrium and kinetic carbon monoxide binding parameters of T- and R-state hemoglobin chains using iron-manganese hybrids
Neil V. Blough and Brian M. Hoffman
pp 4247 - 4250; DOI:
10.1021/ja00379a035
PDF
Oscillating chemiluminescence from the reduction of bromate by malonic acid catalyzed by tris(2,2'-bipyridine)ruthenium(II)
Fabrizio Bolletta and Vincenzo Balzani
pp 4250 - 4251; DOI:
10.1021/ja00379a036
PDF
A chiral total synthesis of compactin
Masahiro Hirama and Mitsuko Uei
pp 4251 - 4253; DOI:
10.1021/ja00379a037
PDF
Novel binuclear platinum(III) octaphosphite complexes
Chi Mng Che, William P. Schaefer, Harry B. Gray, Mark K. Dickson, Paul B. Stein, and D. Max Roundhill
pp 4253 - 4255; DOI:
10.1021/ja00379a038
PDF
Novel nickel(II) complexes with doubly deprotonated dioxopentaamine macrocyclic ligands for uptake and activation of molecular oxygen
Eiichi Kimura, Atsuko Sakonaka, Ryosuke Machida, and Mutsuo Kodama
pp 4255 - 4257; DOI:
10.1021/ja00379a039
PDF
Selective formation of trans olefins by a catalytic hydrogenation of alkynes mediated at two adjacent metal centers
R. R. Burch, E. L. Muetterties, R. G. Teller, and Jack M. Williams
pp 4257 - 4258; DOI:
10.1021/ja00379a040
PDF
Reduction of isocyanomethane and acetonitrile by the reduced species of [Fe4S4(SPh)4]2- and [Mo2Fe6S8(SPh)9]3-: model reactions to nitrogenase
Koji Tanaka, Yoshinobu Imasaka, Masahiro Tanaka, Makoto Honjo, and Toshio Tanaka
pp 4258 - 4260; DOI:
10.1021/ja00379a041
PDF
Bis[bis(trifluoromethanesulfonyl)imido]xenon: a new compound possessing xenon-nitrogen bonds
Jerry Foropoulos and Darryl D. DesMarteau
pp 4260 - 4261; DOI:
10.1021/ja00379a042
PDF
Drastic fluorescence enhancement of cyanine dyes bound to synthetic bilayer membranes. Its high sensitivity to the chemical structure and the physical state of the membrane
N. Nakashima and T. Kunitake
pp 4261 - 4262; DOI:
10.1021/ja00379a043
PDF
Photochemical transformation of cephalosporins into carbapenems
Robert L. Rosati, Leilani V. Kapili, Peter Morrissey, Jon Bordner, and E. Subramanian
pp 4262 - 4264; DOI:
10.1021/ja00379a044
PDF
Interhelical DNA-DNA crosslinking. Bis(monoazidomethidium)octaoxahexacosanediamine: a probe of packaged nucleic acid
Mark A. Mitchell and Peter B. Dervan
pp 4265 - 4266; DOI:
10.1021/ja00379a045
PDF
Cobalt nitro complexes as oxygen transfer agents. 4. Epoxidation of olefins
S. E. Diamond, F. Mares, A. Szalkiewicz, D. A. Muccigrosso, and J. P. Solar
pp 4266 - 4268; DOI:
10.1021/ja00379a046
PDF
Epoxidation of cyclic alkenes by bis(acetonitrile)chloronitropalladium(II): on the role of heterometallacyclopentanes and .beta.-hydrogen elimination in the catalytic oxidation of alkenes
Mark A. Andrews and Chi Wen F. Cheng
pp 4268 - 4270; DOI:
10.1021/ja00379a047
PDF
Pulsed-laser photocatalytic isomerization and hydrogenation of olefins
Robert L. Whetten, Ke Jian Fu, and Edward R. Grant
pp 4270 - 4272; DOI:
10.1021/ja00379a048
PDF
Circular dichroism of 1,1'-spirobi[benzindans]: demonstration of nongenerality of the C2 rule
Keiji Shingu, Seiichi Imajo, and Hiroko Kuritani
pp 4272 - 4273; DOI:
10.1021/ja00379a049
PDF
Carbanion photochemistry. 6. Formation of a reactive carbene via photoinduced halide elimination
Laren M. Tolbert and Shahabuddin Siddiqui
pp 4273 - 4274; DOI:
10.1021/ja00379a050
PDF
Lithiated carbocations. The generation, structure, and stability of CLi5+
Eluvathingal D. Jemmis, Jayaraman Chandrasekhar, Ernst Ulrich Wuerthwein, Paul von Rague Schleyer, John W. Chinn, Frederick J. Landro, Richard J. Lagow, Brian Luke, and John A. Pople
pp 4275 - 4276; DOI:
10.1021/ja00379a051
PDF
Inherently dissymmetric chromophores and vibrational circular dichroism. The CH2-CH2-C*H fragment
Leo Laux, Vaughan Pultz, S. Abbate, Henry A. Havel, John Overend, Albert Moscowitz, and David A. Lightner
pp 4276 - 4278; DOI:
10.1021/ja00379a052
PDF
Transition metal-promoted carbon-carbon bond formation by reductive dimerization of carbon disulfide: direct synthesis of the bis(1,2-dithiolene-like) tetrathiooxalato (C2S4) ligand from carbon disulfide by reaction with the dimeric nickel(I) complexes Ni2(.eta.5-C5R5)2(.mu.-CO)2 (R = H, Me)
Joseph J. Maj, A. David Rae, and Lawrence F. Dahl
pp 4278 - 4280; DOI:
10.1021/ja00379a053
PDF
Studies of exciplexes in mixed crystals. Activation energy for solid-state photoaddition proceeding via an exciplex
Garry E. Berkovic and Zvi Ludmer
pp 4280 - 4282; DOI:
10.1021/ja00379a054
PDF
New synthetic route to (1R)-trans-chrysanthemic ester and to the (1R)-cis-gem-dibromovinyl analog from a common intermediate
Marie Joelle De Vos and Alain Krief
pp 4282 - 4283; DOI:
10.1021/ja00379a055
PDF
Synthesis and rapid hydrolysis of a 12-membered macrocyclic peptide thiolactone
Shabbir A. Khan and Bruce W. Erickson
pp 4283 - 4285; DOI:
10.1021/ja00379a056
PDF
Homo- and heterodinuclear platinum and palladium complexes with a single unsupported monoatomic bridging group. Crystal structure of the 2,6-bis[(dimethylamino)methyl]phenylpalladium(II) derivative [(Pd{C6H3(CH2NMe2)2-o,o'})2(.mu.-Cl)]BF4
David M. Grove, Gerard Van Koten, Henk J. C. Ubbels, and Anthony L. Spek
pp 4285 - 4286; DOI:
10.1021/ja00379a057
PDF
Multiplet selection in crowded proton NMR spectra via double quantum coherence
P. J. Hore, E. R. P. Zuiderweg, K. Nicolay, K. Dijkstra, and R. Kaptein
pp 4286 - 4288; DOI:
10.1021/ja00379a058
PDF
Molecular and crystal structure of 1,1-bis(tert-butyldimethylsilyl)-2,2-bis(trimethylsilyl)ethylene, the most twisted known olefin, and unusual rearrangement during its preparation
Hideki Sakurai, Hiromi Tobita, Yasuhiro Nakadaira, and Chizuko Kabuto
pp 4288 - 4289; DOI:
10.1021/ja00379a059
PDF
.beta.-Hydroxysulfoximine-directed Simmons-Smith cyclopropanations. Synthesis of (-)- and (+)-thujopsene
Carl R. Johnson and Michael R. Barbachyn
pp 4290 - 4291; DOI:
10.1021/ja00379a060
PDF
Metathesis of tungsten-tungsten triple bonds with acetylenes and nitriles to give alkylidyne and nitrido complexes
Richard R. Schrock, Mark L. Listemann, and Lynda G. Sturgeoff
pp 4291 - 4293; DOI:
10.1021/ja00379a061
PDF
Structure of the glycopeptide antibiotic vancomycin. Evidence for an asparagine residue in the peptide
Constance M. Harris and Thomas M. Harris
pp 4293 - 4295; DOI:
10.1021/ja00379a062
PDF
Synthesis and thermal behavior of 6-methoxytricyclo[5.3.0.02,5]deca-3,6,8,10-tetraene (methoxy-Dewar azulene). Similarity between valence isomers of azulene and benzene
Yoshikazu Sugihara, Takashi Sugimura, and Ichiro Murata
pp 4295 - 4296; DOI:
10.1021/ja00379a063
PDF
Long-distance (25 .ANG.) electron transfer by triplet excited states in rigid media
John R. Miller, Keith W. Hartman, and Sam Abrash
pp 4296 - 4298; DOI:
10.1021/ja00379a064
PDF
Hydrogenation and reduction of nitrogen containing heteroaromatics. Electron transfer and radical induced dimerization of phthalazine
David R. Corbin, Galen D. Stucky, William S. Willis, and Elizabeth G. Sherry
pp 4298 - 4299; DOI:
10.1021/ja00379a065
PDF
2,3-Bis[(trimethylsilyl)methyl]-1,3-butadiene. A conjunctive reagent for tandem Diels-Alder reactions
Barry M. Trost and Makoto Shimizu
pp 4299 - 4301; DOI:
10.1021/ja00379a066
PDF
Ruthenium-containing dimetal complexes of meso-tetrakis(o-nicotinamidophenyl)porphyrin
C. Michael Elliott and R. R. Krebs
pp 4301 - 4303; DOI:
10.1021/ja00379a067
PDF
Direct chiral synthesis of boronic acids and esters of high optical purity via asymmetric hydroboration-displacement
Herbert C. Brown, Prabhakar K. Jadhav, and Manoj C. Desai
pp 4303 - 4304; DOI:
10.1021/ja00379a068
PDF

Issue 16


Magnetic circular dichroism studies. 60. Substituent-induced sign variation in the magnetic circular dichroism spectra of reduced porphyrins. 1. Spectra and band assignments
Joseph D. Keegan, Alan M. Stolzenberg, Yu Cheng Lu, Robert E. Linder, Guenter Barth, Albert Moscowitz, Edward Bunnenberg, and Carl Djerassi
pp 4305 - 4317; DOI:
10.1021/ja00380a001
PDF
Magnetic circular dichroism studies. 61. Substituent-induced sign variation in the magnetic circular dichroism spectra of reduced porphyrins. 2. Perturbed molecular orbital analysis
Joseph D. Keegan, Alan M. Stolzenberg, Yu Cheng Lu, Robert E. Linder, Guenter Barth, Albert Moscowitz, Edward Bunnenberg, and Carl Djerassi
pp 4317 - 4329; DOI:
10.1021/ja00380a002
PDF
Thermochemistry of Group IVA isobutene analogs by pulsed ion cyclotron double resonance spectroscopy
William J. Pietro and Warren J. Hehre
pp 4329 - 4332; DOI:
10.1021/ja00380a003
PDF
NMR spectra of porphyrins. 18. A ring-current model for chlorophyll derivatives
Raymond J. Abraham, Kevin M. Smith, Dane A. Goff, and Jan Ji Lai
pp 4332 - 4337; DOI:
10.1021/ja00380a004
PDF
Vinyl influences on protoheme resonance Raman spectra: nickel(II) protoporphyrin IX with deuterated vinyl groups
S. Choi, T. G. Spiro, K. C. Langry, and K. M. Smith
pp 4337 - 4344; DOI:
10.1021/ja00380a005
PDF
Structural correlations and vinyl influences in resonance Raman spectra of protoheme complexes and proteins
S. Choi, T. G. Spiro, K. C. Langry, K. M. Smith, D. L. Budd, and G. N. La Mar
pp 4345 - 4351; DOI:
10.1021/ja00380a006
PDF
Effects of polar substituents on carbon-silicon multiple bonds
Mark S. Gordon
pp 4352 - 4357; DOI:
10.1021/ja00380a007
PDF
Cytochrome oxidase models. 3. Spin coupling across imidazolate bridges in binuclear metalloporphyrin complexes of iron and copper
Steven E. Dessens, Connie L. Merrill, Robert J. Saxton, Robert L. Ilaria, John W. Lindsey, and Lon J. Wilson
pp 4357 - 4361; DOI:
10.1021/ja00380a008
PDF
Electron-diffraction study of gaseous cyclohexasilane
Zuzana Smith, Arne Almenningen, Edwin Hengge, and Dieter Kovar
pp 4362 - 4366; DOI:
10.1021/ja00380a009
PDF
A new approach to nitrogen fixation. Protonation of dinitrogen ligand by means of hydridometal carbonyls and the synthesis of alkoxide hydrazido(2-) complexes of tungsten with iron and cobalt carbonyl complex anions
Hiroshi Nishihara, Takehiko Mori, Yasushi Tsurita, Koji Nakano, Taro Saito, and Yukiyoshi Sasaki
pp 4367 - 4372; DOI:
10.1021/ja00380a010
PDF
Doubly bridged double cubanes containing MFe3S4 clusters (M = Mo, W). Synthesis, structure, and conversion to spin-quartet single clusters in solution
W. H. Armstrong, P. K. Mascharak, and R. H. Holm
pp 4373 - 4383; DOI:
10.1021/ja00380a011
PDF
The hydrogen oxide bridging ligand (H3O2-). 1. Dimerization and polymerization of hydrolyzed trinuclear metal cluster ions
Avi Bino and Dan Gibson
pp 4383 - 4388; DOI:
10.1021/ja00380a012
PDF
Metal alkoxides: models for metal oxides. 2. Addition of ethyne, propyne, and 2-butyne to Mo2(OR)6 (M.tplbond.M) compounds (R = tert-Bu, iso-Pr, and neopentyl). Characterization of .mu.-alkyne and .mu.-C4H4 adducts and an evaluation of their role in alkyne oligomerization reactions
Malcolm H. Chisholm, Kirsten Folting, John C. Huffman, and Ian P. Rothwell
pp 4389 - 4399; DOI:
10.1021/ja00380a013
PDF
Kinetic applications of electron paramagnetic resonance spectroscopy. 38. Rearrangement of .beta.-(acyloxy)alkyl and .beta.-(benzoyloxy)alkyl radicals
L. R. C. Barclay, D. Griller, and K. U. Ingold
pp 4399 - 4403; DOI:
10.1021/ja00380a014
PDF
Characterization of the 1:1 charge-transfer reaction between decamethylferrocene and 2,3-dichloro-5,6-dicyanoquinone (DDQ): structure of the DDQH- anion
Elizabeth Gebert, A. H. Reis, Joel S. Miller, Heiko Rommelmann, and Arthur J. Epstein
pp 4403 - 4410; DOI:
10.1021/ja00380a015
PDF
Relationship of the anionic behavior of unsaturated medium-ring alcohols to structure. Generation and antarafacial cyclization of coiled 8.pi.-electron carbanions
Leo A. Paquette, Gary D. Crouse, and Ashok K. Sharma
pp 4411 - 4423; DOI:
10.1021/ja00380a016
PDF
Organic photochemistry with 6.7-eV photons: .gamma.,.delta.-unsaturated ketones
William J. Leigh and R. Srinivasan
pp 4424 - 4429; DOI:
10.1021/ja00380a017
PDF
Laser photochemistry: trapping of quinone-olefin preoxetane intermediates with molecular oxygen and chemistry of the resulting 1,2,4-trioxanes
R. Marshall Wilson, Stephen W. Wunderly, Thomas F. Walsh, Arlene K. Musser, Russell Outcalt, Fiona Geiser, Stephen K. Gee, Wayne Brabender, Lario Yerino Jr., and et al.
pp 4429 - 4446; DOI:
10.1021/ja00380a018
PDF
Mild and simple biomimetic conversion of amines to carbonyl compounds
Thomas F. Buckley and Henry Rapoport
pp 4446 - 4450; DOI:
10.1021/ja00380a019
PDF
One-electron chemical reductions of phenylalkylsulfonium salts
Peter Beak and Thomas A. Sullivan
pp 4450 - 4457; DOI:
10.1021/ja00380a020
PDF
Laboratory-scale enzymic/chemical syntheses of D- and L-.beta.-chlorolactic acid and D- and L-potassium glycidate
Bernard L. Hirschbein and George M. Whitesides
pp 4458 - 4460; DOI:
10.1021/ja00380a021
PDF
Cyclophanes. 14. Synthesis, structure assignment, and conformational properties of [2.2](2,5)oxazolo- and thiazolophanes
Sabir H. Mashraqui and Philip M. Keehn
pp 4461 - 4465; DOI:
10.1021/ja00380a022
PDF
Crystal structure of cyclo(Gly-L-Pro-L-Pro-Gly-L-Pro-L-Pro) trihydrate. Unusual conformational characteristics of a cyclic hexapeptide
Matyas Czugler, Kalman Sasvari, and Miklos Hollosi
pp 4465 - 4469; DOI:
10.1021/ja00380a023
PDF
Kinetic studies on the formation of two intramolecular excimers in substituted dinaphthylpropanes
Hideyuki Itagaki, Noriko Obukata, Akio Okamoto, Kazuyuki Horie, and Itaru Mita
pp 4469 - 4477; DOI:
10.1021/ja00380a024
PDF
Fredericamycin A, an antitumor antibiotic of a novel skeletal type
Renuka Misra, Ramesh C. Pandey, and J. V. Silverton
pp 4478 - 4479; DOI:
10.1021/ja00380a025
PDF
Concerning the mechanism of Ziegler-Natta polymerization: isotope effects on propagation rates
Jorge Soto, Michael L. Steigerwald, and Robert H. Grubbs
pp 4479 - 4480; DOI:
10.1021/ja00380a026
PDF
Substituent effects on rates and product distributions in the hydrolysis reactions of naphthalene tetrahydro epoxides. Models for tetrahydro epoxides of polycyclic aromatic hydrocarbons
Richard E. Gillilan, Terese M. Pohl, and Dale L. Whalen
pp 4481 - 4482; DOI:
10.1021/ja00380a027
PDF
The .alpha.- and .beta.-deuterium isotope effects in the hydrolysis of tetrahydronaphthalene epoxides: rate-limiting hydrogen migration in the spontaneous hydrolysis of 6-methoxy-1,2,3,4-tetrahydronaphthalene oxide
Richard E. Gillilan, Terese M. Pohl, and Dale L. Whalen
pp 4482 - 4484; DOI:
10.1021/ja00380a028
PDF
Generation and trapping of terminal phosphinidene complexes. Synthesis and x-ray crystal structure of stable phosphirene complexes
Angela Marinetti, Francois Mathey, Jean Fischer, and Andre Mitschler
pp 4484 - 4485; DOI:
10.1021/ja00380a029
PDF
Peptide conformation. 18. Analysis of the conformational equilibrium of cyclo[Pro-NBGly2] by means of two-dimensional NMR spectroscopy
H. Kessler, R. Schuck, and R. Siegmeier
pp 4486 - 4487; DOI:
10.1021/ja00380a030
PDF
Isolation of an iron-nitrene complex from the dioxygen- and iron porphyrin-dependent oxidation of a hydrazine
D. Mansuy, P. Battioni, and J. P. Mahy
pp 4487 - 4489; DOI:
10.1021/ja00380a031
PDF
Short synthesis of parabactin
Raymond J. Bergeron and Steven J. Kline
pp 4489 - 4492; DOI:
10.1021/ja00380a032
PDF
NMR determination of site-specific deuterium isotope effects
David M. Grant, Janet Curtis, William R. Croasmun, Don K. Dalling, Felix W. Wehrli, and Suzanne Wehrli
pp 4492 - 4494; DOI:
10.1021/ja00380a033
PDF
Tricyclo[5.1.0.02,8]octa-3,5-diene (octavalene)
Manfred Christl and Reinhard Lang
pp 4494 - 4496; DOI:
10.1021/ja00380a034
PDF
Total synthesis of (+)-phyllanthocin
Paul R. McGuirk and David B. Collum
pp 4496 - 4497; DOI:
10.1021/ja00380a035
PDF
Delesserine, a new metabolite of mixed biogenesis from the red marine alga Delesseria sanguinea (Lamouroux)
Jean Claude Yvin, Anne Marie Chevolot-Magueur, Lionel Chevolot, Jean Yves Lallemand, Pierre Potier, and Jean Guilhem
pp 4497 - 4498; DOI:
10.1021/ja00380a036
PDF
Synthesis of a cofacial porphyrin-quinone via entropically favored macropolycyclization
Jonathan S. Lindsey and David C. Mauzerall
pp 4498 - 4500; DOI:
10.1021/ja00380a037
PDF
Pivaloxy decarboxylates less rapidly than propionoxy: steric retardation of the decarboxylation of aliphatic carboxylate radicals
Donald D. May and Philip S. Skell
pp 4500 - 4502; DOI:
10.1021/ja00380a038
PDF
A strategy for the synthesis of monosubstituted dodecahedrane and the isolation of an isododecahedrane
Leo A. Paquette, Robert J. Ternansky, and Douglas W. Balogh
pp 4502 - 4503; DOI:
10.1021/ja00380a039
PDF
Dodecahedrane
Robert J. Ternansky, Douglas W. Balogh, and Leo A. Paquette
pp 4503 - 4504; DOI:
10.1021/ja00380a040
PDF
Total synthesis of (.+-.)-pentalenene
Gary D. Annis and Leo A. Paquette
pp 4504 - 4506; DOI:
10.1021/ja00380a041
PDF

Issue 17


Photoprocesses in diphenylpolyenes. Oxygen and heavy-atom enhancement of triplet yields
S. K. Chattopadhyay, P. K. Das, and G. L. Hug
pp 4507 - 4514; DOI:
10.1021/ja00381a001
PDF
Configuration interaction study of the three lowest electronic states in the formyl and acetyl radicals
Sigrid D. Peyerimhoff, Philip S. Skell, Donald D. May, and Robert J. Buenker
pp 4515 - 4520; DOI:
10.1021/ja00381a002
PDF
Electron-exchange processes by organic solids: an electrochemical solid-state study of a series of TTF radical-cation halides with various stoichiometries
Myriam Lamache, Hubert Menet, and Alec Moradpour
pp 4520 - 4524; DOI:
10.1021/ja00381a003
PDF
An E and C modification of the .beta.-.pi. solvation approach
Peter E. Doan and Russell S. Drago
pp 4524 - 4529; DOI:
10.1021/ja00381a004
PDF
Unusual bonding in trans-bent digermene
Georges Trinquier, Jean Paul Malrieu, and Pierre Riviere
pp 4529 - 4533; DOI:
10.1021/ja00381a005
PDF
Peptide conformations. 15. One- and two-dimensional proton, carbon-13 and nitrogen-15 NMR studies of cyclo(Pro-Phe-Gly-Phe-Gly)n (n = 1, 2): selective complexation of lithium ions (n = 1) and potassium ions (n = 2)
Horst Kessler, Wolfgang Hehlein, and Regina Schuck
pp 4534 - 4540; DOI:
10.1021/ja00381a006
PDF
The oxonium (H3O+) cation: molecular structure of an oxonium-macrocyclic polyether complex
Jean Paul Behr, Philippe Dumas, and Dino Moras
pp 4540 - 4543; DOI:
10.1021/ja00381a007
PDF
Binding and reactivity of thiosulfate dianion in positively charged micelles: a quantitative analysis
Iolanda M. Cuccovia, Regina M. V. Aleixo, Norma E. Erismann, Norbertus T. E. Van der Zee, Shirley Schreier, and Hernan Chaimovich
pp 4544 - 4546; DOI:
10.1021/ja00381a008
PDF
Model-free approach to the interpretation of nuclear magnetic resonance relaxation in macromolecules. 1. Theory and range of validity
Giovanni Lipari and Attila Szabo
pp 4546 - 4559; DOI:
10.1021/ja00381a009
PDF
Model-free approach to the interpretation of nuclear magnetic resonance relaxation in macromolecules. 2. Analysis of experimental results
Giovanni Lipari and Attila Szabo
pp 4559 - 4570; DOI:
10.1021/ja00381a010
PDF
Relative ordering and spacing of n and .pi. levels in isomeric bipyrimidines. A theoretical and gas-phase UV photoelectron spectroscopic study
Vincenzo Barone, Carla Cauletti, Francesco Lelj, Maria Novella Piancastelli, and Nino Russo
pp 4571 - 4578; DOI:
10.1021/ja00381a011
PDF
Oxidative addition of hydrogen to bis(phosphine)platinum(0) complexes: an ab initio theoretical treatment
J. Oakey Noell and P. Jeffrey Hay
pp 4578 - 4584; DOI:
10.1021/ja00381a012
PDF
Quantum and statistical mechanical studies of liquids. 21. The nature of dilute solutions of sodium and methoxide ions in methanol
William L. Jorgensen, Bernard Bigot, and Jayaraman Chandrasekhar
pp 4584 - 4591; DOI:
10.1021/ja00381a013
PDF
The importance of van der Waals attractions in determining the equilibrium between 1,4- and 1,6-dialkylcyclooctatetraenes
N. L. Allinger, M. Frierson, and F. A. Van-Catledge
pp 4592 - 4593; DOI:
10.1021/ja00381a014
PDF
Electron-transfer rates in mixed-valence europium sulfide by time domain reflectometry
Bruce C. Bunker, Russell S. Drago, and Michael K. Kroeger
pp 4593 - 4598; DOI:
10.1021/ja00381a015
PDF
Syntheses, kinetics, and mechanism of formation of polynuclear hydroxo-bridged complexes of (trans-1,2-diaminocyclohexane)platinum(II)
Devinder S. Gill and Barnett Rosenberg
pp 4598 - 4604; DOI:
10.1021/ja00381a016
PDF
An efficient total synthesis of (.+-.)-aklavinone
Robert K. Boeckman and F. W. Sum
pp 4604 - 4610; DOI:
10.1021/ja00381a017
PDF
Resolution of conglomerates with the assistance of tailor-made impurities. Generality and mechanistic aspects of the "rule of reversal". A new method for assignment of absolute configuration
L. Addadi, S. Weinstein, E. Gati, I. Weissbuch, and M. Lahav
pp 4610 - 4617; DOI:
10.1021/ja00381a018
PDF
Kinetic resolution of racemic .alpha.-methylbenzyl methacrylate: asymmetric selective polymerization catalyzed by Grignard reagent-(-)-sparteine derivative complexes
Yoshio Okamoto, Koichi Suzuki, Tatsuki Kitayama, Heimei Yuki, Hiroyuki Kageyama, Kunio Miki, Nobuo Tanaka, and Nobutami Kasai
pp 4618 - 4624; DOI:
10.1021/ja00381a019
PDF
Acyl transfer reactions in the gas phase. Ion-molecule chemistry of vinyl acetate
Jhong K. Kim and Marjorie C. Caserio
pp 4624 - 4629; DOI:
10.1021/ja00381a020
PDF
Chain decomposition of hydrogen peroxide induced by catalytic levels of reduced 5-methylphenazinium and metal ions: a nonclassical Fenton system
Helen W. Richter and Walter H. Waddell
pp 4630 - 4634; DOI:
10.1021/ja00381a021
PDF
Surface photochemistry: translational motion of organic molecules adsorbed on silica gel and its consequences
Richard K. Bauer, Raphaela Borenstein, Paul De Mayo, Keiji Okada, Maria Rafalska, William R. Ware, and Kam C. Wu
pp 4635 - 4644; DOI:
10.1021/ja00381a022
PDF
Naphthonitrile-alkene exciplexes. Comparison of bimolecular and bichromophoric cases: effects of linking on fluorescence and photochemistry
John J. McCullough, W. Keith MacInnis, Colin J. L. Lock, and Rommulo Faggiani
pp 4644 - 4658; DOI:
10.1021/ja00381a023
PDF
Enzymes in organic synthesis. 24. Preparations of enantiomerically pure chiral lactones via stereospecific horse liver alcohol dehydrogenase catalyzed oxidations of monocyclic meso diols
Ignac J. Jakovac, H. Bruce Goodbrand, Kar P. Lok, and J. Bryan Jones
pp 4659 - 4665; DOI:
10.1021/ja00381a024
PDF
Enzymes in organic synthesis. 25. Heterocyclic ketones as substrates of horse liver alcohol dehydrogenase. Highly stereoselective reductions of 2-substituted tetrahydropyran-4-ones
J. Anthony Haslegrave and J. Bryan Jones
pp 4666 - 4671; DOI:
10.1021/ja00381a025
PDF
Observations on the geometry of hydrogen transfer in [1,5] sigmatropic rearrangements
H. Kwart, M. W. Brechbiel, R. M. Acheson, and D. C. Ward
pp 4671 - 4672; DOI:
10.1021/ja00381a026
PDF
Effects of 15-crown-5 on reactions of dialkylmagnesium compounds
Herman G. Richey and Bruce A. King
pp 4672 - 4674; DOI:
10.1021/ja00381a027
PDF
Cyclopropenyl, dimethylcyclopropenyl, and trimethylcyclopropenyl radicals
R. Sutcliffe, D. A. Lindsay, D. Griller, J. C. Walton, and K. U. Ingold
pp 4674 - 4676; DOI:
10.1021/ja00381a028
PDF
The origin of oxonitine: a potassium permanganate oxidation product of aconitine
S. William Pelletier, Jan A. Glinski, and Naresh V. Mody
pp 4676 - 4677; DOI:
10.1021/ja00381a029
PDF
Intrinsic steric deuterium/hydrogen isotope effects on carbon-13 shieldings: dihedral angular dependence of shifts over three bonds in saturated systems
Jeffrey L. Jurlina and J. B. Stothers
pp 4677 - 4678; DOI:
10.1021/ja00381a030
PDF
Synthesis and structure determination of Os3[1,2-.mu.-H;1,2-.mu.-O:C(Me)][1-C(OMe)Me][CO)9: the first cluster complex containing a Fischer-type carbene group
C. M. Jensen, T. J. Lynch, C. B. Knobler, and H. D. Kaesz
pp 4679 - 4680; DOI:
10.1021/ja00381a031
PDF
Dichlorine monoxide: a powerful and selective chlorinating reagent
F. D. Marsh, W. B. Farnham, D. J. Sam, and B. E. Smart
pp 4680 - 4682; DOI:
10.1021/ja00381a032
PDF
Phospholipids chiral at phosphorus. 2. Preparation, property, and application of chiral thiophospholipids
Karol Bruzik, Sanjeev M. Gupte, and Ming Daw Tsai
pp 4682 - 4684; DOI:
10.1021/ja00381a033
PDF
Bis[benzylbis(dimethylamido)molybdenum] and -tungsten (M.tplbond.M) compounds and their reactions with carbon dioxide and 1,3-diaryltriazenes. A radical difference
M. J. Chetcuti, M. H. Chisholm, K. Folting, J. C. Huffman, and J. Janos
pp 4684 - 4686; DOI:
10.1021/ja00381a034
PDF
Stereoselective synthesis of the chiral sequence of erythronolide A
Gilbert Stork, Ian Paterson, and Ferdinand K. C. Lee
pp 4686 - 4688; DOI:
10.1021/ja00381a035
PDF
(E)-Bicyclo[3.3.1]non-1-ene
John R. Wiseman and James E. Kipp
pp 4688 - 4689; DOI:
10.1021/ja00381a036
PDF
A simple relationship between carbocation lifetime and reactivity-selectivity relationships for the solvolysis of ring-substituted 1-phenylethyl derivatives
John P. Richard and William P. Jencks
pp 4689 - 4691; DOI:
10.1021/ja00381a037
PDF
Concerted SN2 displacement reactions of 1-phenylethyl chlorides
John P. Richard and William P. Jencks
pp 4691 - 4692; DOI:
10.1021/ja00381a038
PDF
Actinide tris(hydrocarbyls). Synthesis, properties, structure, and molecular dynamics of thorium and uranium pentamethylcyclopentadienyltris(.eta.n-benzyls)
Eric A. Mintz, Kenneth G. Moloy, Tobin J. Marks, and Victor W. Day
pp 4692 - 4695; DOI:
10.1021/ja00381a039
PDF
Fluoride-promoted, dye-sensitized photooxidation of enols
Harry H. Wasserman and James E. Pickett
pp 4695 - 4696; DOI:
10.1021/ja00381a040
PDF
Chemistry of higher order, mixed organocuprates. 4. The stereochemical outcome of substitution reactions at unactivated secondary centers using organocopper reagents
Bruce H. Lipshutz and Robert S. Wilhelm
pp 4696 - 4698; DOI:
10.1021/ja00381a041
PDF
6-Methyl-1,6-diazabicyclo[6.2.2]dodecane: an inside, outside six-atom bridged boat piperidine
Stephen F. Nelsen and Peter M. Gannett
pp 4698 - 4700; DOI:
10.1021/ja00381a042
PDF
Metal-templated synthesis of a macrocyclic triphosphine-molybdenum complex, fac-(CO)3Mo(PHC3H6)3
Bruce N. Diel, R. Curtis Haltiwanger, and Arlan D. Norman
pp 4700 - 4701; DOI:
10.1021/ja00381a043
PDF
Cleavage of the triple bond in phenylacetylene by monomeric ruthenium(II) and osmium(II) complexes. Formation of stable ruthenium(II) alkyls from terminal alkynes
B. Patrick Sullivan, Robert S. Smythe, Edward M. Kober, and Thomas J. Meyer
pp 4701 - 4703; DOI:
10.1021/ja00381a044
PDF
Iron EXAFS of the iron-molybdenum cofactor of nitrogenase
Mark R. Antonio, Boon Keng Teo, W. H. Orme-Johnson, Mark J. Nelson, Susan E. Groh, Paul A. Lindahl, Susan M. Kauzlarich, and Bruce A. Averill
pp 4703 - 4705; DOI:
10.1021/ja00381a045
PDF
Nucleophilic addition of phenolate oxygen to an unactivated carbon-carbon double bond
Christopher M. Evans and Anthony J. Kirby
pp 4705 - 4706; DOI:
10.1021/ja00381a046
PDF
A very large stereoelectronic effect on acetal cleavage
Christopher M. Evans, Robert Glenn, and Anthony J. Kirby
pp 4706 - 4707; DOI:
10.1021/ja00381a047
PDF
Crystal and molecular structure of a free-base N-methylporphyrin; N-methyl-5,10,15,20-tetra(p-bromophenyl)porphyrin
David K. Lavallee and Oren P. Anderson
pp 4707 - 4708; DOI:
10.1021/ja00381a048
PDF
Total synthesis of milbemycin .beta.3
D. R. Williams, B. A. Barner, K. Nishitani, and J. G. Phillips
pp 4708 - 4710; DOI:
10.1021/ja00381a049
PDF
Iron-57 ENDOR of the nitrogenase molybdenum-iron protein
Brian M. Hoffman, Ronald A. Venters, James E. Roberts, Mark Nelson, and W. H. Orme-Johnson
pp 4711 - 4712; DOI:
10.1021/ja00381a050
PDF
Carbon-carbon bond formation by reductive coupling of two carbonyl ligands of binuclear transition metal complexes
Donald H. Berry, John E. Bercaw, Alan J. Jircitano, and Kristin B. Mertes
pp 4712 - 4715; DOI:
10.1021/ja00381a051
PDF
The structure of the nitric oxide dimer
Stephen G. Kukolich
pp 4715 - 4716; DOI:
10.1021/ja00381a052
PDF
Atom connectivities in polyhedral boranes elucidated via two-dimensional J-correlated boron-11-boron-11 FT NMR: a general method
T. Leon Venable, William C. Hutton, and Russell N. Grimes
pp 4716 - 4717; DOI:
10.1021/ja00381a053
PDF
Germanium-hydrogen bond strengths in germanes
Matthew J. Almond, Alan M. Doncaster, Paul N. Noble, and Robin Walsh
pp 4717 - 4718; DOI:
10.1021/ja00381a054
PDF
Microbial degradation of the phytosterol side chain. I. Enzymic conversion of 3-oxo-24-ethylcholest-4-en-26-oic acid into 3-oxochol-4-en-24-oic acid and androst-4-ene-3,17-dione
Yoshinori Fujimoto, Ching Shih Chen, Zoltan Szeleczky, Dennis Ditullio, and Charles J. Sih
pp 4718 - 4720; DOI:
10.1021/ja00381a055
PDF
Microbial degradation of the phytosterol side chain. II. Incorporation of [14C]-NaHCO3 onto the C-28 position
Yoshinori Fujimoto, Ching Shih Chen, Aravamudan S. Gopalan, and Charles J. Sih
pp 4720 - 4722; DOI:
10.1021/ja00381a056
PDF
Symmetrical intermediates in C9H12 biradical rearrangements. Possible intervention of an organic tetraradical
Lisa McElwell-White and Dennis A. Dougherty
pp 4722 - 4724; DOI:
10.1021/ja00381a057
PDF
.alpha.-Lithiomethylenetriphenylphosphorane, a highly reactive ylide equivalent
E. J. Corey and Jahyo Kang
pp 4724 - 4725; DOI:
10.1021/ja00381a058
PDF
Intramolecular Diels-Alder reaction of an isobenzofuran: a convergent synthesis of resistomycin
B. A. Keay and R. Rodrigo
pp 4725 - 4727; DOI:
10.1021/ja00381a059
PDF
"Triple-decker sandwich" with a planar As5 ring. Synthesis and crystal structure of CpMo[.mu.-(.eta.4-As5)]MoCp
Arnold L. Rheingold, Michael J. Foley, and Patrick J. Sullivan
pp 4727 - 4729; DOI:
10.1021/ja00381a060
PDF
Mechanism-based inactivation of 4-methylsterol oxidase by 4.alpha.-cyanomethyl-5.alpha.-cholestan-3.beta.-ol
Desiree L. Bartlett and Cecil H. Robinson
pp 4729 - 4730; DOI:
10.1021/ja00381a061
PDF
Xanthine oxidase initiated oxidation of model membranes. Effect of position of abstractable hydrogen atoms in the bilayer on the distribution of products
Ned A. Porter and Laura S. Lehman
pp 4731 - 4732; DOI:
10.1021/ja00381a062
PDF
Book Reviews

pp 4733 - 4740; DOI:
10.1021/ja00381a600
PDF

Issue 18


Kinetics of free radicals produced by infrared multiphoton-induced decomposition. 2. Formation of acetyl and dichlorofluoromethyl radicals and their reactions with nitrogen dioxide
Irene R. Slagle and David Gutman
pp 4741 - 4748; DOI:
10.1021/ja00382a001
PDF
Bifurcated hydrogen bond and large amplitude vibrations in glycine methyl ester
Walther Caminati and Rinaldo Cervellati
pp 4748 - 4752; DOI:
10.1021/ja00382a002
PDF
A study of the unimolecular decomposition of the (C2H2)3+ complex
Y. Ono and C. Y. Ng
pp 4752 - 4758; DOI:
10.1021/ja00382a003
PDF
Electronic structure of bridged dialuminum compounds
J. M. Howell, A. M. Sapse, E. Singman, and G. Snyder
pp 4758 - 4759; DOI:
10.1021/ja00382a004
PDF
CIDNP and triplet-state reactivity of biradicals
F. J. J. De Kanter and R. Kaptein
pp 4759 - 4766; DOI:
10.1021/ja00382a005
PDF
Spectroelectrochemistry and electrochemical preparation method of Prussian blue modified electrodes
Kingo Itaya, Tatsuaki Ataka, and Shinobu Toshima
pp 4767 - 4772; DOI:
10.1021/ja00382a006
PDF
Gas- and liquid-phase reaction of free phenylium cation with methanol
Giancarlo Angelini, Simonetta Fornarini, and Maurizio Speranza
pp 4773 - 4780; DOI:
10.1021/ja00382a007
PDF
Aromaticity in three dimensions. 4. Influence of orbital compatibility on the geometry and stability of capped annulene rings with six interstitial electrons
Eluvathingal D. Jemmis and Paul von Rague Schleyer
pp 4781 - 4788; DOI:
10.1021/ja00382a008
PDF
Transient Raman scattering study of the initial semiquinone radical kinetics following photolysis of aqueous benzoquinone and hydroquinone
S. M. Beck and L. E. Brus
pp 4789 - 4792; DOI:
10.1021/ja00382a009
PDF
Solvent dielectric attenuation of substituent effects. Field transmission dependence on cavity boundary representation
S. Ehrenson
pp 4793 - 4798; DOI:
10.1021/ja00382a010
PDF
Polyelectrolyte-enhanced excimer formation of bis(.alpha.-naphthylmethyl)ammonium chloride and (.alpha.-naphthylmethyl)ammonium chloride
Nicholas J. Turro, Tsuneo Okubo, Chao Jen Chung, Jack Emert, and Robert Catena
pp 4799 - 4803; DOI:
10.1021/ja00382a011
PDF
Photochemistry of tris(2,2'-bipyridine)ruthenium(2+) ion
Bill Durham, Jonathan V. Caspar, Jeffrey K. Nagle, and Thomas J. Meyer
pp 4803 - 4810; DOI:
10.1021/ja00382a012
PDF
Polymer films on electrodes. 8. Investigation of charge-transport mechanisms in Nafion polymer modified electrodes
Henry S. White, Johna Leddy, and Allen J. Bard
pp 4811 - 4817; DOI:
10.1021/ja00382a013
PDF
Polymer films on electrodes. 9. Electron and mass transfer in Nafion films containing tris(2,2'-bipyridine)ruthenium(2+)
Charles R. Martin, Israel Rubinstein, and Allen J. Bard
pp 4817 - 4824; DOI:
10.1021/ja00382a014
PDF
Electrochemical control of the luminescent lifetime of Ru(bpy)32+* incorporated in Nafion films on graphite electrodes
Daniel A. Buttry and Fred C. Anson
pp 4824 - 4829; DOI:
10.1021/ja00382a015
PDF
Intramolecular potential functions from observed crystal structures. 1. 1,3,5-Triphenylbenzene, p,p'-bitolyl, 1,1'-binaphthyl, and o-terphenyl
William R. Busing
pp 4829 - 4836; DOI:
10.1021/ja00382a016
PDF
The thio analog of peroxynitrite, [SSNS]-: preparation, electronic structure, resonance Raman spectrum, and formation of complexes with nickel and cobalt
J. Bojes, T. Chivers, W. G. Laidlaw, and M. Trsic
pp 4837 - 4841; DOI:
10.1021/ja00382a017
PDF
2-Cyclopropene-1-carbonyl compounds of rhenium, manganese, and iron. A facile route to nonfluxional 3-.eta.1-cyclopropenyl compounds of rhenium
D. Michael DeSimone, Peter J. Desrosiers, and Russell P. Hughes
pp 4842 - 4846; DOI:
10.1021/ja00382a018
PDF
Mechanism of formation of (.eta.3-oxocyclobutenyl)cobalt compounds from [Co(CO)4]- and cyclopropenium cations
William A. Donaldson and Russell P. Hughes
pp 4846 - 4859; DOI:
10.1021/ja00382a019
PDF
Characterization of the silicon-aluminum distribution in synthetic faujasites by high-resolution solid-state silicon-29 NMR
M. T. Melchior, D. E. W. Vaughan, and A. J. Jacobson
pp 4859 - 4864; DOI:
10.1021/ja00382a020
PDF
Synthesis and properties of [(.eta.-C5H5)Re(NO)(PPh3)(:CHC6H5)]+PF6-: a benzylidene complex that is formed by a stereospecific .alpha.-hydride abstraction, exists as two geometric isomers, and undergoes stereospecific nucleophilic attack
William A. Kiel, Gong Yu Lin, Anthony G. Constable, Fred B. McCormick, Charles E. Strouse, Odile Eisenstein, and J. A. Gladysz
pp 4865 - 4878; DOI:
10.1021/ja00382a021
PDF
Crystal and molecular structures of tert-butyltetrakis(dimethylamido)tantalum(V), bromo(p-tolyl)tris(dimethylamido)tantalum(V), and [(trimethylsilyl)methyl]tetrakis(N,N-dimethylcarbamato)tantalum(V). Evidence for stabilization of .sigma.-alkyl ligands by strongly .pi.-donating ligands in early transition metal chemistry
Malcolm H. Chisholm, Loon Seng Tan, and John C. Huffman
pp 4879 - 4884; DOI:
10.1021/ja00382a022
PDF
Hydration and hydrolysis of methyl pyruvate. A bifunctional probe of chemical and enzymic catalysis
Y. Pocker, J. E. Meany, and Ronald C. Jones
pp 4885 - 4889; DOI:
10.1021/ja00382a023
PDF
Reaction of a benzvalene with sulfur dioxide. A chemical cascade
H. Hogeveen and L. Zwart
pp 4889 - 4895; DOI:
10.1021/ja00382a024
PDF
Reactivity-selectivity correlations. 4. The .alpha. effect in SN2 reactions at sp3 carbon. The reactions of hydrogen peroxide anion with methyl phenyl sulfates
Erwin Buncel, Harold Wilson, and Claudio Chuaqui
pp 4896 - 4900; DOI:
10.1021/ja00382a025
PDF
Mechanistic study of thermal Z-E isomerization of azobenzenes by high-pressure kinetics
Tsutomu Asano, Toshio Yano, and Toshio Okada
pp 4900 - 4904; DOI:
10.1021/ja00382a026
PDF
Rate control by restricting mobility of substrate in specific reaction field. Negative photochromism of water-soluble spiropyran in AOT reversed micelles
Junzo Sunamoto, Kiyoshi Iwamoto, Masashi Akutagawa, Masahiro Nagase, and Hiroki Kondo
pp 4904 - 4907; DOI:
10.1021/ja00382a027
PDF
Hydroboration kinetics. 4. Kinetics and mechanism of the reaction of 9-borabicyclo[3.3.1]nonane with representative haloalkenes. The effect of halogen substitution upon the rate of hydroboration
Donna J. Nelson and Herbert C. Brown
pp 4907 - 4912; DOI:
10.1021/ja00382a028
PDF
Hydroboration kinetics. 5. Kinetics of the reaction of 9-borabicyclo[3.3.1]nonane with representative haloalkynes in carbon tetrachloride. The effect of halogen substitution upon the stoichiometry and rate of hydroboration
Donna J. Nelson, Clarence D. Blue, and Herbert C. Brown
pp 4913 - 4917; DOI:
10.1021/ja00382a029
PDF
Cobalt-mediated 1,4-acylation/alkylation of 1,3-dienes
Louis S. Hegedus and Yoshio Inoue
pp 4917 - 4921; DOI:
10.1021/ja00382a030
PDF
Kinetics and mechanism of the stepwise dissociation of iron(III) from ferrioxamine B in aqueous acid
Bruce Monzyk and Alvin L. Crumbliss
pp 4921 - 4929; DOI:
10.1021/ja00382a031
PDF
Treflorine, trenudine, and N-methyltrenudone: novel maytansinoid tumor inhibitors containing two fused macrocyclic rings
Richard G. Powell, David Weisleder, Cecil R. Smith, John Kozlowski, and William K. Rohwedder
pp 4929 - 4934; DOI:
10.1021/ja00382a032
PDF
Thiamin biosynthesis in yeast. Origin of the five-carbon unit of the thiazole moiety
Robert L. White and Ian D. Spenser
pp 4934 - 4943; DOI:
10.1021/ja00382a033
PDF
Proton NMR study of cobalt(II)-substituted carboxypeptidase A
Ivano Bertini, G. Canti, and C. Luchinat
pp 4943 - 4946; DOI:
10.1021/ja00382a034
PDF
A synthetic isorhodopsin formed with a retinal derivative lacking an intact ring
Rosalie K. Crouch
pp 4946 - 4948; DOI:
10.1021/ja00382a035
PDF
Syntheses and reactions of rhenium vinylidene and acetylide complexes. Unprecedented chirality transfer through a C.tplbond.C triple bond
Andrew Wong and J. A. Gladysz
pp 4948 - 4950; DOI:
10.1021/ja00382a036
PDF
Hydrocarbation: addition of the carbon-hydrogen bond of a cationic bridging iron-methylidyne complex to alkenes
Charles P. Casey and Paul J. Fagan
pp 4950 - 4951; DOI:
10.1021/ja00382a037
PDF
Carbonyl ylides from aldehydes and carbenes
Pedro de March and Rolf Huisgen
pp 4952 - 4952; DOI:
10.1021/ja00382a038
PDF
Three-component reactions of diazomalonic ester, benzaldehyde, and electrophilic olefins
Rolf Huisgen and Pedro De March
pp 4953 - 4954; DOI:
10.1021/ja00382a039
PDF
Chemistry of the energy-rich m-quinomethane system. Formal [3 + 2] cycloadditions to olefins via a singlet intermediate
Albert R. Matlin, Thomas A. Inglin, and Jerome A. Berson
pp 4954 - 4955; DOI:
10.1021/ja00382a040
PDF
Photolysis of dirhenium decacarbonyl in the presence of simple olefins. Reactions of (.mu.-hydrido)(.mu.-alkenyl)dirhenium carbonyl compounds
Philip O. Nubel and Theodore L. Brown
pp 4955 - 4957; DOI:
10.1021/ja00382a041
PDF
Stereocontrolled total synthesis of (.+-.)-saframycin B
Tohru Fukuyama and Richard A. Sachleben
pp 4957 - 4958; DOI:
10.1021/ja00382a042
PDF
The effect of redox site concentration on the rate of electron transport in a redox copolymer film
J. S. Facci, R. H. Schmehl, and Royce W. Murray
pp 4959 - 4960; DOI:
10.1021/ja00382a043
PDF
Generation of superoxide in a cobalt(II) tetraphenylporphyrin-thiolate-oxygen system
Hiromu Sakurai and Kazuhiko Ishizu
pp 4960 - 4962; DOI:
10.1021/ja00382a044
PDF
Optically active allylsilanes. 1. Preparation by palladium-catalyzed asymmetric Grignard cross-coupling and anti stereochemistry in electrophilic substitution reactions
Tamio Hayashi, Mitsuo Konishi, Hiroshi Ito, and Makoto Kumada
pp 4962 - 4963; DOI:
10.1021/ja00382a045
PDF
Optically active allylsilanes. 2. High stereoselectivity in asymmetric reaction with aldehydes producing homoallylic alcohols
Tamio Hayashi, Mitsuo Konishi, and Makoto Kumada
pp 4963 - 4965; DOI:
10.1021/ja00382a046
PDF
Stereocontrolled total synthesis of (.+-.)-coriamyrtin
Kiyoshi Tanaka, Fumiaki Uchiyama, Kiyoshi Sakamoto, and Yasuo Inubushi
pp 4965 - 4967; DOI:
10.1021/ja00382a047
PDF
Enantiomeric selectivity in binding tris(phenanthroline)zinc(II) to DNA
Jacqueline K. Barton, J. J. Dannenberg, and Adrienne L. Raphael
pp 4967 - 4969; DOI:
10.1021/ja00382a048
PDF
Biosynthesis of the antitumor antibiotic naphthyridinomycin
Milton J. Zmijewski, Marcia Mikolajczak, Venkatappa Viswanatha, and Victor J. Hruby
pp 4969 - 4971; DOI:
10.1021/ja00382a049
PDF
Composition of elemental sulfur in solution: equilibrium of S6, S7 and S8 at ambient temperatures
Fred N. Tebbe, E. Wasserman, William G. Peet, Arturs Vatvars, and Alan C. Hayman
pp 4971 - 4972; DOI:
10.1021/ja00382a050
PDF
Carbanion-accelerated Claisen rearrangements
S. E. Denmark and M. A. Harmata
pp 4972 - 4974; DOI:
10.1021/ja00382a051
PDF
Origin of Huisgen's factor x: staggering of allylic bonds promotes anomalously rapid exo attack on norbornenes
Nelson G. Rondan, Michael N. Paddon-Row, Pierluigi Caramella, Jiri Mareda, Paul H. Mueller, and K. N. Houk
pp 4974 - 4976; DOI:
10.1021/ja00382a052
PDF
Highly stereoselective approaches to .alpha.- and .beta.-C-glycopyranosides
Michael D. Lewis, Jin Kun Cha, and Yoshito Kishi
pp 4976 - 4978; DOI:
10.1021/ja00382a053
PDF
Enantioselective synthesis and absolute configuration of (-)-.alpha.-kainic acid
Wolfgang Oppolzer and Klaus Thirring
pp 4978 - 4979; DOI:
10.1021/ja00382a054
PDF
New geometric isomers of vitamin A and carotenoids. XI. 19,19,19-Trifluororetinal and 20,20,20-trifluororetinal
Alfred E. Asato, Dennis Mead, Marlene Denny, T. T. Bopp, and R. S. H. Liu
pp 4979 - 4981; DOI:
10.1021/ja00382a055
PDF
Fused thiirene sulfoxides. Synthesis via [2 + 4] cycloaddition of thiiranoradialene sulfoxide and structural characterization
Wataru Ando, Yukio Hanyu, Toshikazu Takata, and Katsuhiko Ueno
pp 4981 - 4982; DOI:
10.1021/ja00382a056
PDF
The preparation and study of a low potential flavin analog
Edward B. Skibo and Thomas C. Bruice
pp 4982 - 4984; DOI:
10.1021/ja00382a057
PDF
A carbonate receptor model by macromonocyclic polyamines and its physiological implications
Eiichi Kimura, Atsuko Sakonaka, and Mutsuo Kodama
pp 4984 - 4985; DOI:
10.1021/ja00382a058
PDF
Cooperativity in chemical model systems: Ligand-induced subunit dimerization
T. G. Traylor, M. J. Mitchell, J. P. Ciccone, and S. Nelson
pp 4986 - 4989; DOI:
10.1021/ja00382a059
PDF
Preparation and spectroelectrochemical characterization of silicon electrodes modified with molybdenum dinitrogen complexes
Daniel L. DuBois and John A. Turner
pp 4989 - 4990; DOI:
10.1021/ja00382a060
PDF
Cyclohexenones by the Barton fragmentation of tertiary alcohols derived from furanone/alkene photoadducts
S. W. Baldwin and H. R. Blomquist
pp 4990 - 4992; DOI:
10.1021/ja00382a061
PDF
Sonochemical and electrochemical synthesis of tetramesityldisilene
Philip Boudjouk, Byung Hee Han, and Kevin R. Anderson
pp 4992 - 4993; DOI:
10.1021/ja00382a062
PDF
Complete analysis of oligosaccharide primary structure using two-dimensional high-field proton NMR
James H. Prestegard, Theodore A. W. Koerner, Peter C. Demou, and Robert K. Yu
pp 4993 - 4995; DOI:
10.1021/ja00382a063
PDF
Photosensitized [4 + 4] cycloreversion of anthracene dimer via an electron-transfer mechanism
Richard A. Barber, Paul De Mayo, Keiji Okada, and S. King Wong
pp 4995 - 4997; DOI:
10.1021/ja00382a064
PDF
Stereocontrolled total synthesis of (.+-.)-maytansinol
Minoru Isobe, Masato Kitamura, and Toshio Goto
pp 4997 - 4999; DOI:
10.1021/ja00382a065
PDF
Microwave structure determination for the furan-hydrogen chloride complex
James A. Shea and Stephen G. Kukolich
pp 4999 - 5000; DOI:
10.1021/ja00382a066
PDF
Intramolecular exciplexes of polychromophoric molecules
James R. Larson, Jacob W. Petrich, and Nienchu C. Yang
pp 5000 - 5002; DOI:
10.1021/ja00382a067
PDF
Measurement of spin-spin distances from the intensity of the EPR half-field transition
Sandra S. Eaton and Gareth R. Eaton
pp 5002 - 5003; DOI:
10.1021/ja00382a068
PDF
Additions and Corrections - Total Synthesis of Antitumor Agent AT-125(αS,5S)-α-Amino-3-chloro-4,5-dihydro-5-isoxazoleacetic Acid
Jack E. Baldwin, Lawrence I. Kruse, and Jin-Kun Cha
pp 5004 - 5004; DOI:
10.1021/ja00382a600
PDF
Additions and Corrections - Pentamethylcyclopentadienyl-Substituted Phosphorous and Arsenic Cations: Evidence for Multihapto Bonding between Group 5A Elements and Carbocyclic Ligands
S. G .Baxter, A. H. Cowley, and S. K. Mehrotra
pp 5004 - 5004; DOI:
10.1021/ja00382a601
PDF
Additions and Corrections - Antimicrobial Metabolites of the Sponge Reniera sp.
James M. Frincke, and D. John Faulkner
pp 5004 - 5004; DOI:
10.1021/ja00382a602
PDF
Additions and Corrections - Studies of Hydrogen-Bonded 5'-Guanosine Monophosphate Self-Associates Using Low-Frequency Raman Scattering
O. Faurskov Nielsen, P. A. Lund, and Steffen B. Petersen
pp 5004 - 5004; DOI:
10.1021/ja00382a603
PDF
Additions and Corrections - Reactions of Bi(cyclophosphophazenes) with Sodium Alkoxides or Aryl Oxides
Harry R. Allcock, Mark S. Connolly, and Paul J. Harris
pp 5004 - 5004; DOI:
10.1021/ja00382a604
PDF
Additions and Corrections - The Use of "Enantiopolar" Directions in Centrosymmetric Crystals for Direct Assignment of Absolute Configuration of Chiral Molecules: Application of the System Serine/Threonine
L. Addadi, Z. Berkovitch-Yellin, I. Weissbuch, M. Lahav, L. Leiserowitz, and S. Weinstein
pp 5004 - 5004; DOI:
10.1021/ja00382a605
PDF
Additions and Corrections - End-to-End Cyclization of Hydrocarbon Chains. Photochemical and Computer Simulation Studies.
Andrew Mar, Simon Frasier, and Mitchell A, Winnik
pp 5004 - 5004; DOI:
10.1021/ja00382a606
PDF
Book Reviews

pp 5005 - 5006; DOI:
10.1021/ja00382a607
PDF

Issue 19


NMR studies of self-association of disodium guanosine 5'-monophosphate
Steffen B. Petersen, Jens J. Led, Eric R. Johnston, and David M. Grant
pp 5007 - 5015; DOI:
10.1021/ja00383a001
PDF
Photoionization study of the heat of formation of HCS+
James J. Butler and Tomas Baer
pp 5016 - 5018; DOI:
10.1021/ja00383a002
PDF
Correlations between core photoionization energies (EB1s) and gas-phase basicity. A general method for determining sites of protonation and intramolecular ion reorganization energies
J. M. Buschek, F. S. Joergensen, and R. S. Brown
pp 5019 - 5025; DOI:
10.1021/ja00383a003
PDF
Laser photoelectron spectrometry of Ni(CO)n-, n = 1-3
Amy E. Stevens, C. S. Feigerle, and W. C. Lineberger
pp 5026 - 5031; DOI:
10.1021/ja00383a004
PDF
Observation of some transition metal complexes in solution by electrohydrodynamic ionization mass spectrometry
Kelvin W. S. Chan and Kelsey D. Cook
pp 5031 - 5034; DOI:
10.1021/ja00383a005
PDF
Rotation about the carbonyl carbon-nitrogen bond in micelles of N-(dodecyloxycarbonyl)sarcosinate
J. T. Gerig, D. H. Peyton, and D. F. Nicoli
pp 5034 - 5039; DOI:
10.1021/ja00383a006
PDF
Self-consistent molecular orbital methods. 24. Supplemented small split-valence basis sets for second-row elements
W. J. Pietro, M. M. Francl, W. J. Hehre, D. J. DeFrees, J. A. Pople, and J. S. Binkley
pp 5039 - 5048; DOI:
10.1021/ja00383a007
PDF
Micellar dediazoniation: dramatic directive effects on the course of reaction
Robert A. Moss, Frank M. Dix, and Laurence Romsted
pp 5048 - 5050; DOI:
10.1021/ja00383a008
PDF
Primary amide hydrogen exchange in model amino acids: asparagine, glutamine, and glycine amides
N. Rama Krishna, K. Partha Sarathy, Dee Hua Huang, Richard L. Stephens, Jerry D. Glickson, Clark W. Smith, and Roderich Walter
pp 5051 - 5053; DOI:
10.1021/ja00383a009
PDF
Primary event in the thermal dehydrochlorination of pristine poly(vinyl chloride): intermediacy of a cyclic chloronium ion
Krishnan Raghavachari, Robert C. Haddon, and William H. Starnes
pp 5054 - 5056; DOI:
10.1021/ja00383a010
PDF
Electron-transfer reactions and associated conformational changes. Extended redox series for some bianthrones, lucigenin, and dixanthylene
Dennis H. Evans and Robert W. Busch
pp 5057 - 5062; DOI:
10.1021/ja00383a011
PDF
Crystallographic evidence for the existence of CH.cntdot..cntdot..cntdot.O, CH.cntdot..cntdot..cntdot.N and CH.cntdot..cntdot..cntdot.Cl hydrogen bonds
Robin Taylor and Olga Kennard
pp 5063 - 5070; DOI:
10.1021/ja00383a012
PDF
Kinetics and mechanism of oxidation of aromatic hydrocarbons by Ru(trpy)(bpy)O2+
Mark S. Thompson and Thomas J. Meyer
pp 5070 - 5076; DOI:
10.1021/ja00383a013
PDF
Oxidation of hydrocarbons. 11. Kinetics and mechanism of the reaction between methyl (E)-cinnamate and quaternary ammonium permanganates
Donald G. Lee and Keith C. Brown
pp 5076 - 5081; DOI:
10.1021/ja00383a014
PDF
Carbon dioxide fixation: bifunctional complexes containing acidic and basic sites working as reversible carriers
Sandro Gambarotta, Francesco Arena, Carlo Floriani, and Pier Francesco Zanazzi
pp 5082 - 5092; DOI:
10.1021/ja00383a015
PDF
Synthetic, structural, and physical studies of bis(triethylammonium) tris(catecholato)vanadate(IV), potassium bis(catecholato)oxovanadate(IV), and potassium tris(catecholato)vanadate (III)
Stephen R. Cooper, Yun Bai Koh, and Kenneth N. Raymond
pp 5092 - 5102; DOI:
10.1021/ja00383a016
PDF
Angle-resolved ultraviolet photoelectron spectroscopic studies of carbon monoxide binding to three chemically different surfaces of zinc oxide. Confirmation of step-binding sites on (000.hivin.1)
K. L. D'Amico, M. Trenary, N. D. Shinn, Edward I. Solomon, and F. R. McFeely
pp 5102 - 5105; DOI:
10.1021/ja00383a017
PDF
A kinetic study of the reactions of tert-butoxyl with alkenes: hydrogen abstraction vs. addition
P. C. Wong, D. Griller, and J. C. Scaiano
pp 5106 - 5108; DOI:
10.1021/ja00383a018
PDF
Laser photolysis study of the reactions of alkoxyl radicals generated in the photosensitized decomposition of organic hyponitrites
G. D. Mendenhall, L. C. Stewart, and J. C. Scaiano
pp 5109 - 5114; DOI:
10.1021/ja00383a019
PDF
Laser Raman and infrared spectra, and x-ray crystal structure of trans-di-tert-butyl hyponitrite
Craig A. Ogle, Karen A. Van der Kooi, G. David Mendenhall, Veerayooth Lorprayoon, and Bahne C. Cornilsen
pp 5114 - 5119; DOI:
10.1021/ja00383a020
PDF
Absolute rate constants for the addition of triethylsilyl radicals to the carbonyl group
C. Chatgilialoglu, K. U. Ingold, and J. C. Scaiano
pp 5119 - 5123; DOI:
10.1021/ja00383a021
PDF
Absolute rate constants for the reaction of triethylsilyl radicals with organic halides
C. Chatgilialoglu, K. U. Ingold, and J. C. Scaiano
pp 5123 - 5127; DOI:
10.1021/ja00383a022
PDF
Intramolecular charge-transfer absorption and emission resulting from through-bond interaction in bichromophoric molecules
P. Pasman, F. Rob, and J. W. Verhoeven
pp 5127 - 5133; DOI:
10.1021/ja00383a023
PDF
Nucleophilic addition to olefins. 6. Structure-reactivity relationships in the reactions of substituted benzylidene Meldrum's acids with water, hydroxide ion, and aryloxide ions
Claude F. Bernasconi and Gianni D. Leonarduzzi
pp 5133 - 5142; DOI:
10.1021/ja00383a024
PDF
Nucleophilic addition to olefins. 7. Kinetic deuterium isotope effects as criterion for an enforced preassociation mechanism in the hydrolysis of substituted benzylidene Meldrum's acids
Claude F. Bernasconi and Gianni D. Leonarduzzi
pp 5143 - 5153; DOI:
10.1021/ja00383a025
PDF
Reactivity of some transition metal systems toward liquid carbon dioxide
Michael G. Mason and James A. Ibers
pp 5153 - 5157; DOI:
10.1021/ja00383a026
PDF
Fission fragment ionization mass spectrometry of alamethicin I
B. T. Chait, B. F. Gisin, and F. H. Field
pp 5157 - 5162; DOI:
10.1021/ja00383a027
PDF
Crystal and molecular structure of bis(9-triptycyl) ketone and bis(9-triptycyl)methane
Constance A. Johnson, Alberto Guenzi, Robert B. Nachbar, John F. Blount, Olof Wennerstroem, and Kurt Mislow
pp 5163 - 5168; DOI:
10.1021/ja00383a028
PDF
Stable carbocations. 209. .alpha.,.alpha.-Ethylenenaphthalenium ions
George A. Olah and Brij P. Singh
pp 5168 - 5172; DOI:
10.1021/ja00383a029
PDF
Structure of rubradirin
H. Hoeksema, S. A. Mizsak, L. Baczynskyj, and L. Pschigoda
pp 5173 - 5181; DOI:
10.1021/ja00383a030
PDF
Benzidine rearrangements. 17. The concerted nature of the one-proton p-semidine rearrangement of 4-methoxyhydrazobenzene
Henry J. Shine, Henryk Zmuda, Harold Kwart, Ann Gafney Horgan, and Martin Brechbiel
pp 5181 - 5184; DOI:
10.1021/ja00383a031
PDF
Host-guest complexation. 24. Synthesis of multiheteromacrocycles containing intramolecularly interacting units or new steric barriers
Thomas W. Bell, Paul G. Cheng, Martin Newcomb, and Donald J. Cram
pp 5185 - 5188; DOI:
10.1021/ja00383a032
PDF
Multicenter organic redox systems composed of bis(1,4-dihydronicotinamides): optimal conformation for intramolecular electronic interaction
Yukito Murakami, Yasuhiro Aoyama, Junichi Kikuchi, and Koji Nishida
pp 5189 - 5197; DOI:
10.1021/ja00383a033
PDF
Carrier-mediated transport of amino acid and simple organic anions by lipophilic metal complexes
Kazuhiro Maruyama, Hiroshi Tsukube, and Takeo Araki
pp 5197 - 5203; DOI:
10.1021/ja00383a034
PDF
Proton NMR characterization of the state of protonation of the axial imidazole in reduced horseradish peroxidase
Gerd N. La Mar and Jeffrey S. De Ropp
pp 5203 - 5206; DOI:
10.1021/ja00383a035
PDF
Proton NMR evidence for a left-handed helical structure of poly(ribocytidylic acid) in neutral solution
Michelle S. Broido and David R. Kearns
pp 5207 - 5216; DOI:
10.1021/ja00383a036
PDF
Autoxidation of model membrane systems: cooxidation of polyunsaturated lecithins with steroids, fatty acids, and .alpha.-tocopherol
Hugo Weenen and Ned A. Porter
pp 5216 - 5221; DOI:
10.1021/ja00383a037
PDF
Carboxypeptidase A catalyzed hydrolysis of thiopeptide and thioester analogs of specific substrates. An effect on kcat for peptide, but not ester, substrates
Peter Campbell and Nashaat T. Nashed
pp 5221 - 5226; DOI:
10.1021/ja00383a038
PDF
The first isolated, stable cis-hydridoalkylrhodium complexes and their reductive elimination reaction
D. Milstein
pp 5227 - 5228; DOI:
10.1021/ja00383a039
PDF
Simplification and assignment of carbon-13 spectra by using J-resolved NMR spectroscopy in solids
T. Terao, H. Miura, and A. Saika
pp 5228 - 5229; DOI:
10.1021/ja00383a040
PDF
An orbital explanation for Pauling's third rule
Jeremy K. Burdett and Timothy J. McLarnan
pp 5229 - 5230; DOI:
10.1021/ja00383a041
PDF
Intramolecular homolytic displacement of cobaloxime(II) from saturated carbon. A novel synthesis of (trichloroethyl)cyclopentanes and sulfolanes
Peter Bougeard, Adrian Bury, Christopher J. Cooksey, Michael D. Johnson, James M. Hungerford, and Gary M. Lampman
pp 5230 - 5232; DOI:
10.1021/ja00383a042
PDF
Gymnodinium breve toxins. 1. Isolation and x-ray structure of O,O-dipropyl (E)-2-(1-methyl-2-oxopropylidene)phosphorohydrazidothioate (E)-oxime from the red tide dinoflagellate Gymnodinium breve
Maktoob Alam, Radhika Sanduja, M. Bilayet Hossain, and Dick Van der Helm
pp 5232 - 5234; DOI:
10.1021/ja00383a043
PDF
Homogeneous catalytic hydrogenation. 1. Regiospecific reductions of polynuclear aromatic and polynuclear heteroaromatic nitrogen compounds catalyzed by transition metal carbonyl hydrides
Richard H. Fish, Arne D. Thormodsen, and Gregg A. Cremer
pp 5234 - 5237; DOI:
10.1021/ja00383a044
PDF
Deglycobleomycin: total synthesis and oxygen transfer properties of an active bleomycin analog
Yoshiaki Aoyagi, H. Suguna, Natesan Murugesan, Guy M. Ehrenfeld, Li Ho Chang, Tadaaki Ohgi, Mohammed S. Shekhani, Michael P. Kirkup, and Sidney M. Hecht
pp 5237 - 5239; DOI:
10.1021/ja00383a045
PDF
[1.1.1]Propellane
Kenneth B. Wiberg and Frederick H. Walker
pp 5239 - 5240; DOI:
10.1021/ja00383a046
PDF
Three-coordinate binuclear copper(I) complex: model compound for the copper sites in deoxyhemocyanin and deoxytyrosinase
Kenneth D. Karlin, Yilma Gultneh, John P. Hutchinson, and Jon Zubieta
pp 5240 - 5242; DOI:
10.1021/ja00383a047
PDF
Electrically stimulated release of neurotransmitters from a surface. An analog of the presynaptic terminal
Larry L. Miller, Aldrich N. K. Lau, and Essie Kariv Miller
pp 5242 - 5244; DOI:
10.1021/ja00383a048
PDF
Selective preparation of catalytically active zeolite-encapsulated rhodium complexes
Tai Nang Huang and Jeffrey Schwartz
pp 5244 - 5245; DOI:
10.1021/ja00383a049
PDF
Annelides. 7. Discotic mesophases obtained from substituted metallophthalocyanines. Toward liquid crystalline one-dimensional conductors
Christian Piechocki, Jacques Simon, Antoine Skoulios, Daniel Guillon, and Patrick Weber
pp 5245 - 5247; DOI:
10.1021/ja00383a050
PDF
Electron transmission spectroscopy of 1,3,5-hexatriene: isomeric differences in .pi. orbital energies
P. D. Burrow and K. D. Jordan
pp 5247 - 5248; DOI:
10.1021/ja00383a051
PDF
On the origins of the blue shift of the carbonyl n-.pi.* transition in hydrogen-bonding solvents
Peter R. Taylor
pp 5248 - 5249; DOI:
10.1021/ja00383a052
PDF
Effect of particle size on the activity of supported palladium catalysts
Yoshio Takasu, Tsutomu Akimaru, Kenji Kasahara, Yoshiharu Matsuda, Hiroyuki Miura, and Isamu Toyoshima
pp 5249 - 5250; DOI:
10.1021/ja00383a053
PDF
Asymmetric induction in reactions employing enolates generated from cyclic organo transition metal acyl complexes
Klaus H. Theopold, Paul N. Becker, and Robert G. Bergman
pp 5250 - 5252; DOI:
10.1021/ja00383a054
PDF
Experimental probe of nonadiabatic effects in simple electron-transfer reactions
John F. Endicott and T. Ramasami
pp 5252 - 5254; DOI:
10.1021/ja00383a055
PDF
Trialkyl phosphite complexes of cobalt
Giovanni Agnes, Jan C. J. Bart, Claudio Santini, and Kwamena A. Woode
pp 5254 - 5255; DOI:
10.1021/ja00383a056
PDF
Iron(III) phenoxide complexes: models for iron(III)-tyrosine coordination
Stephen A. Koch and Michelle Millar
pp 5255 - 5257; DOI:
10.1021/ja00383a057
PDF
Book Reviews

pp 5257 - 5258; DOI:
10.1021/ja00383a600
PDF

Issue 20


Structure and isomerization of C7H7+ ions formed in the charge-transfer-induced fragmentation of ethylbenzene, toluene, and norbornadiene
P. Ausloos
pp 5259 - 5265; DOI:
10.1021/ja00384a001
PDF
Electronic structure of uranium halides and oxyhalides in the solid state. An x-ray photoelectron spectral study of bonding ionicity
Elisabeth Thibaut, Jean Pol Boutique, Jacques J. Verbist, Jean Claude Levet, and Henri Noel
pp 5266 - 5273; DOI:
10.1021/ja00384a002
PDF
Vibrational analysis of all-trans-retinal
Bo Curry, Albert Broek, Johan Lugtenburg, and Richard Mathies
pp 5274 - 5286; DOI:
10.1021/ja00384a003
PDF
Charge distributions and chemical effects. XXX. Relationships between nuclear magnetic resonance shifts and atomic charges
Sandor Fliszar, Guy Cardinal, and Marie Therese Beraldin
pp 5287 - 5292; DOI:
10.1021/ja00384a004
PDF
The 3,3-dimethyl-2-azabicyclo[2.2.2]octyl system as a Bredt's rule kinetically stabilized dialkylamino group in electron-transfer studies
Stephen F. Nelsen and Peter M. Gannett
pp 5292 - 5297; DOI:
10.1021/ja00384a005
PDF
Enhancement of through-bond coupling by bond-angle distortion: pyrazine
Harry J. Dewey, Robert D. Miller, and Josef Michl
pp 5298 - 5302; DOI:
10.1021/ja00384a006
PDF
Chemical applications of technetium-99 NMR spectroscopy: preparation of novel technetium(VII) species and their characterization by multinuclear NMR spectroscopy
Kenneth J. Franklin, Colin J. L. Lock, Brian G. Sayer, and Gary J. Schrobilgen
pp 5303 - 5306; DOI:
10.1021/ja00384a007
PDF
Pseudorotation in cyclopentane. An experimental determination of the puckering amplitude by NMR in oriented solvents
R. Poupko, Z. Luz, and H. Zimmermann
pp 5307 - 5314; DOI:
10.1021/ja00384a008
PDF
Preferential solvation of hydrogen ions in mixed clusters of water, methanol, and ethanol
A. J. Stace and A. K. Shukla
pp 5314 - 5318; DOI:
10.1021/ja00384a009
PDF
Heat of formation for acetyl cation in the gas phase
John C. Traeger, Russell G. McLoughlin, and A. J. C. Nicholson
pp 5318 - 5322; DOI:
10.1021/ja00384a010
PDF
Electrochemistry of perfluorotetracyclobuta-1,3,5,7-cyclooctatetraene, a powerful neutral organic oxidant
Wayne E. Britton, John P. Ferraris, and Robert L. Soulen
pp 5322 - 5325; DOI:
10.1021/ja00384a011
PDF
Dynamic features of the ethylenediaminetetraacetate complexes in aqueous solutions studied by the ultrasonic absorption method. 2. Zinc and cadmium complexes
Yoshinori Funaki, Shoji Harada, Kazuhiro Okumiya, and Tatsuya Yasunaga
pp 5325 - 5328; DOI:
10.1021/ja00384a012
PDF
On the stability and properties of organic metals and their isomeric charge-transfer complexes
Sason S. Shaik
pp 5328 - 5334; DOI:
10.1021/ja00384a013
PDF
Photoelectron spectroscopic studies of the intermolecular complexes dimethyl ether-hydrogen fluoride ((CH3)2O.HF) and dimethyl sulfide-hydrogen fluoride ((CH3)2S.HF)
F. Carnovale, M. K. Livett, and J. B. Peel
pp 5334 - 5338; DOI:
10.1021/ja00384a014
PDF
Intermediates in the sulfide reduction of the 3,5-diphenyl-1,2-dithiolylium cation: a resonance Raman study
Olavi Siiman, Sujin Shobsngob, and James Fresco
pp 5338 - 5342; DOI:
10.1021/ja00384a015
PDF
Natural-abundance one-bond carbon-13-carbon-13 coupling constants in monosaccharide derivatives and in sucrose
Andras Neszmelyi and Gabor Lukacs
pp 5342 - 5346; DOI:
10.1021/ja00384a016
PDF
Tautomerization of formamide, 2-pyridone, and 4-pyridone: an ab initio study
H. Bernhard Schlegel, Peter Gund, and Eugene M. Fluder
pp 5347 - 5351; DOI:
10.1021/ja00384a017
PDF
Redox active functionally polymerized surfactant vesicles. Syntheses and characterization
Pietro Tundo, Donald J. Kippenberger, Mario J. Politi, Patricia Klahn, and Janos H. Fendler
pp 5352 - 5358; DOI:
10.1021/ja00384a018
PDF
X-ray crystal and molecular structure of the dimeric 1:1 dimethyltin(IV) dichloride adduct with diphenylcyclopropenone, (Me2SnCl2.cntdot.O:CC2Ph2)2, at 138 .+-. 2 K
S. W. Ng, C. L. Barnes, M. B. Hossain, D. Van der Helm, J. J. Zuckerman, and V. G. Kumar Das
pp 5359 - 5364; DOI:
10.1021/ja00384a019
PDF
Polarized x-ray absorption spectra of oriented plastocyanin single crystals. Investigation of methionine-copper coordination
Robert A. Scott, James E. Hahn, Sebastian Doniach, Hans C. Freeman, and Keith O. Hodgson
pp 5364 - 5369; DOI:
10.1021/ja00384a020
PDF
Chloropalladation of alkyl-substituted methylenecyclopropanes
Thomas A. Albright, Paula R. Clemens, Russell P. Hughes, Donald E. Hunton, and Lawrence D. Margerum
pp 5369 - 5379; DOI:
10.1021/ja00384a021
PDF
Chloropalladation of phenyl-substituted methylenecyclopropanes
Bruce K. Dallas, Russell P. Hughes, and Karen Schumann
pp 5380 - 5383; DOI:
10.1021/ja00384a022
PDF
Tungsten-183 NMR of heteropoly and isopolytungstates. Explanations of chemical shifts and band assignments and theoretical considerations
Rafael Acerete, Charles F. Hammer, and Louis C. W. Baker
pp 5384 - 5390; DOI:
10.1021/ja00384a023
PDF
Determination of the onset of the dezincification of .alpha.-brass using x-ray photoelectron (ESCA) spectroscopy
T. L. Barr and J. J. Hackenberg
pp 5390 - 5394; DOI:
10.1021/ja00384a024
PDF
A new type of trinuclear cluster compound: the incomplete bicapped (or hemicapped) structure in [W3O(O2CCH3)6(H2O)3]ZnBr4.8H2O
Michael Ardon, F. Albert Cotton, Zvi Dori, Anne Fang, Moshe Kapon, George M. Reisner, and Miriam Shaia
pp 5394 - 5398; DOI:
10.1021/ja00384a025
PDF
Metaphosphite (PO2-) symmetric-stretching Raman line and molecular-aggregation states of barium dialkyl phosphates
Hirofumi Okabayashi, Tadayoshi Yoshida, Teruki Ikeda, Hiroatsu Matsuura, and Teizo Kitagawa
pp 5399 - 5402; DOI:
10.1021/ja00384a026
PDF
Highly reduced annulenes. Novel probes for spectroscopy and theory
K. Muellen, W. Huber, T. Meul, M. Nakagawa, and M. Iyoda
pp 5403 - 5411; DOI:
10.1021/ja00384a027
PDF
Chemistry of oxaziridines. 3. Asymmetric oxidation of organosulfur compounds using chiral 2-sulfonyloxaziridines
Franklin A. Davis, Robert H. Jenkins, Sami B. Awad, Orum D. Stringer, William H. Watson, and Jean Galloy
pp 5412 - 5418; DOI:
10.1021/ja00384a028
PDF
Temperature dependence of the neutral ester hydrolysis of chloromethyl dichloroacetate in 2-butoxyethanol-water mixtures over a wide temperature range
Liisa T. Kanerva and Erkki K. Euranto
pp 5419 - 5421; DOI:
10.1021/ja00384a029
PDF
Acyclic trialkyldiazenium cation chemistry. Thermolysis and solvolysis of 1,2-di-tert-butyl-1-ethyldiazenium perchlorate
Evan L. Allred, Tahsin J. Chow, and Joseph E. Oberlander
pp 5422 - 5427; DOI:
10.1021/ja00384a030
PDF
Analysis of the atomic environment of quaternary ammonium groups in crystal structures, using computerized data retrieval and interactive graphics: modeling acetylcholine-receptor interactions
Richard E. Rosenfield and Peter Murray-Rust
pp 5427 - 5430; DOI:
10.1021/ja00384a031
PDF
Multiphoton infrared laser-induced absorption and reaction of organic esters
Wayne C. Danen, V. C. Rio, and D. W. Setser
pp 5431 - 5440; DOI:
10.1021/ja00384a032
PDF
Multiphoton laser-induced chemistry of organic esters: comparison with master equation calculated results
J. C. Jang, D. W. Setser, and Wayne C. Danen
pp 5440 - 5452; DOI:
10.1021/ja00384a033
PDF
Indirect detection of mercury-199 NMR: adducts of ethylmercury phosphate with amino acids and ribonuclease
D. A. Vidusek, Mary F. Roberts, and Geoffrey Bodenhausen
pp 5452 - 5456; DOI:
10.1021/ja00384a034
PDF
Pentacoordinated molecules. 41. Computer simulation of staphylococcal nuclease action on thymidine 3',5'-bis(phosphate) (pdTp)
Joan A. Deiters, Judith C. Gallucci, and Robert R. Holmes
pp 5457 - 5465; DOI:
10.1021/ja00384a035
PDF
Pyrimidine ring contraction with a 5-deazaflavin 4a,5-epoxide derivative. Model studies for reactions with enzyme-bound epoxide intermediates
Alexander Pokora, Marilyn S. Jorns, and Donald Vargo
pp 5466 - 5469; DOI:
10.1021/ja00384a036
PDF
Resonance Raman detection of an iron-sulfur bond in cytochrome P 450cam
P. M. Champion, B. R. Stallard, G. C. Wagner, and I. C. Gunsalus
pp 5469 - 5472; DOI:
10.1021/ja00384a037
PDF
Efficient, stereocontrolled total syntheses of racemic and natural brefeldin-A
Claude Le Drian and Andrew E. Greene
pp 5473 - 5483; DOI:
10.1021/ja00384a038
PDF
Nucleotidophospholipids: oligonucleotide derivatives with membrane-recognition groups
Fausto Ramirez, Sukhendu B. Mandal, and James F. Marecek
pp 5483 - 5486; DOI:
10.1021/ja00384a039
PDF
Synthesis of (.+-.)-lineatin, an aggregation pheromone of Trypodendron lineatum
James D. White, Mitchell A. Avery, and J. Paul Carter
pp 5486 - 5489; DOI:
10.1021/ja00384a040
PDF
Intramolecularly chelated di- and tetranuclear aryllithium compounds: crystal structure of Li4[C6H4(2-CH2NMe2)]4 containing 4-center 2-electron-bonded C(aryl) atoms and heptacoordinate lithium atoms
Johann T. B. H. Jastrzebski, Gerard Van Koten, Marcel Konijn, and Casper H. Stam
pp 5490 - 5492; DOI:
10.1021/ja00384a041
PDF
4-(1-Adamantyl)homoadamant-3-ene: an extraordinarily stable bridgehead olefin
Simon F. Sellers, Theodorus C. Klebach, Frederic Hollowood, Maitland Jones, and Paul von Rague Schleyer
pp 5492 - 5493; DOI:
10.1021/ja00384a042
PDF
Carbon-14 and deuterium isotope effects in the borderline solvolysis of isopropyl .beta.-naphthalenesulfonate
Takashi Ando, Hiroshi Yamataka, Shinichi Tamura, and Terukiyo Hanafusa
pp 5493 - 5494; DOI:
10.1021/ja00384a043
PDF
Identification of degradation products of d(C-G) by a 1,10-phenanthroline-copper ion complex
Seiichi Uesugi, Toshio Shida, Morio Ikehara, Yuji Kobayashi, and Yoshimasa Kyogoku
pp 5494 - 5495; DOI:
10.1021/ja00384a044
PDF
Systematic iron(II)-thiolate chemistry: synthetic entry to trinuclear complexes
K. S. Hagen and R. H. Holm
pp 5496 - 5497; DOI:
10.1021/ja00384a045
PDF
Synthesis and structure of tri-s-triazine
Ramachandra S. Hosmane, Mitchell A. Rossman, and Nelson J. Leonard
pp 5497 - 5499; DOI:
10.1021/ja00384a046
PDF
Preparation and reaction of metal-ketene complexes of zirconium and titanium
Daniel A. Straus and Robert H. Grubbs
pp 5499 - 5500; DOI:
10.1021/ja00384a047
PDF
Photoreactivity of .alpha.,.beta.-unsaturated carbonyl compounds. Competitive 2-cyclohexenone dimerization and adduct formation with triethylamine
Norbert J. Pienta and Jennifer E. McKimmey
pp 5501 - 5502; DOI:
10.1021/ja00384a048
PDF
Liposomal membranes. 13. Transport of an amino acid across liposomal bilayers as mediated by a photoresponsive carrier
Junzo Sunamoto, Kiyoshi Iwamoto, Yukio Mohri, and Tetsumi Kominato
pp 5502 - 5504; DOI:
10.1021/ja00384a049
PDF
Nitrogen-15 NMR study of [15N]actinomycin D complexed with d(pGpC) and DNA
Stephen C. Brown, Richard H. Shafer, and Peter A. Mirau
pp 5504 - 5506; DOI:
10.1021/ja00384a050
PDF
Direct evidence of microscopic homogeneity in disordered solids
P. Caravatti, J. Deli, G. Bodenhausen, and R. R. Ernst
pp 5506 - 5507; DOI:
10.1021/ja00384a051
PDF
Characterization of novel rhodium(II) dimers with N-phenylacetamido bridging ligands
J. Duncan, T. Malinski, T. P. Zhu, Z. S. Hu, K. M. Kadish, and J. L. Bear
pp 5507 - 5509; DOI:
10.1021/ja00384a052
PDF
.alpha.-(Phenylthio)-.beta.-vinylbutenolide, a novel annulating reagent for the synthesis of 4-oxygenated perhydro-2-oxo-1-benzofuran derivatives
Fusao Kido, Yoshihiro Noda, and Akira Yoshikoshi
pp 5509 - 5511; DOI:
10.1021/ja00384a053
PDF
Electron paramagnetic resonance detection of electric field effect on the nucleation of the ferroelectric phase of KD2PO4
N. S. Dalal
pp 5511 - 5512; DOI:
10.1021/ja00384a054
PDF
Carbon-14 isotope effects in the addition of 2,4-dinitrobenzenesulfenyl chloride to styrene-1-14C and styrene-2-14C
Marianna Kanska and Arthur Fry
pp 5512 - 5514; DOI:
10.1021/ja00384a055
PDF
Electrooxidative catalysis using dispersed alumina on glassy carbon surfaces
Jerzy Zak and Theodore Kuwana
pp 5514 - 5515; DOI:
10.1021/ja00384a056
PDF
Molecular structure and charge transfer excitation of electron donor-acceptor complexes. Ion pairs from arenes and mercury(II)
W. Lau, J. C. Huffman, and J. K. Kochi
pp 5515 - 5517; DOI:
10.1021/ja00384a057
PDF
Selective trans to cis isomerization of alkenes via infrared multiphoton excitation
Peter P. Teng, Eric Weitz, and Frederick D. Lewis
pp 5518 - 5519; DOI:
10.1021/ja00384a058
PDF
Californium-252 fission fragment ionization mass spectrometry of chlorophyll a
B. T. Chait and F. H. Field
pp 5519 - 5521; DOI:
10.1021/ja00384a059
PDF
Aldol methodology: synthesis of versatile intermediates, 3-hydroxy-2-vinylcarbonyl compounds
Satoru Masamune, Tatsuo Kaiho, and David S. Garvey
pp 5521 - 5523; DOI:
10.1021/ja00384a060
PDF
Synthesis of tylonolide, the aglycone of tylosin
Satoru Masamune, Linda D. L. Lu, William P. Jackson, Tatsuo Kaiho, and Tatsuo Toyoda
pp 5523 - 5526; DOI:
10.1021/ja00384a061
PDF
Aldol strategy: coordination of the lithium cation with an alkoxy substituent
Satoru Masamune, John W. Ellingboe, and William Choy
pp 5526 - 5528; DOI:
10.1021/ja00384a062
PDF
Synthesis of ansamycins: the ansa chain of rifamycin S
Satoru Masamune, Barbara Imperiali, and David S. Garvey
pp 5528 - 5531; DOI:
10.1021/ja00384a063
PDF
Directed metalation of tertiary benzamides. Ortho N-aryl amination and synthesis of acridones
M. Iwao, J. N. Reed, and V. Snieckus
pp 5531 - 5533; DOI:
10.1021/ja00384a064
PDF
High-yield acyl-anion trapping reactions: a synthesis of acyltrimethylsilanes
Dietmar Seyferth and Robert M. Weinstein
pp 5534 - 5535; DOI:
10.1021/ja00384a065
PDF
Picosecond dynamics of hydride transfer
Kevin S. Peters, Edward Pang, and Jeanne Rudzki
pp 5535 - 5537; DOI:
10.1021/ja00384a066
PDF
Total synthesis of bleomycin
Yoshiaki Aoyagi, Kiyoaki Katano, Hosbett Suguna, John Primeau, Li Ho Chang, and Sidney M. Hecht
pp 5537 - 5538; DOI:
10.1021/ja00384a067
PDF
Synthesis of .beta.-lactams by the photolytic reaction of chromium carbene complexes with imines
Michael A. McGuire and Louis S. Hegedus
pp 5538 - 5540; DOI:
10.1021/ja00384a068
PDF
Use of two-dimensional NMR in the study of a double-stranded DNA decamer
J. Feigon, J. M. Wright, W. Leupin, W. A. Denny, and D. R. Kearns
pp 5540 - 5541; DOI:
10.1021/ja00384a069
PDF
Lifetime of oxygen (O2(1.DELTA.g)) in liquid water as determined by time-resolved infrared luminescence measurements
Michael A. J. Rodgers and Paul T. Snowden
pp 5541 - 5543; DOI:
10.1021/ja00384a070
PDF
Molybdenum catalysts for allylic alkylation
Barry M. Trost and Mark Lautens
pp 5543 - 5545; DOI:
10.1021/ja00384a071
PDF
Structure of a photodimer determined by natural-abundance 13C-13C coupling
Ray Freeman, Thomas Frenkiel, and Mordecai B. Rubin
pp 5545 - 5547; DOI:
10.1021/ja00384a072
PDF
Formation and enhanced stability of fluoroalkyl bilayer membranes
T. Kunitake, Y. Okahata, and S. Yasunami
pp 5547 - 5549; DOI:
10.1021/ja00384a073
PDF
Hydrogen bonding in alcohols: its effect on the carbene insertion reaction
D. Griller, M. T. H. Liu, and J. C. Scaiano
pp 5549 - 5551; DOI:
10.1021/ja00384a074
PDF
Total synthesis of the complement inhibitor K-76 in racemic form. Structural assignment to "K-76 monocarboxylic acid"
E. J. Corey and Jagabandhu Das
pp 5551 - 5553; DOI:
10.1021/ja00384a075
PDF
De novo sequencing of oligosaccharides by proton NMR spectroscopy
M. A. Bernstein and L. D. Hall
pp 5553 - 5555; DOI:
10.1021/ja00384a076
PDF
The endiandric acid cascade. Electrocyclizations in organic synthesis. I. Stepwise, stereocontrolled total synthesis of endiandric acids A and B
K. C. Nicolaou, N. A. Petasis, R. E. Zipkin, and J. Uenishi
pp 5555 - 5557; DOI:
10.1021/ja00384a077
PDF
The endiandric acid cascade. Electrocyclizations in organic synthesis. 2. Stepwise, stereocontrolled total synthesis of endiandric acids C-G
K. C. Nicolaou, N. A. Petasis, J. Uenishi, and R. E. Zipkin
pp 5557 - 5558; DOI:
10.1021/ja00384a078
PDF
The endiandric acid cascade. Electrocyclizations in organic synthesis. 3. "Biomimetic" approach to endiandric acids A-G. Synthesis of precursors
K. C. Nicolaou, R. E. Zipkin, and N. A. Petasis
pp 5558 - 5560; DOI:
10.1021/ja00384a079
PDF
The endiandric acid cascade. Electrocyclizations in organic synthesis. 4. Biomimetic approach to endiandric acids A-G. Total synthesis and thermal studies
K. C. Nicolaou, N. A. Petasis, and R. E. Zipkin
pp 5560 - 5562; DOI:
10.1021/ja00384a080
PDF
Extremely facile reaction between the ultimate carcinogen benzo[a]pyrene-7,8-diol 9,10-epoxide and ellagic acid
Jane M. Sayer, Haruhiko Yagi, Alexander W. Wood, Allan H. Conney, and Donald M. Jerina
pp 5562 - 5564; DOI:
10.1021/ja00384a081
PDF
Homolytic carbocyclization by use of a heterogeneous supported organotin catalyst. A new synthetic route to 2-alkoxytetrahydrofurans and .gamma.-butyrolactones
Yoshio Ueno, Kunitake Chino, Masaru Watanabe, Osamu Moriya, and Makoto Okawara
pp 5564 - 5566; DOI:
10.1021/ja00384a082
PDF
Tetrathiazyl tetrakis(perfluoro-tert-butoxide)
Gary L. Gard and Jean'ne M. Shreeve
pp 5566 - 5567; DOI:
10.1021/ja00384a083
PDF
Structure of trans-bis(1,5-dithiacyclooctane)tetrachlorotin(IV): evidence for an intramolecular interaction between a remote donor and a coordinated atom
Marilyn M. Olmstead, Keith A. Williams, and W. Kenneth Musker
pp 5567 - 5568; DOI:
10.1021/ja00384a084
PDF
Total synthesis of hibiscone C (gmelofuran)
Emil R. Koft and Amos B. Smith
pp 5568 - 5570; DOI:
10.1021/ja00384a085
PDF
Electron-transfer mechanism for a hydride-transfer reaction: evidence for selective .alpha.-hydride abstraction from a transition metal alkyl
Jeffrey C. Hayes and N. John Cooper
pp 5570 - 5572; DOI:
10.1021/ja00384a086
PDF
Additions & Corrections: Absolute Stereochemistry of Palytoxin
R.E. Moore, G. Bartolini, J. Barchi, A.A. Bothner-By, J. Dadok, and J. Ford
pp 5572 - 5572; DOI:
10.1021/ja00384a600
PDF

Issue 21


Use of the INEPT [Insensitive Nuclei Enhanced by Polarization Transfer] polarization transfer method for nitrogen-15 NMR relaxation study of linear peptides
Dominique Marion, Christiane Garbay-Jaureguiberry, and Bernard P. Roques
pp 5573 - 5576; DOI:
10.1021/ja00385a001
PDF
Effect of electron correlation of theoretical equilibrium geometries. 2. Comparison of third-order perturbation and configuration interaction results with experiment
Douglas J. DeFrees, Krishnan Raghavachari, H. Bernhard Schlegel, and John A. Pople
pp 5576 - 5580; DOI:
10.1021/ja00385a002
PDF
Metal ion photoinitiated addition of acetonitrile and methanol to olefins
Joseph W. Bruno, Tobin J. Marks, and Frederick D. Lewis
pp 5580 - 5585; DOI:
10.1021/ja00385a003
PDF
Metal ion initiated charge-transfer photopolymerization of tetrahydrofuran. A mechanistic investigation
Michael E. Woodhouse, Frederick D. Lewis, and Tobin J. Marks
pp 5586 - 5594; DOI:
10.1021/ja00385a004
PDF
Orientation and linear dichroism of symmetrical aromatic molecules imbedded in stretched polyethylene
Erik W. Thulstrup and Josef Michl
pp 5594 - 5604; DOI:
10.1021/ja00385a005
PDF
Temperature dependence of excimer formation between pyrenes at the ends of a polymer in a good solvent. Cyclization dynamics of polymers. 9
A. E. C. Redpath and M. A. Winnik
pp 5604 - 5607; DOI:
10.1021/ja00385a006
PDF
Effects of chemical modification and cobalt(II) chloride addition on the carbon-13 NMR spectra of carnosine as a solid powder
Charles Eric Brown
pp 5608 - 5610; DOI:
10.1021/ja00385a007
PDF
Geometrical structures of electronically excited states of conjugated hydrocarbons
T. Nakajima, A. Toyota, and M. Kataoka
pp 5610 - 5616; DOI:
10.1021/ja00385a008
PDF
Photodissociation of isomeric chloropropene cations and structure of reactively produced chloropropene ions
Robert G. Orth and Robert C. Dunbar
pp 5617 - 5621; DOI:
10.1021/ja00385a009
PDF
Nucleophilic attack and structural rearrangements in some iron carbonyl cluster carbides. Syntheses, structures, and reactions of the tetrahedral four-iron clusters [Fe4(CO)12(.mu.3-COMe)]- and [Fe4(CO)12(CMe)]-
E. M. Holt, K. H. Whitmire, and D. F. Shriver
pp 5621 - 5626; DOI:
10.1021/ja00385a010
PDF
Reactivity of metal carbide clusters: alkylation and protonation of [Fe5(CO)14C]2-
J. W. Kolis, F. Basolo, and D. F. Shriver
pp 5626 - 5630; DOI:
10.1021/ja00385a011
PDF
Proton-induced reduction of CO to CH4 in homonuclear and heteronuclear metal carbonyls: a survey of the influence of the metal and nuclearity
M. A. Drezdzon, K. H. Whitmire, A. A. Bhattacharyya, Wen Liang Hsu, C. C. Nagel, S. G. Shore, and D. F. Shriver
pp 5630 - 5633; DOI:
10.1021/ja00385a012
PDF
Paramagnetic organometallic molecules. 12. Electrochemical studies of reactions with Lewis bases following metal-metal bond cleavage in R2C2Co2(CO)6 radical anions
Malini Arewgoda, Philip H. Rieger, Brian H. Robinson, Jim Simpson, and Steven J. Visco
pp 5633 - 5640; DOI:
10.1021/ja00385a013
PDF
Solvent effects in the complexation of [2]-cryptands and related monocycles with transition- and heavy-metal cations
F. Arnaud-Neu, B. Spiess, and M. J. Schwing-Weill
pp 5641 - 5645; DOI:
10.1021/ja00385a014
PDF
Photoinduced reactions of (.eta.5-C5H5)2MH3 and (.eta.5-C5H5)2M(CO)H (M = Nb, Ta) and the molecular structure of (.eta.5-C5H5)2Ta(CO)H
Donald F. Foust, Robin D. Rogers, Marvin D. Rausch, and Jerry L. Atwood
pp 5646 - 5650; DOI:
10.1021/ja00385a015
PDF
Preparation, properties and structures of the clusters hexakis(.mu.3-oxo)pentakis(.eta.5-cyclopentadienylvanadium), [(.eta.5-C5H5)5V5O6], and tetrakis(.mu.3-oxo)tetrakis(.eta.5-cyclopentadienylchromium), [(.eta.5-C5H5)4Cr4O4]
Frank Bottomley, Daniel E. Paez, and Peter S. White
pp 5651 - 5657; DOI:
10.1021/ja00385a016
PDF
Formation and magnetic properties of hemin-azide-dimethyl sulfoxide, a model complex for azide catalase
Saburo Neya and Isao Morishima
pp 5658 - 5661; DOI:
10.1021/ja00385a017
PDF
Complexation of calcium by the synthetic ionophore McN-4308, [2-(4-(diphenylmethy)-1-piperidinyl)-2-oxoethoxy]acetic acid. Crystal and molecular structure of the free acid and of the calcium complex
Patrick Van Roey, G. David Smith, William L. Duax, Michael J. Umen, and Bruce E. Maryanoff
pp 5661 - 5666; DOI:
10.1021/ja00385a018
PDF
Stable solid silaethylenes
A. G. Brook, S. C. Nyburg, Fereydon Abdesaken, Brigitte Gutekunst, Gerhard Gutekunst, R. Krishna, M. R. Kallury, Yiu C. Poon, Yau Min Chang, and Wong Ng Winnie
pp 5667 - 5672; DOI:
10.1021/ja00385a019
PDF
Photochemistry of benzophenone in micelles. Formation and decay of radical pairs
J. C. Scaiano, Elsa B. Abuin, and Laura C. Stewart
pp 5673 - 5679; DOI:
10.1021/ja00385a020
PDF
Enthalpies of formation of fused cyclobutane derivatives
Kenneth B. Wiberg and John J. Wendoloski
pp 5679 - 5686; DOI:
10.1021/ja00385a021
PDF
CIDNP studies of photoinitiated electron-transfer reactions. Sensitized isomerization of an electron-acceptor norbornadiene
Wolfgang Schwarz, Karl Michael Dangel, Joachim Bargon, and Guilford Jones
pp 5686 - 5689; DOI:
10.1021/ja00385a022
PDF
Dianions of 2-methyl-1,5-hexadiene: evidence against Y aromaticity
Nancy S. Mills
pp 5689 - 5693; DOI:
10.1021/ja00385a023
PDF
Stabilization of stibabenzene and bismabenzene by 4-alkyl substituents
Arthur J. Ashe, Timothy R. Diephouse, and Maher Y. El-Sheikh
pp 5693 - 5699; DOI:
10.1021/ja00385a024
PDF
Elongated (one-electron) carbon-carbon bond in .sigma. and n organic cation radicals
Dennis J. Bellville and Nathan L. Bauld
pp 5700 - 5702; DOI:
10.1021/ja00385a025
PDF
Synthesis of oligodeoxyribonucleotides using N-(benzyloxycarbonyl)-blocked nucleosides
Bruce E. Watkins, John S. Kiely, and Henry Rapoport
pp 5702 - 5708; DOI:
10.1021/ja00385a026
PDF
Applications of the intramolecular Diels-Alder reaction to the formation of strained molecules. Synthesis of bridgehead alkenes
Kenneth J. Shea, Sean Wise, Lonnie D. Burke, Peter D. Davis, Jeffrey W. Gilman, and Arthur C. Greeley
pp 5708 - 5715; DOI:
10.1021/ja00385a027
PDF
Synthesis and chemistry of a bridgehead enol lactone
Kenneth J. Shea and Eiji Wada
pp 5715 - 5719; DOI:
10.1021/ja00385a028
PDF
Chiral and stereochemical control via intramolecular Diels-Alder reaction of Z dienes
Stephen G. Pyne, Mark J. Hensel, and P. L. Fuchs
pp 5719 - 5728; DOI:
10.1021/ja00385a029
PDF
Cytochalasin support studies. 5. Conjugate addition of .beta.-oxo ester dianions to vinyl sulfones: a new procedure for seven-ring annulation. Synthesis of a chiral cytochalasin C intermediate via an intramolecular Diels-Alder reaction of a chiral Z diene
S. G. Pyne, D. C. Spellmeyer, S. Chen, and P. L. Fuchs
pp 5728 - 5740; DOI:
10.1021/ja00385a030
PDF
The SN2-SN1 spectrum. 4. The SN2 (intermediate) mechanism for solvolyses of tert-butyl chloride: a revised Y scale of solvent ionizing power based on solvolyses of 1-adamantyl chloride
T. William Bentley and Gillian E. Carter
pp 5741 - 5747; DOI:
10.1021/ja00385a031
PDF
Photochemical and thermal denitrogenations of azoalkanes as mechanistic probes for the diradical intermediates involved in the di-.pi.-methane rearrangement of dibenzobarrelene
Waldemar Adam, Ottorino De Lucchi, Karl Peters, Eva Maria Peters, and Hans Georg Von Schnering
pp 5747 - 5753; DOI:
10.1021/ja00385a032
PDF
Electroorganic chemistry. 62. Reaction of iminium ion with nucleophile: a versatile synthesis of tetrahydroquinolines and julolidines
Tatsuya Shono, Yoshihiro Matsumura, Kenji Inoue, Hiroshi Ohmizu, and Shigenori Kashimura
pp 5753 - 5757; DOI:
10.1021/ja00385a033
PDF
Base-catalyzed halogenation of acetone
Eliana Tapuhi and William P. Jencks
pp 5758 - 5765; DOI:
10.1021/ja00385a034
PDF
.alpha.-Disulfoxide formation during the m-chloroperoxybenzoic acid oxidation of S-(2,2-dimethylpropyl) 2,2-dimethylpropanethiosulfinate
Fillmore Freeman and Christos N. Angeletakis
pp 5766 - 5774; DOI:
10.1021/ja00385a035
PDF
Measurement of nonsynergistic anion binding to transferrin by EPR difference spectroscopy
Donald A. Folajtar and N. Dennis Chasteen
pp 5775 - 5780; DOI:
10.1021/ja00385a036
PDF
Effects of wavelength on the photochemistry of provitamin D3
William G. Dauben and Richard B. Phillips
pp 5780 - 5781; DOI:
10.1021/ja00385a037
PDF
Bicyclo[2.2.1]heptanes in organic synthesis. Total synthesis of the 16-membered ring macrolide tylonolide hemiacetal: synthesis and coupling of the C(3)-C(9) and C(11)-C(17) fragments
Paul A. Grieco, Junji Inanaga, Nan Horng Lin, and Tetsuji Yanami
pp 5781 - 5784; DOI:
10.1021/ja00385a038
PDF
Application of rapid-scan Fourier transform infrared spectroscopy to characterize the monodentate intermediate in the photochemical formation of tetracarbonyl(4,4'-dialkyl-2,2'-bipyridine)metal from hexacarbonylmetal
Romas J. Kazlauskas and Mark S. Wrighton
pp 5784 - 5786; DOI:
10.1021/ja00385a039
PDF
Electrochemical behavior of a surface-confined naphthoquinone derivative.Electrochemical and photoelectrochemical reduction of oxygen to hydrogen peroxide at derivatized electrodes
Gary S. Calabrese, Robert M. Buchanan, and Mark S. Wrighton
pp 5786 - 5788; DOI:
10.1021/ja00385a040
PDF
Diastereoselection in intermolecular nitrile oxide cycloaddition (NOC) reactions: confirmation of the "anti-periplanar effect" through a simple synthesis of 2-deoxy-D-ribose
Alan P. Kozikowski and Arun K. Ghosh
pp 5788 - 5789; DOI:
10.1021/ja00385a041
PDF
Oxidatively promoted alkyl-to-acyl migratory insertion reactions: a thermodynamic assessment for iron methyl complexes
Roy H. Magnuson, Randy Meirowitz, Samu Zulu, and Warren P. Giering
pp 5790 - 5791; DOI:
10.1021/ja00385a042
PDF
13C{2H} Insensitive Nuclei Enhanced by Polarization Transfer (INEPT): a new NMR strategy for isotopic labeling studies
Peter L. Rinaldi and Nicholas J. Baldwin
pp 5791 - 5793; DOI:
10.1021/ja00385a043
PDF
The antitumor drug cis-dichlorodiammineplatinum forms an intrastrand d(GpG) crosslink upon reaction with [d(ApGpGpCpCpT)]2
John P. Caradonna, Stephen J. Lippard, Michael J. Gait, and Mohinder Singh
pp 5793 - 5795; DOI:
10.1021/ja00385a044
PDF
Photodisproportionation of .mu.-oxo-bis[(tetraphenylporphinato)iron(III)]
Robert M. Richman and Mark W. Peterson
pp 5795 - 5796; DOI:
10.1021/ja00385a045
PDF
Schiff base of 11-cis-retinal: photoisomerization as a function of solvent and protonation
Ralph S. Becker, Kenn Freedman, and Guy Causey
pp 5797 - 5798; DOI:
10.1021/ja00385a046
PDF
Electron-transfer kinetics of pentaammineruthenium(III)(histidine-33)-ferricytochrome c. Measurement of the rate of intramolecular electron transfer between redox centers separated by 15.ANG. in a protein
Jay R. Winkler, Daniel G. Nocera, Kathryn M. Yocom, Emilio Bordignon, and Harry B. Gray
pp 5798 - 5800; DOI:
10.1021/ja00385a047
PDF
New approach to pseudoguaianolide sesquiterpene lactone construction. Total synthesis of dl-confertin
Arthur G. Schultz and Linda A. Motyka
pp 5800 - 5801; DOI:
10.1021/ja00385a048
PDF
Convergence, molecular complexity, and synthetic analysis
Steven H. Bertz
pp 5801 - 5803; DOI:
10.1021/ja00385a049
PDF
Quantum yield evidence for a chain reaction in the photochemical decomposition of phenyl azide
Walter H. Waddell and Celia H. Lee
pp 5804 - 5805; DOI:
10.1021/ja00385a050
PDF
Synthetic studies on arene-olefin cycloadditions. 4. Total synthesis of (.+-.)-modhephene
Paul A. Wender and Geoffrey B. Dreyer
pp 5805 - 5807; DOI:
10.1021/ja00385a051
PDF
Titanium-induced reductive elimination. Syntheses of 1,3-dienes
H. M. Walborsky and H. H. Wuest
pp 5807 - 5808; DOI:
10.1021/ja00385a052
PDF
Mechanism and regioisomeric control in palladium(II)-mediated cycloalkenylations. A novel total synthesis of (.+-.)-quadrone
Andrew S. Kende, Bruce Roth, Pauline J. Sanfilippo, and Thomas J. Blacklock
pp 5808 - 5810; DOI:
10.1021/ja00385a053
PDF
Proton NMR studies of 15N-labeled Escherichia coli tRNAfMet. Use of 1J1H-15N couplings to identify imino resonances of uridine-related bases
Richard H. Griffey, C. Dale Poulter, Ziro Yamaizumi, Susumu Nishimura, and Ralph E. Hurd
pp 5810 - 5811; DOI:
10.1021/ja00385a054
PDF
Proton NMR studies of 15N-labeled Escherichia coli tRNAfMet. An unambiguous assignment for the G-U pair and detection of a uridine resonance at 11.4 ppm
Richard H. Griffey, C. Dale Poulter, Ziro Yamaizumi, Susumu Nishimura, and Ralph E. Hurd
pp 5811 - 5813; DOI:
10.1021/ja00385a055
PDF
Reaction of cumene with ozone. Formation of a charge-transfer complex, its thermal and photochemical conversion to cumyl hydrotrioxide, and the mechanism of decomposition of the hydrotrioxide
William A. Pryor, Norio Ohto, and Daniel F. Church
pp 5813 - 5814; DOI:
10.1021/ja00385a056
PDF
Stereochemistry of spermidine synthase
Bernard T. Golding and Ishaq K. Nassereddin
pp 5815 - 5817; DOI:
10.1021/ja00385a057
PDF
Interconversion of nitrite and ammonia: progress toward a model for nitrite reductase
W. Rorer Murphy, Kenneth J. Takeuchi, and Thomas J. Meyer
pp 5817 - 5819; DOI:
10.1021/ja00385a058
PDF
Transfer of oxygen (O2) from triphenyl phosphite ozonide to alkyl-substituted olefins
L. M. Stephenson and Matthew B. Zielinski
pp 5819 - 5820; DOI:
10.1021/ja00385a059
PDF
Diphosphenes (RP:PR). Synthesis and NMR characterization
A. H. Cowley, J. E. Kilduff, T. H. Newman, and M. Pakulski
pp 5820 - 5821; DOI:
10.1021/ja00385a060
PDF
Cis selectivity of salt-free Wittig reactions: a "Leeward Approach" of the aldehyde at the origin?
Manfred Schlosser and Bruno Schaub
pp 5821 - 5823; DOI:
10.1021/ja00385a061
PDF
An inverse reactivity-selectivity relationship. Kinetic nitrogen isotope effects on methyl transfer to pyridines
Joseph L. Kurz and Moheb M. Seif El-Nasr
pp 5823 - 5824; DOI:
10.1021/ja00385a062
PDF
New copper chemistry. V. New heterocuprates with greatly improved thermal stability
Steven H. Bertz, Gary Dabbagh, and G. M. Villacorta
pp 5824 - 5826; DOI:
10.1021/ja00385a063
PDF
Cavitands: synthetic molecular vessels
John R. Moran, Stefan Karbach, and Donald J. Cram
pp 5826 - 5828; DOI:
10.1021/ja00385a064
PDF
Transients generated upon photolysis of colloidal titanium dioxide in acetonitrile containing organic redox couples
Marye Anne Fox, Barbara Lindig, and Chia Chung Chen
pp 5828 - 5829; DOI:
10.1021/ja00385a065
PDF
Carbon-carbon bond formation via the reaction of trialkylallylstannanes with organic halides
Gary E. Keck and John B. Yates
pp 5829 - 5831; DOI:
10.1021/ja00385a066
PDF
Enzymic cyclization of geranyl pyrophosphate to bornyl pyrophosphate. Role of the pyrophosphate moiety
David E. Cane, Akio Saito, Rodney Croteau, John Shaskus, and Mark Felton
pp 5831 - 5833; DOI:
10.1021/ja00385a067
PDF
On the electronic excited states of model chlorophyll
W. Daniel Edwards, John D. Head, and Michael C. Zerner
pp 5833 - 5834; DOI:
10.1021/ja00385a068
PDF
Reinvestigation of NADH analog redox reactions in acetonitrile: consequences of isotope scrambling on kinetic and product isotope effects
Michael F. Powell and Thomas C. Bruice
pp 5834 - 5836; DOI:
10.1021/ja00385a069
PDF
A facile stereospecific synthesis of .alpha.-fluoro .beta.-amino acids
Lila Somekh and Abraham Shanzer
pp 5836 - 5837; DOI:
10.1021/ja00385a070
PDF
Synthesis and structure of novel mononuclear and binuclear zerovalent platinum complexes involving coordination by tin centers to give heteropolymetallic arrays of three or five atoms. A unique bridging function for bivalent tin and a new class of platinum(0) dimers
Gordon W. Bushnell, Donald T. Eadie, Alan Pidcock, Anthony R. Sam, Rupert D. Holmes-Smith, Stephen R. Stobart, Eileen T. Brennan, and T. Stanley Cameron
pp 5837 - 5839; DOI:
10.1021/ja00385a071
PDF
Effectively hypervalent first-row molecules. 1. Octet rule violations by OLi3 and OLi4
Paul v. R. Schleyer, Ernst Ulrich Wuerthwein, and John A. Pople
pp 5839 - 5841; DOI:
10.1021/ja00385a072
PDF
Evidence implicating cyclo-diphosphates as intermediates in reactions of nucleoside phosphorothioates with cyanogen bromide
R. Douglas Sammons, Hsu Tsu Ho, and Perry A. Frey
pp 5841 - 5842; DOI:
10.1021/ja00385a073
PDF
Mercury(II)-induced cyclization of acetylenic alcohols: a new route to enol ethers and substituted enol ethers
Martin Riediker and Jeffrey Schwartz
pp 5842 - 5844; DOI:
10.1021/ja00385a074
PDF
Palladium-catalyzed decarboxylation-dehydrogenation of allyl .beta.-oxo carboxylates and allyl enol carbonates as a novel synthetic method for .alpha.-substituted .alpha.,.beta.-unsaturated ketones
Isao Shimizu and Jiro Tsuji
pp 5844 - 5846; DOI:
10.1021/ja00385a075
PDF
Chiroptical properties of trans-dichlorotetrakis(pyridine)cobalt(III) ion. A fixed propeller conformation
Shunji Utsuno
pp 5846 - 5847; DOI:
10.1021/ja00385a076
PDF
Gas-phase bifluoride ion. An ion cyclotron resonance determination of the hydrogen bond energy in fluoride ion (FHF-) from gas-phase fluoride transfer equilibrium measurements
J. W. Larson and T. B. McMahon
pp 5848 - 5849; DOI:
10.1021/ja00385a077
PDF
Opening of epoxides with trimethylsilyl cyanide to produce .beta.-hydroxy isonitriles. A general synthesis of oxazolines and .beta.-amino alcohols
Paul G. Gassman and Thomas L. Guggenheim
pp 5849 - 5850; DOI:
10.1021/ja00385a078
PDF
The synthesis of nanaomycin A and deoxyfrenolicin by alkyne cycloaddition to chromium-carbene complexes
M. F. Semmelhack, Joseph J. Bozell, Tadahisa Sato, W. Wulff, E. Spiess, and A. Zask
pp 5850 - 5852; DOI:
10.1021/ja00385a079
PDF
Four-component condensation: a new versatile method for the synthesis of substituted prolyl peptides
Ruth F. Nutt and Madeleine M. Joullie
pp 5852 - 5853; DOI:
10.1021/ja00385a080
PDF
Cyclodextrin catalysis in the intramolecular Diels-Alder reaction with the furan diene
Daniel D. Sternbach and Debby M. Rossana
pp 5853 - 5854; DOI:
10.1021/ja00385a081
PDF
Book Reviews

pp 5855 - 5856; DOI:
10.1021/ja00385a600
PDF

Issue 22


Nuclear magnetic resonance examination of organic dianions
Joseph B. Lambert and Stephen M. Wharry
pp 5857 - 5862; DOI:
10.1021/ja00386a001
PDF
Polymer films on electrodes. 10. Electrochemical behavior of solution species at Nafion-tetrathiafulvalenium bromide polymers
Timothy P. Henning, Henry S. White, and Allen J. Bard
pp 5862 - 5868; DOI:
10.1021/ja00386a002
PDF
Photochemistry in polymerized microemulsion systems
S. S. Atik and J. K. Thomas
pp 5868 - 5874; DOI:
10.1021/ja00386a003
PDF
Picosecond laser studies of intramolecular excited-state charge-transfer dynamics and small-chain relaxation
Y. Wang, M. C. Crawford, and K. B. Eisenthal
pp 5874 - 5878; DOI:
10.1021/ja00386a004
PDF
Magnetic field dependence of fluorine-19 nuclear spin polarization. The system tetrafluorobenzoquinone-tetrafluorohydroquinone
Richard S. Hutton, Heinz D. Roth, Marcia L. Manion Schilling, Anthony M. Trozzolo, and Thomas M. Leslie
pp 5878 - 5883; DOI:
10.1021/ja00386a005
PDF
A systematic investigation on the structure and stability of the lowest singlet and triplet states of Si2H4 and SiH3SiH and the carbon analogous compounds SiH2CH2, SiH3CH, CH3SiH, C2H4, and CH3CH
Hans Joachim Koehler and Hans Lischka
pp 5884 - 5889; DOI:
10.1021/ja00386a006
PDF
Electronic structure of long polyiodide chains
Miklos Kertesz and Ferenc Vonderviszt
pp 5889 - 5893; DOI:
10.1021/ja00386a007
PDF
Chemical reaction paths. 8. Stereoisomerization path for triphenylphosphine oxide and related molecules: indirect observation of the structure of the transition state
Erik Bye, W. Bernd Schweizer, and Jack D. Dunitz
pp 5893 - 5898; DOI:
10.1021/ja00386a008
PDF
Basicities of methyl-, methylphenyl-, and phenylphosphines in the gas phase
S. Ikuta, P. Kebarle, G. Michael Bancroft, Tammy Chan, and Richard J. Puddephatt
pp 5899 - 5902; DOI:
10.1021/ja00386a009
PDF
Solution thermodynamic studies. VII. A thermodynamic study of solvent effects on the relative stability of cis- and trans-dichloroethylene: importance of the quadrupolar and octupolar electric moments in the reaction field model
Marie Louise Stien, Michel Claessens, Andre Lopez, and Jacques Reisse
pp 5902 - 5905; DOI:
10.1021/ja00386a010
PDF
ENDOR study of vanadyl(2+)-imidazole complexes in frozen aqueous solution
Charles F. Mulks, Burkhard Kirste, and Hans Van Willigen
pp 5906 - 5911; DOI:
10.1021/ja00386a011
PDF
Systematic design of chemical oscillators. 11. Chlorite oscillators: new experimental examples, tristability, and preliminary classification
Miklos Orban, Christopher Dateo, Patrick De Kepper, and Irving R. Epstein
pp 5911 - 5918; DOI:
10.1021/ja00386a012
PDF
Systematic design of chemical oscillators. 12. Bistability in the oxidation of iron(II) by nitric acid
Miklos Orban and Irving R. Epstein
pp 5918 - 5922; DOI:
10.1021/ja00386a013
PDF
.beta.-Thioxo ketones. 8. X-ray photoelectron-spectroscopic study of the enol-enethiol tautomerism of thioacetylacetone and related .beta.-thioxo ketones
Flemming S. Joergensen, R. S. Brown, Lars Carlsen, and Fritz Duus
pp 5922 - 5926; DOI:
10.1021/ja00386a014
PDF
Phase-transition behavior of saturated, symmetric chain phospholipid bilayer dispersions determined by Raman spectroscopy: correlation between spectral and thermodynamic parameters
Ching Hsien Huang, Jeffrey R. Lapides, and Ira W. Levin
pp 5926 - 5930; DOI:
10.1021/ja00386a015
PDF
Double bonds vs. carbene-like unsaturations in germanium intermediates
Georges Trinquier, Jean Claude Barthelat, and Jacques Satge
pp 5931 - 5936; DOI:
10.1021/ja00386a016
PDF
Photochemical reactivity in organized assemblies. 24. Solute partitioning in aqueous surfactant assemblies: comparison of hydrophobic-hydrophilic interactions in micelles, alcohol-swollen micelles, microemulsions, and synthetic vesicles
John C. Russell and David G. Whitten
pp 5937 - 5942; DOI:
10.1021/ja00386a017
PDF
Monte Carlo study of macrocyclization to form benzo-crown ethers
Wayne L. Mattice and George R. Newkome
pp 5942 - 5944; DOI:
10.1021/ja00386a018
PDF
Gas-phase reactions of rhodium(+) ion with alkanes
G. D. Byrd and B. S. Freiser
pp 5944 - 5950; DOI:
10.1021/ja00386a019
PDF
Auger line-shape studies of the bonding in transition metal carbonyls and nitrosyls
G. D. Stucky, R. R. Rye, D. R. Jennison, and J. A. Kelber
pp 5951 - 5959; DOI:
10.1021/ja00386a020
PDF
Long-range electron transfer in photoexcited cobalt(III)-copper(I) binuclear ions
Kenneth A. Norton and James K. Hurst
pp 5960 - 5966; DOI:
10.1021/ja00386a021
PDF
Thermodynamics of molecular metal formation: metallophthalocyanine and tetrathiafulvalene iodides
William B. Euler, Mary E. Melton, and Brian M. Hoffman
pp 5966 - 5971; DOI:
10.1021/ja00386a022
PDF
Crystal structure of tetrapropylammonium fluoride-containing precursor to fluoride silicalite
Geoffrey D. Price, Joseph J. Pluth, Joseph V. Smith, J. Michael Bennett, and R. Lyle Patton
pp 5971 - 5977; DOI:
10.1021/ja00386a023
PDF
Susceptibility of the tungsten-tungsten quadruple bond to oxidative addition. Structure of a hydrogen chloride adduct
F. Albert Cotton and Graham N. Mott
pp 5978 - 5982; DOI:
10.1021/ja00386a024
PDF
Oxidative fusion of carborane ligands in iron and cobalt complexes: a systematic study
Richard B. Maynard and Russell N. Grimes
pp 5983 - 5986; DOI:
10.1021/ja00386a025
PDF
Molecular and electronic structure of a mixed-spin diiron "wedged" metallacarborane, (Me2C2B4H4)2[FeII(low-spin)][FeII(high-spin)]L2 [L2 = (THF)2 or (MeO)2C2H4], an oxidative fusion intermediate
Russell N. Grimes, Richard B. Maynard, Ekk Sinn, Greg A. Brewer, and Gary J. Long
pp 5987 - 5992; DOI:
10.1021/ja00386a026
PDF
Oxygenation patterns for substituted meso-tetraphenylporphyrin complexes of iron(II). Spectroscopic detection of dioxygen complexes in the absence of amines
Lechoslaw Latos-Grazynski, Ru Jen Cheng, Gerd N. La Mar, and Alan L. Balch
pp 5992 - 6000; DOI:
10.1021/ja00386a027
PDF
Factors influencing the formation of cis and trans isomers in long-chain bis(phosphine) complexes of platinum(II)
William E. Hill, David M. A. Minahan, John G. Taylor, and Charles A. McAuliffe
pp 6001 - 6005; DOI:
10.1021/ja00386a028
PDF
Photochemistry of metal carbonyl alkyls. Study of thermal .beta.-hydrogen transfer in photogenerated, 16-valence-electron alkyldicarbonylcyclopentadienylmolybdenum and -tungsten complexes
Romas J. Kazlauskas and Mark S. Wrighton
pp 6005 - 6015; DOI:
10.1021/ja00386a029
PDF
Synthesis and reactivity of aza-capped encapsulated cobalt(III) ions
I. I. Creaser, R. J. Geue, J. M. Harrowfield, A. J. Herlt, A. M. Sargeson, M. R. Snow, and J. Springborg
pp 6016 - 6025; DOI:
10.1021/ja00386a030
PDF
Electrochemical synthesis and characterization of the single-electron oxidation products of ferric porphyrins
Martin A. Phillippi and Harold M. Goff
pp 6026 - 6034; DOI:
10.1021/ja00386a031
PDF
Crystal structures of the cyclic oligoesters from 6,8-dioxabicyclo[3.2.1]octan-7-one. 3. The cyclic pentamer
Isao Sakuragi, Isao Tanaka, Tamaichi Ashida, Ichiro Tajima, Masahiko Okada, and Hiroshi Sumitomo
pp 6035 - 6039; DOI:
10.1021/ja00386a032
PDF
Chair-boat conformational equilibrium in (+)-(1S,5R)-1,8,8-trimethylbicyclo[3.2.1]octan-3-one
B. Vincent Crist, Stephen L. Rodgers, and David A. Lightner
pp 6040 - 6045; DOI:
10.1021/ja00386a033
PDF
Organic sulfur chemistry. 42. Sulfur-sulfur bond cleavage processes. Selective desulfurization of trisulfides
David N. Harpp and Roger A. Smith
pp 6045 - 6053; DOI:
10.1021/ja00386a034
PDF
O-Sulfated .beta.-lactam hydroxamic acids (monosulfactams). Novel monocyclic .beta.-lactam antibiotics of synthetic origin
E. M. Gordon, M. A. Ondetti, Jelka Pluscec, C. M. Cimarusti, D. P. Bonner, and R. B. Sykes
pp 6053 - 6060; DOI:
10.1021/ja00386a035
PDF
Chemistry of singlet oxygen. 38. Temperature effect on the photooxidation of sulfides
Chee Liang Gu and C. S. Foote
pp 6060 - 6063; DOI:
10.1021/ja00386a036
PDF
Kinetic applications of electron paramagnetic resonance spectroscopy. 39. Bimolecular self-reactions of some N-alkylcarboxyamidyl, N-alkylsulfonamidyl, and N-alkyl-N-(alkoxycarbonyl)aminyl radicals. Intermolecular hydrogen atom abstraction by N-ethylpropionamidyl radical
R. Sutcliffe, M. Anpo, A. Stolow, and K. U. Ingold
pp 6064 - 6070; DOI:
10.1021/ja00386a037
PDF
Kinetic applications of electron paramagnetic resonance spectroscopy. 40. Intramolecular reactions of some N-alkylcarboxamidyl radicals
R. Sutcliffe and K. U. Ingold
pp 6071 - 6075; DOI:
10.1021/ja00386a038
PDF
An efficient stereospecific total synthesis of (.+-.)-anisomycin and related new synthetic antibiotics
Doris P. Schumacher and Stan S. Hall
pp 6076 - 6080; DOI:
10.1021/ja00386a039
PDF
Synthesis of sesquiterpene antitumor lactones. 10. Total synthesis of (.+-.)-parthenin
Clayton H. Heathcock, Colin M. Tice, and Ted C. Germroth
pp 6081 - 6091; DOI:
10.1021/ja00386a040
PDF
A new and efficient cyclization reaction to construct the bicyclomycin ring system: synthesis of N,N'-dimethyl-4-desmethylenebicyclomycin
Robert M. Williams, Oren P. Anderson, Robert Armstrong, John Josey, Harold Meyers, and Carina Eriksson
pp 6092 - 6099; DOI:
10.1021/ja00386a041
PDF
Studies on vitamin D (calciferol) and its analogs. 23. Effect of 3-methyl substituents on the thermal [1,5]- and [1,7]-sigmatropic hydrogen shifts of vinylallenes and other seco steroids related to vitamin D: synthesis of 3-methyl- and 3,3-dimethyl-substituted analogs of 3-deoxy-1.alpha.,25-dihydroxyvitamin D3
Gregory A. Leyes and William H. Okamura
pp 6099 - 6105; DOI:
10.1021/ja00386a042
PDF
Studies on vitamin D (calciferol) and its analogs. 24. Heterocalciferols: novel 3-thia and 3-sulfinyl analogs of 1.alpha.-hydroxyvitamin D3
Alberto Haces and William H. Okamura
pp 6105 - 6109; DOI:
10.1021/ja00386a043
PDF
Total synthesis of verrucarol
Barry M. Trost and Patrick G. McDougal
pp 6110 - 6112; DOI:
10.1021/ja00386a044
PDF
Macrocyclization via an isomerization reaction at high concentrations promoted by palladium templates
Barry M. Trost and Robert W. Warner
pp 6112 - 6114; DOI:
10.1021/ja00386a045
PDF
The 12-s-cis-locked retinoids (vitamin A): synthesis and novel spectral properties
Roshantha A. S. Chandraratna and William H. Okamura
pp 6114 - 6115; DOI:
10.1021/ja00386a046
PDF
Electrocyclization of 1-allenyldienes: novel synthesis of drimatrienes and related trans-decalins
Wolfgang Reischl and William H. Okamura
pp 6115 - 6117; DOI:
10.1021/ja00386a047
PDF
Chlorophyll a-sensitized trans-cis photoisomerization of all-trans-.beta.-carotene
Niels Henrik Jensen, Anne B. Nielsen, and Robert Wilbrandt
pp 6117 - 6119; DOI:
10.1021/ja00386a048
PDF
Generation of (.eta.5-cyclopentadienyl)dicarbonyliron carbene complexes via protonation of the corresponding alkenyl complexes
Kenneth A. M. Kremer, Gee Hong Kuo, Edward J. O'Connor, Paul Helquist, and Robert C. Kerber
pp 6119 - 6121; DOI:
10.1021/ja00386a049
PDF
Lifetimes of conjugated diene triplets
Richard A. Caldwell and Majar Singh
pp 6121 - 6122; DOI:
10.1021/ja00386a050
PDF
Ketonization of enols. Enol content and acid dissociation constants of simple carbonyl compounds
Y. Chiang, A. J. Kresge, and P. A. Walsh
pp 6122 - 6123; DOI:
10.1021/ja00386a051
PDF
Use of the N-oxide of p-cyano-N,N-dimethylaniline as an "oxygen" donor in a cytochrome P-450 model system
Michael W. Nee and Thomas C. Bruice
pp 6123 - 6125; DOI:
10.1021/ja00386a052
PDF
Cyclophanes. 15. Thermolysis of 1,1',4,4'-tetrahydro-1,4:1',4'-diepoxy[2.2](1,4)naphthalenophane. Intracavity nonbonded interaction and evidence for the intermediacy of an isobenzofuranophane
Ann Halverson and Philip M. Keehn
pp 6125 - 6126; DOI:
10.1021/ja00386a053
PDF
New EXAFS models for the iron sites of the iron-molybdenum cofactor in nitrogenase: the [(p-CH3C6H4S)2FeS2FeS2MoS2]3- trianion and the [(C6H5O)2FeS2MoS2]2- dianion
Boon Keng Teo, Mark R. Antonio, R. H. Tieckelmann, H. C. Silvis, and B. A. Averill
pp 6126 - 6129; DOI:
10.1021/ja00386a054
PDF
Total synthesis of gibberellic acid. A simple synthesis of a key intermediate
E. J. Corey and John E. Munroe
pp 6129 - 6130; DOI:
10.1021/ja00386a055
PDF
Oxygen-18-labeling evidence against a hexacoordinate phosphorus intermediate in the alkaline hydrolysis of ethyl ethylene phosphate
David G. Gorenstein and Kazunari Taira
pp 6130 - 6132; DOI:
10.1021/ja00386a056
PDF
EXAFS and Raman evidence for histidine binding at the active site of protocatechuate 3,4-dioxygenase
R. H. Felton, W. L. Barrow, S. W. May, A. L. Sowell, S. Goel, G. Bunker, and E. A. Stern
pp 6132 - 6134; DOI:
10.1021/ja00386a057
PDF
A reactive three-metal carbide cluster precursor, [Fe3(CO)9(CCO)]2-
J. W. Kolis, E. M. Holt, M. Drezdzon, K. H. Whitmire, and D. F. Shriver
pp 6134 - 6135; DOI:
10.1021/ja00386a058
PDF
Synthesis of a cyclotrigermane and its conversion to a digermene
Satoru Masamune, Yuji Hanzawa, and David J. Williams
pp 6136 - 6137; DOI:
10.1021/ja00386a059
PDF
A new synthesis of penems, the oxalimide cyclization reaction
Adriano Afonso, Frank Hon, Jay Weinstein, A. K. Ganguly, and Andrew T. McPhail
pp 6138 - 6139; DOI:
10.1021/ja00386a060
PDF
An ion gate membrane: electrochemical control of ion permeability through a membrane with an embedded electrode
Paul Burgmayer and Royce W. Murray
pp 6139 - 6140; DOI:
10.1021/ja00386a061
PDF
Orchestrated silylene to silene to silylene rearrangement. The unusual behavior of C3H5 silylsilylenes
Stephanie A. Burns, Gary T. Burns, and Thomas J. Barton
pp 6140 - 6142; DOI:
10.1021/ja00386a062
PDF
Direct observation of the special salt effect: picosecond dynamics of ion-pair exchange
John D. Simon and Kevin S. Peters
pp 6142 - 6144; DOI:
10.1021/ja00386a063
PDF
Evidence for inversion of configuration in reactions involving radical processes
E. C. Ashby and Robert DePriest
pp 6144 - 6146; DOI:
10.1021/ja00386a064
PDF
Inversion of configuration in a free-radical process. Mechanisms of the reactions of trimethylstannyl alkalis with (+)-2-bromooctane
Henry G. Kuivila and Mikhail S. Alnajjar
pp 6146 - 6147; DOI:
10.1021/ja00386a065
PDF
Photochemistry in multichromophoric systems: remote energy transfer from naphthyl to a carbon-sulfur bond in 2,2-bis(naphthylmethyl)-1,3-dithianes
Rina Arad-Yellin and David F. Eaton
pp 6147 - 6149; DOI:
10.1021/ja00386a066
PDF
Structure elucidation of a potent mutagen from human feces
Nobuhiro Hirai, David G. I. Kingston, Roger L. Van Tassell, and Tracy D. Wilkins
pp 6149 - 6150; DOI:
10.1021/ja00386a067
PDF
Cobalt-catalyzed carbalkoxylation of olefins: a new mechanism
D. Milstein and J. L. Huckaby
pp 6150 - 6152; DOI:
10.1021/ja00386a068
PDF
Bisfuran formation in aflatoxin biosynthesis: the fate of the averufin side chain
Craig A. Townsend, Siegfried B. Christensen, and Steven G. Davis
pp 6152 - 6153; DOI:
10.1021/ja00386a069
PDF
Bisfuran formation in aflatoxin biosynthesis: the role of versiconal acetate
Craig A. Townsend, Siegfried B. Christensen, and Steven G. Davis
pp 6154 - 6155; DOI:
10.1021/ja00386a070
PDF
Complexes of the new ligand tetracyanobiimidazole
P. G. Rasmussen, R. L. Hough, J. E. Anderson, O. H. Bailey, and J. C. Bayon
pp 6155 - 6156; DOI:
10.1021/ja00386a071
PDF
Facile preparation of 2,3-benzo-1,4-diphenyl-7-silanorbornadiene derivatives and the first clear evidence of silylene-to-disilene thermal rearrangement
H. Sakurai, H. Sakaba, and Y. Nakadaira
pp 6156 - 6158; DOI:
10.1021/ja00386a072
PDF
Synthesis and structure of the {[(C7H8)Rh]5(cis-Nb2W4O19)2}3- anion
C. J. Besecker, W. G. Klemperer, and V. W. Day
pp 6158 - 6159; DOI:
10.1021/ja00386a073
PDF
Reversible iron-nitrogen migration of alkyl, aryl, or vinyl groups in iron porphyrins: a possible passage between .sigma. FeIII(porphyrin)(R) and FeII(N-R)(porphyrin)complexes
Daniel Mansuy, Jean Paul Battioni, Daniel Dupre, Eric Sartori, and Genevieve Chottard
pp 6159 - 6161; DOI:
10.1021/ja00386a074
PDF
Osmium(IV)-mediated oxidative dehydrogenation of coordinated amines: crystal and molecular structures of cis-1,2-ethanediaminebis(1,2-ethanediaminato(1-))osmium(IV) dibromide
Peter A. Lay, Alan M. Sargeson, Brian W. Skelton, and Allan H. White
pp 6161 - 6164; DOI:
10.1021/ja00386a075
PDF
Total synthesis of the C19-C29 aliphatic segment of (+)-rifamycin S - A formal synthesis of the antibiotic
S. Hanessian, J. R. Pougny, and I. K. Boessenkool
pp 6164 - 6166; DOI:
10.1021/ja00386a076
PDF
Additions and Corrections - General Methods of Synthesis of Indole Alkaloids. 141,2 Short Routes of Construction of Yohimboid and Ajmalicinoid Alkaloid Systems and Their 13C Nuclear Magnetic Resonance Spectral Analysis.
Ernest Wenkert, Ching-Jer Chang, H. P. S. Chawla, David W. Cochran, Edward W. Hagaman, James C. King, and Kazuhiko Orito
pp 6166 - 6166; DOI:
10.1021/ja00386a600
PDF
Additions and Corrections - Total Synthesis of the Yohimbines
Ernest Wenkert, Timothy D. J. Halls, Gerhard Kunesch, Kazuhiko Orito, Richard L. Stephens, Wayne A. Temple, and Jhillu Yadav
pp 6166 - 6166; DOI:
10.1021/ja00386a601
PDF
Additions and Corrections - Reactions of Metal-Metal Multiple Bonds. 8. Forming Mo-Mo Quadruple Bonds by Reductive Elimination (Alkyl Group Disproportionation) in the Reactions of 1,2-Mo2R2(NMe2)4Compounds (M≡M) with Carbon Dioxide and 1,3-Diaryltriazines
M. J. Chetcuti, M. H. Chisholm, K. Folting, D. A. Haitko, and J. C. Huffman
pp 6166 - 6166; DOI:
10.1021/ja00386a602
PDF
Additions and Corrections - Coordination Chemistry of Metal Surfaces. 31. Benzene and Toluene Interactions with Nickel Surfaces.
C. M .Friend, and E. L. Muetterties
pp 6166 - 6166; DOI:
10.1021/ja00386a603
PDF
Additions and Corrections - Microwave Spectrum and Unusual Geometry of Propadienone (Methylene Ketene)
Ronald D. Brown, Peter D. Godfrey, Robert Champion, and Donald McNaughton
pp 6167 - 6167; DOI:
10.1021/ja00386a604
PDF
Additions and Corrections - Synthesis and Structure of Bis(2,4,6-tri-tert-butylphenyl)diphosphene: Isolation of a True "Phosphobenzene"
Masaaki Yoshifuji, Ichiro Shima, Naoki Inamoto, Ken Hirotsu, and Taiichi Higuchi
pp 6167 - 6167; DOI:
10.1021/ja00386a605
PDF
Additions and Corrections - The Effect of Pressure on the Rate of Alkaline Fading of Malachite Green. A REinvestigaiton.
W. J. Le Noble, Elzbieta Gebicka, and Sushil Srivastava
pp 6167 - 6167; DOI:
10.1021/ja00386a606
PDF
Additions and Corrections - Synthesis of Saccharides and Related Polyhydroxylated Natural Products. 3. Efficient Conversion of 2,3-erythro-Aldoses to 2,3-threo-Aldoses
Albert W. M. Lee, Victor S. Martin, Santoru Masamune, K. Barry Sharpless, and Frederick J. Walker
pp 6167 - 6167; DOI:
10.1021/ja00386a607
PDF
Additions and Corrections - Direct Observation of a Hydrocarbon Singlet 1,3-Biradical by Picosecond Fluorescence Spectroscopy
David F. Kelley, P. M. Rentzepis, Mark R. Mazur, and Jerome A. Berson
pp 6167 - 6167; DOI:
10.1021/ja00386a608
PDF
Additions and Corrections - Reduction of Ch3NC and CH3CN by the Reduced Species of [Fe4S4(SPh)4]2- and [Mo2Fe6S8(SPh)9]3-: Model Reactions to Nitrogenase
Koji Tanaka, Yashinobu Imasaka, Masahiro Tanaka, Makoto Honjo, and Toshio Tanaka
pp 6167 - 6167; DOI:
10.1021/ja00386a609
PDF
Additions and Corrections - Carbon-Phosphorous Heterocycles. Synthesis, Separation, and Resolution of Stereoisomers of 1,1'-(1,2-Ethanediyl)bis(1,2,3,4-tetrahydro-4,4-dimethyl-1-phenylphosphinolinium) Diperchlorate. The Use of 31P NMR Analysis To Monitor the Resolution.
Narayanasamy Gurusamy, and K. Darrell Berlin
pp 6167 - 6167; DOI:
10.1021/ja00386a610
PDF
Book Reviews

pp 6168 - 6168; DOI:
10.1021/ja00386a611
PDF

Issue 23


Quantum chemical studies of a model for peptide bond formation: formation of formamide and water from ammonia and formic acid
Tetsuro Oie, Gilda H. Loew, Stanley K. Burt, J. Stephen Binkley, and Robert D. MacElroy
pp 6169 - 6174; DOI:
10.1021/ja00387a001
PDF
Structural effects on twisted olefin triplet lifetimes. Styrene derivatives
R. A. Caldwell and C. V. Cao
pp 6174 - 6180; DOI:
10.1021/ja00387a002
PDF
Fourier transform infrared matrix spectra of substituted alkene-hydrogen fluoride complexes
Lester Andrews, Gary L. Johnson, and Benuel J. Kelsall
pp 6180 - 6186; DOI:
10.1021/ja00387a003
PDF
Structure of perfluoromethanimine by microwave, infrared, and Raman spectroscopy, electron diffraction, and ab initio methods
Dines Christen, Heinz Oberhammer, Robert M. Hammaker, Shi Cheng Chang, and Darryl D. DesMarteau
pp 6186 - 6190; DOI:
10.1021/ja00387a004
PDF
Proximate charge effects. 2. Enthalpies of solvent transfer in the choline-anhydrocholine equilibrium
Paul Haberfield and Jeffrey Pessin
pp 6191 - 6194; DOI:
10.1021/ja00387a005
PDF
Use of ion-selective electrodes for monitoring oscillating reactions. 1. Potential response of the silver halide membrane electrodes to hypohalous acids
Z. Noszticzius, E. Noszticzius, and Z. A. Schelly
pp 6194 - 6199; DOI:
10.1021/ja00387a006
PDF
Photochemical reactivity in organized assemblies. 29. Photoreactions and photoelectrochemical effects in supported multilayer assemblies. Mechanisms of interfacial reactions involving reactive supports, metalloporphyrin surface films, and solutions
K. Chandrasekaran, C. Giannotti, K. Monserrat, J. P. Otruba, and D. G. Whitten
pp 6200 - 6206; DOI:
10.1021/ja00387a007
PDF
Direct measurement of the chemical shift anisotropy of thallium-205 using the matrix isolation technique. The thallium/potassium/nitrate system
Kenneth R. Metz and James F. Hinton
pp 6206 - 6210; DOI:
10.1021/ja00387a008
PDF
Organic molecule ejection from surfaces due to heavy particle bombardment
Barbara J. Garrison
pp 6211 - 6217; DOI:
10.1021/ja00387a009
PDF
Dynamic NMR study of cyclopropylcarbonyl fluoride. A comparison of the conjugating abilities of the cyclopropyl, vinyl, and phenyl groups
Eric A. Noe and Rose M. Young
pp 6218 - 6220; DOI:
10.1021/ja00387a010
PDF
Radiative lifetime of vibrationally excited iodo- and bromobenzene ions by two-laser photodissociation spectroscopy
Jeffrey P. Honovich and Robert C. Dunbar
pp 6220 - 6224; DOI:
10.1021/ja00387a011
PDF
Stereodynamics of diethylmethylamine and triethylamine
C. Hackett Bushweller, Stephen H. Fleischman, Gilbert L. Grady, Paul McGoff, Christopher D. Rithner, Michael R. Whalon, John G. Brennan, Richard P. Marcantonio, and Raymond P. Dominigue
pp 6224 - 6236; DOI:
10.1021/ja00387a012
PDF
Nonplanar conformers and the phase behavior of solid n-alkanes
Mark Maroncelli, Song Ping Qi, Herbert L. Strauss, and Robert G. Snyder
pp 6237 - 6247; DOI:
10.1021/ja00387a013
PDF
Influence of ion pairing on cation transport in the polymer electrolytes formed by poly(ethylene oxide) with sodium tetrafluoroborate and sodium tetrahydroborate
R. Dupon, B. L. Papke, M. A. Ratner, D. H. Whitmore, and D. F. Shriver
pp 6247 - 6251; DOI:
10.1021/ja00387a014
PDF
Peroxy spin probe studies of motion in poly(vinylidene fluoride)
Darbha Suryanarayana and Larry Kevan
pp 6251 - 6254; DOI:
10.1021/ja00387a015
PDF
Formation, thermochemistry, and relative stabilities of proton-bound dimers of oxygen n-donor bases from ion cyclotron resonance solvent-exchange equilibrium measurements
J. W. Larson and T. B. McMahon
pp 6255 - 6261; DOI:
10.1021/ja00387a016
PDF
Photoreduction of flavin by NADH. A flash photolysis photo-CIDNP study
P. J. Hore, A. Volbeda, K. Dijkstra, and R. Kaptein
pp 6262 - 6267; DOI:
10.1021/ja00387a017
PDF
Reactivity and decay pathways of photoexcited anilinonaphthalenes
K. H. Grellmann and U. Schmitt
pp 6267 - 6272; DOI:
10.1021/ja00387a018
PDF
Torsional potential function of n-butane. Correlation effects in the quantum-mechanical prediction of the syn-anti energy difference
F. A. Van-Catledge and N. L. Allinger
pp 6272 - 6273; DOI:
10.1021/ja00387a019
PDF
Oxidation of ascorbic acid and dehydroascorbic acid by superoxide ion in aprotic media
Donald T. Sawyer, Glaico Chiericato, and Tohru Tsuchiya
pp 6273 - 6278; DOI:
10.1021/ja00387a020
PDF
Porphyrins. 43. Triplet sublevel emission of platinum tetrabenzoporphyrin by spectrothermal principal component decomposition
Thijs J. Aartsma, Martin Gouterman, Clemens Jochum, Alvin L. Kwiram, Barry V. Pepich, and Loren D. Williams
pp 6278 - 6283; DOI:
10.1021/ja00387a021
PDF
Cyclohexaamylose complexation with organic solvent molecules
Robert I. Gelb, Lowell M. Schwartz, Michael Radeos, Robert B. Edmonds, and Daniel A. Laufer
pp 6283 - 6288; DOI:
10.1021/ja00387a022
PDF
Exciplex formation in dodecylammonium propionate reversed micellar systems
E. Gelade, N. Boens, and F. C. De Schryver
pp 6288 - 6292; DOI:
10.1021/ja00387a023
PDF
Nickel ions effect a highly specific 1,4-dehydrogenation of hydrocarbons in the gas phase: metallacycles are not involved
L. F. Halle, Raymond Houriet, Manfred M. Kappes, Ralph H. Staley, and J. L. Beauchamp
pp 6293 - 6297; DOI:
10.1021/ja00387a024
PDF
Peptide conformation. 17. cyclo-(L-Pro-L-Pro-D-Pro). Conformational analysis by 270- and 500-MHZ one- and two-dimensional proton NMR spectroscopy
Horst Kessler, Wolfgang Bermel, Axel Friedrich, Gerhard Krack, and William E. Hull
pp 6297 - 6304; DOI:
10.1021/ja00387a025
PDF
Optical vs. thermodynamic basicities: probe lead(2+) ion spectra in thermodynamically characterized molten chloroaluminate solutions
C. A. Angell and P. D. Bennett
pp 6304 - 6309; DOI:
10.1021/ja00387a026
PDF
Spectroscopic studies of copper(II) bound at the native copper site or substituted at the native zinc site of bovine erythrocuprein (superoxide dismutase)
Michael W. Pantoliano, Joan S. Valentine, and Lawrence A. Nafie
pp 6310 - 6317; DOI:
10.1021/ja00387a027
PDF
Characterization of superoxide-metalloporphyrin reaction products: effective use of deuterium NMR spectroscopy
Ataollah Shirazi and Harold M. Goff
pp 6318 - 6322; DOI:
10.1021/ja00387a028
PDF
Multiple metal-carbon bonds. 26. .alpha.-Hydride elimination from methylene and neopentylidene ligands. Preparation and protonation of tungsten(IV) methylidyne and neopentylidyne complexes
S. J. Holmes, D. N. Clark, H. W. Turner, and R. R. Schrock
pp 6322 - 6329; DOI:
10.1021/ja00387a029
PDF
Dinuclear copper(II) cryptates of macrocyclic ligands: synthesis, crystal structure, and magnetic properties. Mechanism of the exchange interaction through bridging azido ligands
Jacques Comarmond, Pierre Plumere, Jean Marie Lehn, Yvette Agnus, Remy Louis, Raymond Weiss, Olivier Kahn, and Irene Morgenstern-Badarau
pp 6330 - 6340; DOI:
10.1021/ja00387a030
PDF
Photochemical reactions of dirhenium decacarbonyl with water
David R. Gard and Theodore L. Brown
pp 6340 - 6347; DOI:
10.1021/ja00387a031
PDF
Stereochemistry and detailed mechanism of the conversion of carbon-13-labeled cis-acetylbenzoyltetracarbonylrhenate(I) to cis-acetylphenyltetracarbonylrhenate(I)
Charles P. Casey and Laima M. Baltusis
pp 6347 - 6353; DOI:
10.1021/ja00387a032
PDF
Crystalline-state reaction of cobaloxime complexes by x-ray exposure. 2. An order-to-order racemization in the crystal of [(S)-1-cyanoethyl](pyridine)bis(dimethylglyoximato) cobalt(III)
Yuji Ohashi, Kazunori Yanagi, Toshiharu Kurihara, Yoshio Sasada, and Yoshiaki Ohgo
pp 6353 - 6359; DOI:
10.1021/ja00387a033
PDF
Dinuclear elimination as a route to unusual bridging carbonyls and acetyls in heterobimetallic complexes
John A. Marsella, John C. Huffman, Kenneth G. Caulton, Bruno Longato, and Jack R. Norton
pp 6360 - 6368; DOI:
10.1021/ja00387a034
PDF
Structure of the binuclear iron center in hemerythrin by x-ray absorption spectroscopy
W. T. Elam, E. A. Stern, J. D. McCallum, and J. Sanders-Loehr
pp 6369 - 6373; DOI:
10.1021/ja00387a035
PDF
Electrochemistry in liquid sulfur dioxide. 3. Electrochemical production of new highly oxidized 2,2'-bipyridine complexes of ruthenium and iron
John G. Gaudiello, Paul R. Sharp, and Allen J. Bard
pp 6373 - 6377; DOI:
10.1021/ja00387a036
PDF
Photochemistry of inter- and intramolecular .alpha.-diketone:norbornene systems
Ronald R. Sauers, Peter C. Valenti, and Charles A. Crichlow
pp 6378 - 6382; DOI:
10.1021/ja00387a037
PDF
Isobaric and isochoric activation parameters for the water-catalyzed hydrolysis of p-methoxyphenyl 2,2-dichloropropionate in typically aqueous solutions
Herman A. J. Holterman and Jan B. F. N. Engberts
pp 6382 - 6384; DOI:
10.1021/ja00387a038
PDF
Conformations of saturated six-membered ring phosphorus heterocycles. cis- and trans-2-oxo- and -2-thio-2-(dimethylamino)-5-tert-butyl-1,3,2 .lambda.5-oxazaphosphorinanes: molecules related to cyclophosphamide
Gurdip S. Bajwa, Subramanian Chandrasekaran, J. Howard Hargis, Alan E. Sopchik, Duane Blatter, and Wesley G. Bentrude
pp 6385 - 6392; DOI:
10.1021/ja00387a039
PDF
Acid-catalyzed solvolysis of N-sulfonyl- and N-acyl-O-arylhydroxylamines. Phenoxenium ions
Yasuyuki Endo, Koichi Shudo, and Toshihiko Okamoto
pp 6393 - 6397; DOI:
10.1021/ja00387a040
PDF
Photochemistry of ketones in solution. 66. Experimental evidence for the intermediacy of singlet (S1) and triplet (T2) n,.pi.* states in the [1,3]-sigmatropic acyl shift of photoexcited 3-methyl-3-(1-cyclopentenyl)butan-2-one
David I. Schuster and Lidia T. Calcaterra
pp 6397 - 6405; DOI:
10.1021/ja00387a041
PDF
Concerted homolysis in thermal decomposition of peresters from .alpha.-hydroperoxydiazenes
Avtar S. Nazran and John Warkentin
pp 6405 - 6407; DOI:
10.1021/ja00387a042
PDF
Neighboring-group participation by the carbon-carbon bond of an epoxide. Synthesis and solvolysis of derivatives of 3-oxa-endo-tricyclo[3.2.1.02,4]octan-anti-8-ol
Paul G. Gassman, John G. Schaffhausen, and Peter W. Raynolds
pp 6408 - 6411; DOI:
10.1021/ja00387a043
PDF
Synthesis and solvolysis of sulfonate esters of 3-phenyl-3-aza-endo-tricyclo[3.2.1.02,4]octan-anti-8-ols. Identification of the carbon-carbon bond of aziridines as a powerful neighboring group in solvolysis reactions
Paul G. Gassman, John G. Schaffhausen, Frank D. Starkey, and Peter W. Raynolds
pp 6411 - 6414; DOI:
10.1021/ja00387a044
PDF
Marine natural products: parguerol, deoxyparguerol, and isoparguerol. New brominated diterpenes with modified pimarane skeletons from the sea hare Aplysia dactylomela
Francis J. Schmitz, Dennis P. Michaud, and Paul G. Schmidt
pp 6415 - 6423; DOI:
10.1021/ja00387a045
PDF
Molecular mechanics simulation of protein-ligand interactions: binding of thyroid hormone analogs to prealbumin
Jeffrey M. Blaney, Paul K. Weiner, Andrew Dearing, Peter A. Kollman, Eugene C. Jorgensen, Stuart J. Oatley, Jane M. Burridge, and Colin C. F. Blake
pp 6424 - 6434; DOI:
10.1021/ja00387a046
PDF
Model chemistry for a covalent mechanism of action of orotidine 5'-phosphate decarboxylase
Richard B. Silverman and Michael P. Groziak
pp 6434 - 6439; DOI:
10.1021/ja00387a047
PDF
Biomimetic synthesis of anatabine from 2,5-dihydropyridine produced by the oxidative decarboxylation of baikiain
Edward Leete and Mark E. Mueller
pp 6440 - 6444; DOI:
10.1021/ja00387a048
PDF
Arrhenius parameters for the tert-butoxy radical reactions with trimethylsilane in the gas phase
Chan Ryang Park, Se Ahn Song, Yong Eun Lee, and Kwang Yul Choo
pp 6445 - 6448; DOI:
10.1021/ja00387a049
PDF
A novel conjugate hydrocyanation with titanium tetrachloride-tert-butyl isocyanide
Yoshihiko Ito, Hidehito Kato, Hiroshi Imai, and Takeo Saegusa
pp 6449 - 6450; DOI:
10.1021/ja00387a050
PDF
[Fe3O(OCOR)6L3]+-catalyzed epoxidation of olefinic alcohol acetates by molecular oxygen
Satoru Ito, Koh Inoue, and Masakatsu Mastumoto
pp 6450 - 6452; DOI:
10.1021/ja00387a051
PDF
Relationship between the Freundlich adsorption constants K and 1/N hydrophobic adsorption
Ikuo Abe, Katsumi Hayashi, Tsuneaki Hirashima, and Mutsuo Kitagawa
pp 6452 - 6453; DOI:
10.1021/ja00387a052
PDF
Bis[(trimethylsilyl)methylidene]tetrakis(trimethylphosphine)dibromodimolybdenum (M.tplbond.M)
K. J. Ahmed, M. H. Chisholm, I. P. Rothwell, and J. C. Huffman
pp 6453 - 6454; DOI:
10.1021/ja00387a053
PDF
O-Methylation and O-protonation of coordinated nitric oxide. Observation of an anion-assisted O-H to M-H tautomerization
Robert E. Stevens and Wayne L. Gladfelter
pp 6454 - 6457; DOI:
10.1021/ja00387a054
PDF
Stereochemical variations in the cyclocondensation of aldehydes with siloxydienes. An application to the erythronolide series
Samuel Danishefsky, Eric R. Larson, and David Askin
pp 6457 - 6458; DOI:
10.1021/ja00387a055
PDF
Mechanistic variations in the Lewis acid-catalyzed cyclocondensation of siloxydienes with aldehydes
Eric R. Larson and Samuel Danishefsky
pp 6458 - 6460; DOI:
10.1021/ja00387a056
PDF
Synthesis of d-biotin from L-cystine via intramolecular [3+2]cycloaddition
Enrico G. Baggiolini, Hsi Lin Lee, Giacomo Pizzolato, and Milan R. Uskokovic
pp 6460 - 6462; DOI:
10.1021/ja00387a057
PDF
Methoxy group conformations of phenyl methyl ethers in solution
Alexandros Makriyannis and Stephen Fesik
pp 6462 - 6463; DOI:
10.1021/ja00387a058
PDF
Pseudopterolide, an irregular diterpenoid with unusual cytotoxic properties from the Caribbean sea whip Pseudopterogorgia acerosa (Pallas) (Gorgonacea)
Maury M. Bandurraga, William Fenical, Stephen F. Donovan, and Jon Clardy
pp 6463 - 6465; DOI:
10.1021/ja00387a059
PDF
Stereocontrolled synthesis of (+)-negamycin from an acyclic homoallylamine by 1,3-asymmetric induction
Yi Fong Wang, Toshio Izawa, Susumu Kobayashi, and Masaji Ohno
pp 6465 - 6466; DOI:
10.1021/ja00387a060
PDF
1,1-Di-tert-butyldiazene
Daniel K. McIntyre and Peter B. Dervan
pp 6466 - 6468; DOI:
10.1021/ja00387a061
PDF
Synthesis of saccharides and related polyhydroxylated natural products. 4. .alpha.-D- and .beta.-D-C-Glycopyranosides (2,6-dialkyl-substituted tetrahydropyrans)
Lawrence A. Reed, Yukishige Ito, Satoru Masamune, and K. Barry Sharpless
pp 6468 - 6470; DOI:
10.1021/ja00387a062
PDF
Photonitration of phenols by tetranitromethane under visible light
Stanley Seltzer, Eric Lam, and Lester Packer
pp 6470 - 6471; DOI:
10.1021/ja00387a063
PDF
.beta.-Alkyl transfer in a lanthanide model for chain termination
Patricia L. Watson and D. Christopher Roe
pp 6471 - 6473; DOI:
10.1021/ja00387a064
PDF
Limits on the activation parameters for automerization of cyclobutadiene-1,2-d2
David W. Whitman and Barry K. Carpenter
pp 6473 - 6474; DOI:
10.1021/ja00387a065
PDF
Nitrobenzene valence bond structures: evidence in support of through-resonance from oxygen-17 shieldings
Robert R. Fraser, Arthur J. Ragauskas, and J. B. Stothers
pp 6475 - 6476; DOI:
10.1021/ja00387a066
PDF
Intramolecular type-II "metallo-ene" reactions of (2-alkenylallyl)magnesium chlorides: regio- and stereochemical studies
Wolfgang Oppolzer, Rita Pitteloud, and Heinrich F. Strauss
pp 6476 - 6477; DOI:
10.1021/ja00387a067
PDF
Short and selective total synthesis of (.+-.)-khusimone via an intramolecular type II "magnesium-ene" reaction
Wolfgang Oppolzer and Rita Pitteloud
pp 6478 - 6479; DOI:
10.1021/ja00387a068
PDF
Action of 2,3-oxidosqualene lanosterol cyclase on 15'-nor-18,19-dihydro-2,3-oxidosqualene
Eugene E. Van Tamelen, Eric J. Leopold, Stuart A. Marson, and Hans R. Waespe
pp 6479 - 6480; DOI:
10.1021/ja00387a069
PDF
Bioorganic characterization and mechanism of the 2,3-oxidosqualene .fwdarw. lanosterol conversion
Eugene E. Van Tamelen
pp 6480 - 6481; DOI:
10.1021/ja00387a070
PDF
Book Reviews

pp 6481 - 6482; DOI:
10.1021/ja00387a600
PDF

Issue 24


Reactions of cyclic ethers with amide and hydroxide ions in the gas phase
Charles H. DePuy, Ellen C. Beedle, and Veronica M. Bierbaum
pp 6483 - 6488; DOI:
10.1021/ja00388a001
PDF
Long-distance fluorescence quenching by electron transfer in rigid solutions
J. R. Miller, J. A. Peeples, M. J. Schmitt, and G. L. Closs
pp 6488 - 6493; DOI:
10.1021/ja00388a002
PDF
Reactions of triplet diphenylcarbene by hydrogen atom tunneling in rigid media
Matthew S. Platz, V. P. Senthilnathan, Bradford B. Wright, and C. W. McCurdy
pp 6494 - 6501; DOI:
10.1021/ja00388a003
PDF
Electron spin resonance and electron spin echo studies of the photoionization of tetramethylbenzidine in frozen aqueous anionic, cationic, and nonionic micellar solutions. Effect of micelle type and anionic micelle size
P. A. Narayana, A. S. W. Li, and Larry Kevan
pp 6502 - 6505; DOI:
10.1021/ja00388a004
PDF
Kinetics and thermodynamics of restricted rotation of the formyl group in nitrobenzaldehyde anion radicals
Mario Branca, Aldo Gamba, Mario Barzaghi, and Massimo Simonetta
pp 6506 - 6515; DOI:
10.1021/ja00388a005
PDF
Investigation of some intermolecular electron transfer reactions of cytochrome c by electrochemical methods
H. Allen O. Hill and Nicholas J. Walton
pp 6515 - 6519; DOI:
10.1021/ja00388a006
PDF
Nucleophilic aromatic substitution in the gas phase: the importance of fluoride ion-molecule complexes formed in gas-phase reactions between nucleophiles and some alkyl pentafluorophenyl ethers
Steen Ingemann, Nico M. M. Nibbering, Sally A. Sullivan, and Charles H. DePuy
pp 6520 - 6527; DOI:
10.1021/ja00388a007
PDF
Surface-enhanced resonance Raman scattering from water-soluble porphyrins adsorbed on a silver electrode
Therese M. Cotton, Steven G. Schultz, and Richard P. Van Duyne
pp 6528 - 6532; DOI:
10.1021/ja00388a008
PDF
Chemistry of triplet vs. singlet biradicals. An ab initio MCSCF study of trimethylene
Charles Doubleday, James W. McIver, and Michael Page
pp 6533 - 6542; DOI:
10.1021/ja00388a009
PDF
Picosecond dynamics of ion pairs: the effect of hydrogen bonding on ion-pair intermediates
John D. Simon and Kevin S. Peters
pp 6542 - 6547; DOI:
10.1021/ja00388a010
PDF
Anion-exchange properties of ammonium salts immobilized on silica gel
Pietro Tundo, Paolo Venturello, and Enrico Angeletti
pp 6547 - 6551; DOI:
10.1021/ja00388a011
PDF
Phase-transfer catalysts immobilized and adsorbed on alumina and silica gel
Pietro Tundo, Paolo Venturello, and Enrico Angeletti
pp 6551 - 6555; DOI:
10.1021/ja00388a012
PDF
Structural and optical studies of the topochemical polymerization mechanism of the bis(p-toluenesulfonate) of 2,4-hexadiyne-1,6-diol
P. A. Albouy, P. Keller, and J. P. Pouget
pp 6556 - 6561; DOI:
10.1021/ja00388a013
PDF
Thermodynamics of conformational change in 1,3-butadiene studied by high-temperature ultraviolet absorption spectroscopy
Philip W. Mui and Ernest Grunwald
pp 6562 - 6566; DOI:
10.1021/ja00388a014
PDF
Bond homolysis in high-temperature fluids
S. E. Stein, D. A. Robaugh, A. D. Alfieri, and R. E. Miller
pp 6567 - 6570; DOI:
10.1021/ja00388a015
PDF
Arbusov rearrangement involving (.eta.5-C5H5)Co(dppe)I+ and methyl phosphite. A proton and phosphorus-31 NMR study of the mechanism leading to the formation of an organometallic phosphonate complex
Shayne J. Landon and Thomas B. Brill
pp 6571 - 6575; DOI:
10.1021/ja00388a016
PDF
Structure-directing properties of sodium(+) ion in the solution ordering of guanosine 5'-monophosphate. Stoichiometry of aggregation, binding to ethidium, and modes of sodium(+) ion complexation
Elene Bouhoutsos-Brown, Christopher L. Marshall, and Thomas J. Pinnavaia
pp 6576 - 6584; DOI:
10.1021/ja00388a017
PDF
Structure and stereochemical nonrigidty in the triarylphosphinepalladium bis(hexafluoroacetylacetonate), a new isomeric class of palladium bis(hexafluoroacetylacetonate) complexes
A. R. Siedle, R. A. Newmark, and L. H. Pignolet
pp 6584 - 6590; DOI:
10.1021/ja00388a018
PDF
Surface-modified photochemistry. Preparation of silica-supported triiron dodecacarbonyl via irradiation of absorbed iron pentacarbonyl
Robert L. Jackson and Mark R. Trusheim
pp 6590 - 6596; DOI:
10.1021/ja00388a019
PDF
Bis(1-methyluracilato-N3)-cis-diammineplatinum(II) tetrahydrate and bis(.mu.-1-methyluracilato-N3,O4)-cis-diammineplatinum(II)diaquacopper(II) sulfate 4.5-hydrate (head-head). Preparation, crystal structures, and implications for the formation of heteronuclear platinum-metal complexes
Dietmar Neugebauer and Bernhard Lippert
pp 6596 - 6601; DOI:
10.1021/ja00388a020
PDF
Zinc(II)-, aluminum(III)-, and copper(II)-catalyzed decarboxylation of 2-oxalopropionic acid
Gregory Kubala and Arthur E. Martell
pp 6602 - 6609; DOI:
10.1021/ja00388a021
PDF
Trans-2,6-bis[(dimethylamino)methyl]phenyl-N,N',C complexes of palladium(II) and platinum(II). Crystal structure of [PtI[MeC6H3(CH2NMe2)2-o,o']]BF4: a cyclohexadienyl carbonium ion with a .sigma.-bonded metal substituent
David M. Grove, Gerard Van Koten, Jaap N. Louwen, Jan G. Noltes, Anthony L. Spek, and Henk J. C. Ubbels
pp 6609 - 6616; DOI:
10.1021/ja00388a022
PDF
NMR spectroscopic studies on chalcogen compounds. 4. Carbon-13 isotope effect on selenium-77 and tellurium-125 nuclear shielding and its correlation with carbon-selenium bond distances. Tellurium-123 isotope effect on tellurium-125 nuclear shielding
Willy Gombler
pp 6616 - 6620; DOI:
10.1021/ja00388a023
PDF
Metallopolymer photochemistry. Photophysical, photochemical and photoelectrochemical properties of (bpy)2RuII sites bound to poly(4-vinylpyridine)
Jeffrey M. Calvert, Jonathan V. Caspar, Robert A. Binstead, T. David Westmoreland, and Thomas J. Meyer
pp 6620 - 6627; DOI:
10.1021/ja00388a024
PDF
Synthesis, molecular structure, and exchange coupling in the alternatingly bridged and alternatingly spaced linear-chain compound catena-dichloro(3,6-dithiaoctane)copper(II)
Marilyn M. Olmstead, W. Kenneth Musker, Leonard W. Ter Haar, and William E. Hatfield
pp 6627 - 6631; DOI:
10.1021/ja00388a025
PDF
A kinetic study of the reactions of carbonyl ylides formed by the addition of fluorenylidene to ketones
P. C. Wong, D. Griller, and J. C. Scaiano
pp 6631 - 6635; DOI:
10.1021/ja00388a026
PDF
Novel conformational distributions of methylproline peptides
Norma G. Delaney and Vincent Madison
pp 6635 - 6641; DOI:
10.1021/ja00388a027
PDF
One-electron oxidation of trialkylsulfenamides
Stephen F. Nelsen, Daniel J. Steffek, Glen T. Cunkle, and Peter M. Gannett
pp 6641 - 6646; DOI:
10.1021/ja00388a028
PDF
An effective approach to stereocontrolled lactone annulation. Application to the total synthesis of pentalenolactone E methyl ester and a partial elaboration of quadrone
Leo A. Paquette, Gary D. Annis, and Heinrich Schostarez
pp 6646 - 6653; DOI:
10.1021/ja00388a029
PDF
Micellar effects upon spontaneous hydrolyses and their relation to mechanism
Hamad Al-Lohedan, Clifford A. Bunton, and Marutirao M. Mhala
pp 6654 - 6660; DOI:
10.1021/ja00388a030
PDF
Photochemistry of 1,1-diazenes. Direct and sensitized photolyses of N-(2,2,5,5-tetramethylpyrrolidyl)nitrene, dl-N-(2,5-diethyl-2,5-dimethylpyrrolidyl)nitrene, and N-(2,2,6,6-tetramethylpiperidyl)nitrene
Peter G. Schultz and Peter B. Dervan
pp 6660 - 6668; DOI:
10.1021/ja00388a031
PDF
Palladium-mediated cycloaddition approach to cyclopentanoid natural products. (.+-.)-Albene
Barry M. Trost and Patrice Renaut
pp 6668 - 6672; DOI:
10.1021/ja00388a032
PDF
Tautomerism of phenindione, 2-phenyl-1,3-indandione, in dipolar aprotic/hydrocarbon solvent mixtures
J. D. Pipkin and V. J. Stella
pp 6672 - 6680; DOI:
10.1021/ja00388a033
PDF
Carbanions. 22. Tautomerism between 2-p-biphenylyl-1,1,2-trimethylpropyl and 1,1,2,2-tetramethyl-6-phenylspiro[2.5]octa-4,6-dienyl anions. Alkali metal cation effects
Erling Grovenstein and Pang Chia Lu
pp 6681 - 6684; DOI:
10.1021/ja00388a034
PDF
Reaction of nitrogen dioxide with alkenes and polyunsaturated fatty acids: addition and hydrogen-abstraction mechanisms
William A. Pryor, John W. Lightsey, and Daniel F. Church
pp 6685 - 6692; DOI:
10.1021/ja00388a035
PDF
Mechanisms of acid-catalyzed proton exchange in N-methyl amides
Charles L. Perrin and Gloria M. L. Arrhenius
pp 6693 - 6696; DOI:
10.1021/ja00388a036
PDF
Electroorganic chemistry. 60. Electroorganic synthesis of enamides and enecarbamates and their utilization in organic synthesis
Tatsuya Shono, Yoshihiro Matsumura, Kenji Tsubata, Yoshihiro Sugihara, Shinichiro Yamane, Takenobu Kanazawa, and Takao Aoki
pp 6697 - 6703; DOI:
10.1021/ja00388a037
PDF
Two syntheses of dl-aplysistatin
Thomas R. Hoye, Andrew J. Caruso, Joseph F. Dellaria, and Mark J. Kurth
pp 6704 - 6709; DOI:
10.1021/ja00388a038
PDF
Cobalt(III)-promoted syntheses of the amino acids (RS)-2-cyclopropylglycine and (R)- and (S)-proline
Peter J. Lawson, Mark G. McCarthy, and Alan M. Sargeson
pp 6710 - 6716; DOI:
10.1021/ja00388a039
PDF
Cobalt(III)-promoted synthesis of .beta.-carboxyaspartic acid. Intramolecular addition of coordinated amide ion to the olefin center in the (3,3-bis(ethoxycarbonyl)-2-propenoato)pentaaminecobalt(III) ion
Nicholas E. Dixon and Alan M. Sargeson
pp 6716 - 6725; DOI:
10.1021/ja00388a040
PDF
Minor and trace sterols in marine invertebrates. 31. Isolation and structure elucidation of 23H-isocalysterol, a naturally occurring cyclopropene. Some comparative observations on the course of hydrogenolytic ring opening of steroidal cyclopropenes and cyclopropanes
Lian Niang Li, Hui Ting Li, Robert W. Lang, Toshihiro Itoh, Donato Sica, and Carl Djerassi
pp 6726 - 6732; DOI:
10.1021/ja00388a041
PDF
Nuclear magnetic resonance studies of the solution chemistry of metal complexes. 19. Formation constants for the complexation of methylmercury by glutathione, ergothioneine, and hemoglobin
R. Stephen Reid and Dallas L. Rabenstein
pp 6733 - 6737; DOI:
10.1021/ja00388a042
PDF
Kinetics of the protonation of buffer and hydration of carbon dioxide catalyzed by human carbonic anhydrase II
R. S. Rowlett and D. N. Silverman
pp 6737 - 6741; DOI:
10.1021/ja00388a043
PDF
Interactions between bilirubin and albumins using picosecond fluorescence and circularly polarized luminescence spectroscopy
Chieu Tran and Godfrey S. Beddard
pp 6741 - 6747; DOI:
10.1021/ja00388a044
PDF
Molecular motions of supercoiled and circular DNA. A phosphorus-31 nuclear magnetic resonance study
Peter Bendel, Orgad Laub, and Thomas L. James
pp 6748 - 6754; DOI:
10.1021/ja00388a045
PDF
Isolation and characterization of pyrimidine-psoralen-pyrimidine photodiadducts from DNA
David Kanne, Kenneth Straub, John E. Hearst, and Henry Rapoport
pp 6754 - 6764; DOI:
10.1021/ja00388a046
PDF
Epimerization of aldoses by molybdate involving a novel rearrangement of the carbon skeleton
Michael L. Hayes, Nicholas J. Pennings, Anthony S. Serianni, and Robert Barker
pp 6764 - 6769; DOI:
10.1021/ja00388a047
PDF
Mechanism of the aminolysis of alkyl benzimidates
Hiram F. Gilbert and William P. Jencks
pp 6769 - 6779; DOI:
10.1021/ja00388a048
PDF
Proton and carbon-13 NMR of vinyl ketene and its dimerization by [4 + 2] cycloaddition. Synthesis of sibirinone and bicyclo[4.2.1]nona-3,7-diene-2-one
Walter S. Trahanovsky, Bruce W. Surber, Marty C. Wilkes, and Margaret M. Preckel
pp 6779 - 6781; DOI:
10.1021/ja00388a049
PDF
Preparation and characterization of a compound containing the octachloroditungstate (tungsten-tungsten quadruple bond) ion, [W2Cl8]4-
F. Albert Cotton, Graham N. Mott, Richard R. Schrock, and Lynda G. Sturgeoff
pp 6781 - 6782; DOI:
10.1021/ja00388a050
PDF
Novel catalytic oxidations of terminal olefins by cobalt(II)-Schiff base complexes
Alan Zombeck, Dorothy E. Hamilton, and Russell S. Drago
pp 6782 - 6784; DOI:
10.1021/ja00388a051
PDF
Ablative photodecomposition: action of far-ultraviolet (193 nm) laser radiation on poly(ethylene terephthalate) films
R. Srinivasan and W. J. Leigh
pp 6784 - 6785; DOI:
10.1021/ja00388a052
PDF
New class of serine protease inactivators based on isatoic anhydride
A. R. Moorman and R. H. Abeles
pp 6785 - 6786; DOI:
10.1021/ja00388a053
PDF
Electronic absorption spectra of polarity-polarizability indicators in the gas phase
Mohammed Essfar, Georges Guiheneuf, and Jose Luis M. Abboud
pp 6786 - 6787; DOI:
10.1021/ja00388a054
PDF
Shikimate-derived metabolites. 11. A total synthesis of (.+-.)-chorismic acid
Bruce Ganem, Nobuo Ikota, V. B. Muralidharan, Warren S. Wade, Stanley D. Young, and Yusuke Yukimoto
pp 6787 - 6788; DOI:
10.1021/ja00388a055
PDF
Evidence for a single-electron-transfer mechanism in aldol condensation reactions
E. C. Ashby, J. N. Argyropoulos, G. Richard Meyer, and A. B. Goel
pp 6788 - 6789; DOI:
10.1021/ja00388a056
PDF
2n Framework electron clusters: directed synthesis of octachlorooctaborane, B8Cl8. The activation of carbon-hydrogen bonds
S. L. Emery and J. A. Morrison
pp 6790 - 6791; DOI:
10.1021/ja00388a057
PDF
Magnetic interactions in metalloporphyrin .pi.-radical cations of copper and iron
William F. Scholz, Christopher A. Reed, Young Ja Lee, W. Robert Scheidt, and George Lang
pp 6791 - 6793; DOI:
10.1021/ja00388a058
PDF
Iron(III)-porphyrin .pi.-cation radical complexes. Molecular structures and magnetic properties
Georges Buisson, Alain Deronzier, Emile Duee, Pierre Gans, Jean Claude Marchon, and Jean Rene Regnard
pp 6793 - 6796; DOI:
10.1021/ja00388a059
PDF
Conformations and competitive [2 + 2] cycloadditions of intramolecular exciplexes of some anisylalkenyl 9-phenanthrenecarboxylates
Hirochika Sakuragi, Katsumi Tokumaru, Hiroki Itoh, Kohki Terakawa, Katsuo Kikuchi, Richard A. Caldwell, and Chien Chung Hsu
pp 6796 - 6797; DOI:
10.1021/ja00388a060
PDF
Evidence for oxide transfer from coordinated carbon dioxide to coordinated carbon monoxide in an anionic carbon dioxide complex
John M. Maher, Gary R. Lee, and N. John Cooper
pp 6797 - 6799; DOI:
10.1021/ja00388a061
PDF
Multiple quantum filters for elucidating NMR coupling networks
U. Piantini, O. W. Sorensen, and Richard R. Ernst
pp 6800 - 6801; DOI:
10.1021/ja00388a062
PDF
Mechanism of sodium borohydride-cobaltous chloride reductions
Stephen W. Heinzman and Bruce Ganem
pp 6801 - 6802; DOI:
10.1021/ja00388a063
PDF
Dihydroxamate analogs of rhodotorulic acid and an exceptional dimer: preparation and crystal structure of Fe2[iso-C3H7N(O)C(:O)(CH2)5C(:O)N(O)-iso-C3H7]2(.mu.-OCH3)2
Susan J. Barclay, Paul E. Riley, and Kenneth N. Raymond
pp 6802 - 6804; DOI:
10.1021/ja00388a064
PDF
Tetracyanoquinodimethane-modified electrodes
Roger W. Day, Gyoergy Inzelt, James F. Kinstle, and James Q. Chambers
pp 6804 - 6805; DOI:
10.1021/ja00388a065
PDF
Use of trichlorodimethylethyl as a protecting group and tributylphosphine as a deprotecting agent in oligonucleotide synthesis
Robert L. Letsinger, E. Patrick Groody, and Toshiki Tanaka
pp 6805 - 6806; DOI:
10.1021/ja00388a066
PDF
Multiple metal-carbon bonds. 30. Rhenium(VII) neopentylidene and neopentylidyne complexes
D. Scott Edwards and Richard R. Schrock
pp 6806 - 6808; DOI:
10.1021/ja00388a067
PDF
Reaction of tungsten(VI) alkylidyne complexes with acetylenes to give tungstenacyclobutadiene and cyclopentadienyl complexes
Steven F. Pedersen, Richard R. Schrock, Melvyn Rowen Churchill, and Harvey J. Wasserman
pp 6808 - 6809; DOI:
10.1021/ja00388a068
PDF
Protodesilylation reactions of simple .beta.-hydroxysilanes (and .alpha.-hydroxysilanes). Homo-Brook rearrangements
Paul F. Hudrlik, Anne M. Hudrlik, and Ashok K. Kulkarni
pp 6809 - 6811; DOI:
10.1021/ja00388a069
PDF
Cryoenzymology of proteases: NMR detection of a productive thioacyl derivative of papain at subzero temperatures
J. Paul G. Malthouse, Michael P. Gamcsik, Alan S. F. Boyd, Neil E. Mackenzie, and A. Ian Scott
pp 6811 - 6813; DOI:
10.1021/ja00388a070
PDF
A critical examination of transient assignments in the laser flash photolysis of 9-diazofluorene
D. Griller, C. R. Montgomery, J. C. Scaiano, M. S. Platz, and L. Hadel
pp 6813 - 6814; DOI:
10.1021/ja00388a071
PDF
Irradiation of diazofluorene on a picosecond time scale and at very low temperature: a reassignment of transient structures
Beth Ellen Brauer, Peter B. Grasse, Kenneth J. Kaufmann, and Gary B. Schuster
pp 6814 - 6816; DOI:
10.1021/ja00388a072
PDF
Total synthesis of aplasmomycin. Stereocontrolled construction of the C(3)-C(17) fragment
E. J. Corey, Bai Chuan Pan, Duy H. Hua, and Donald R. Deardorff
pp 6816 - 6818; DOI:
10.1021/ja00388a073
PDF
Total synthesis of aplasmomycin
E. J. Corey, Duy H. Hua, Bai Chuan Pan, and Steven P. Seitz
pp 6818 - 6820; DOI:
10.1021/ja00388a074
PDF
The formation of perthiocarbonate ligands following the addition of CS2 to binary molybdenum-sulfur complexes. The crystal and molecular structures of the (Ph4P)2[(CS4)2MoS].DMF and (Ph4P)2[(CS4)Mo2S4(CS4)].1/2DMF complexes
D. Coucouvanis and M. Draganjac
pp 6820 - 6822; DOI:
10.1021/ja00388a075
PDF
Photochemistry of a triplet biradical. Cyclization, cleavage, and hydrogen shift in 2-isopropylidenecyclopentane-1,3-diyl
Steven P. Schmidt, Allan R. Pinhas, James H. Hammons, and Jerome A. Berson
pp 6822 - 6823; DOI:
10.1021/ja00388a076
PDF
High-temperature pathways on the energy surface connecting a vinylidene and a trimethylenemethane. Gas-phase generation of a bicyclo[3.1.0]hex-1-ene and a novel cyclization of a 1,2,5-triene
Mark R. Mazur, Stephen E. Potter, Allan R. Pinhas, and Jerome A. Berson
pp 6823 - 6824; DOI:
10.1021/ja00388a077
PDF
Surface photochemistry: deviation of the course of reaction in benzoin ether photolysis by adsorption on silica gel
Paul De Mayo, Akira Nakamura, Peter W. K. Tsang, and S. King Wong
pp 6824 - 6825; DOI:
10.1021/ja00388a078
PDF
Stable gold hydride complexes
H. Lehner, D. Matt, P. S. Pregosin, L. M. Venanzi, and A. Albinati
pp 6825 - 6827; DOI:
10.1021/ja00388a079
PDF
Hemispherands containing cyclic urea and anisyl units
Donald J. Cram, Ira B. Dicker, George M. Lein, Carolyn B. Knobler, and Kenneth N. Trueblood
pp 6827 - 6828; DOI:
10.1021/ja00388a080
PDF
Spherand hosts containing cyclic urea units
Donald J. Cram, Ira B. Dicker, Carolyn B. Knobler, and Kenneth N. Trueblood
pp 6828 - 6830; DOI:
10.1021/ja00388a081
PDF
1,2-Silaoxetane. Isolation and characterization in the reaction of silaethylene with ketones
Wataru Ando, Akira Sekiguchi, and Takashi Sato
pp 6830 - 6831; DOI:
10.1021/ja00388a082
PDF
Regioselective arylation of silyl enol ethers of methyl ketones with aryl bromides
Isao Kuwajima and Hirokazu Urabe
pp 6831 - 6833; DOI:
10.1021/ja00388a083
PDF
High-pressure NMR studies of hemoproteins. Pressure-induced structural changes in the heme environments of cyanometmyoglobin
Isao Morishima and Mitsunobu Hara
pp 6833 - 6834; DOI:
10.1021/ja00388a084
PDF
Electroreduction of carbon dioxide catalyzed by iron-sulfur cluster compounds [Fe4S4(SR)4]2-
Meguru Tezuka, Tatsuhiko Yajima, Atsuhiko Tsuchiya, Yoichi Matsumoto, Yasuzo Uchida, and Masanobu Hidai
pp 6834 - 6836; DOI:
10.1021/ja00388a085
PDF
Hydrogen/deuterium secondary isotope effects in the thermal decomposition of a 1,2-diaza-1-cyclobutene. Mechanism of thermolysis
Henrik Olsen
pp 6836 - 6838; DOI:
10.1021/ja00388a086
PDF
Small ring cyclic allenes: an ab initio study of the structure of 1,2-cyclohexadiene
Michael W. Schmidt, Richard O. Angus, and Richard P. Johnson
pp 6838 - 6839; DOI:
10.1021/ja00388a087
PDF
Construction of bridging organosulfur ligands in hexacarbonyldiiron complexes via proximity-induced reactions of bis(.mu.-mercapto)bis(tricarbonyliron) with .alpha.,.beta.-unsaturated substrates
Dietmar Seyferth and Gary B. Womack
pp 6839 - 6841; DOI:
10.1021/ja00388a088
PDF
Copper(I) catalysis of olefin photoreactions. 11. Synthesis of multicyclic furans and butyrolactones via photobicyclization of homoallyl vinyl and diallyl ethers
Swadesh R. Raychaudhuri, Subrata Ghosh, and Robert G. Salomon
pp 6841 - 6842; DOI:
10.1021/ja00388a089
PDF
Conrotatory ring opening of cis-fused 3-aminocyclobutenes. X-ray analysis of a cis,trans-2H-thiocin
G. W. Visser, W. Verboom, D. N. Reinhoudt, S. Harkema, and G. J. Van Hummel
pp 6842 - 6844; DOI:
10.1021/ja00388a090
PDF
General synthesis of chiral borinic acid esters. Asymmetric synthesis of acyclic ketones via asymmetric hydroboration-carbenoidation
Herbert C. Brown, Prabhakar K. Jadhav, and Manoj C. Desai
pp 6844 - 6846; DOI:
10.1021/ja00388a091
PDF
Isolation and structure of bryostatin 1
George R. Pettit, Cherry L. Herald, Dennis L. Doubek, Delbert L. Herald, Edward Arnold, and Jon Clardy
pp 6846 - 6848; DOI:
10.1021/ja00388a092
PDF
1,3-Dilithiopropanes
J. W. F. L. Seetz, G. Schat, O. S. Akkerman, and F. Bickelhaupt
pp 6848 - 6849; DOI:
10.1021/ja00388a093
PDF
Experimental observations of large interactions of .pi.* orbitals through four bonds
V. Balaji, K. D. Jordan, P. D. Burrow, M. N. Paddon-Row, and H. K. Patney
pp 6849 - 6851; DOI:
10.1021/ja00388a094
PDF
Diprotonated methane, CH62+, and diprotonated ethane, C2H82+
Koop Lammertsma, George A. Olah, Mario Barzaghi, and Massimo Simonetta
pp 6851 - 6852; DOI:
10.1021/ja00388a095
PDF
Bimolecular substitution at carbon in neopentyl-like silylcarbinyl sulfonates
Peter J. Stang, Mladen Ladika, Yitzhak Apeloig, Amnon Stanger, Melvyn D. Schiavelli, and Michael R. Hughey
pp 6852 - 6854; DOI:
10.1021/ja00388a096
PDF
Ene reaction of singlet oxygen: an entropy-controlled process determines the reaction rate
John R. Hurst and Gary B. Schuster
pp 6854 - 6856; DOI:
10.1021/ja00388a097
PDF
Amphoteric ligands. 1. Facile acyl formation and crystal structure of a novel complex containing an .eta.2(C,O)-acylphosphonium ligand
Jay A. Labinger and Joel S. Miller
pp 6856 - 6858; DOI:
10.1021/ja00388a098
PDF
Amphoteric ligands. 2. Formation and structure of a novel carbon-hydrogen-bond-containing product from hydridomanganese pentacarbonyl and an amphoteric ligand
David L. Grimmett, Jay A. Labinger, John N. Bonfiglio, Steven T. Masuo, Eileen Shearin, and Joel S. Miller
pp 6858 - 6859; DOI:
10.1021/ja00388a099
PDF
Estimation of a cyclic 1,4-biradical lifetime using the cyclopropylcarbinyl rearrangement
Paul S. Engel and Dalen E. Keys
pp 6860 - 6861; DOI:
10.1021/ja00388a100
PDF
Design synthesis of a sequence-specific DNA cleaving molecule. (Distamycin-EDTA)iron(II)
Peter G. Shultz, John S. Taylor, and Peter B. Dervan
pp 6861 - 6863; DOI:
10.1021/ja00388a101
PDF
Biosynthesis of swainsonine in Rhizoctonia leguminicola. Epimerization at the ring fusion
Marilyn J. Schneider, Frank S. Ungemach, Harry P. Broquist, and Thomas M. Harris
pp 6863 - 6864; DOI:
10.1021/ja00388a102
PDF
Phototherapy for neonatal jaundice. Configurational isomers of bilirubin
Antony F. McDonagh, Lucita A. Palma, Francesc R. Trull, and David A. Lightner
pp 6865 - 6867; DOI:
10.1021/ja00388a103
PDF
Phototherapy for neonatal jaundice. Stereospecific and regioselective photoisomerization of bilirubin bound to human serum albumin and NMR characterization of intramolecularly cyclized photoproducts
Antony F. McDonagh, Lucita A. Palma, and David A. Lightner
pp 6867 - 6869; DOI:
10.1021/ja00388a104
PDF
Phenylalanine hydroxylase: structural determination of the tetrahydropterin intermediates by carbon-13 NMR spectroscopy
Robert A. Lazarus, Charles W. DeBrosse, and Stephen J. Benkovic
pp 6869 - 6871; DOI:
10.1021/ja00388a105
PDF
Structural determination of quinonoid dihydropterins
Robert A. Lazarus, Charles W. DeBrosse, and Stephen J. Benkovic
pp 6871 - 6872; DOI:
10.1021/ja00388a106
PDF
Hydrogen-deuterium kinetic isotope effects of 16 and 22 in the oxidation of hydrogen peroxide
John A. Gilbert, Susan W. Gersten, and Thomas J. Meyer
pp 6872 - 6873; DOI:
10.1021/ja00388a107
PDF
Longer-range chiroptical effects in conjugated cisoid dienes: contributions by homoallylic and bis-homoallylic alkyl groups
Albert W. Burgstahler, Guenther Wahl, Neeta Dang, Mark E. Sanders, and Alicia Nemirovsky
pp 6873 - 6874; DOI:
10.1021/ja00388a108
PDF
Preservation of chirality in the photochemical interconversion of trans-.DELTA.1,3-hexalin and trans,cis,trans-cyclodeca-1,3,5-triene
Bogdan Matuszewski, Albert W. Burgstahler, and Richard S. Givens
pp 6874 - 6876; DOI:
10.1021/ja00388a109
PDF
Mechanism of the triphenylphosphine and diethyl azodicarboxylate induced dehydration reactions (Mitsunobu reaction). The central role of pentavalent phosphorus intermediates
Edward Grochowski, Bruce D. Hilton, Robert J. Kupper, and Christopher J. Michejda
pp 6876 - 6877; DOI:
10.1021/ja00388a110
PDF
Mechanism of the isomerization of 1,5,9-cyclododecatriyne to hexaradialene: 1,2:3,4:5,6-tricyclobutabenzene is not an intermediate
William V. Dower and K. Peter C. Vollhardt
pp 6878 - 6879; DOI:
10.1021/ja00388a111
PDF
2-Bromo-3-trimethylsilylpropene. An annulating agent for five-membered carbo- and heterocycles
Barry M. Trost and Brian P. Coppola
pp 6879 - 6881; DOI:
10.1021/ja00388a112
PDF
Palladium-mediated macroheterocyclization. A synthesis of inandenin-12-one
Barry M. Trost and Janine Cossy
pp 6881 - 6882; DOI:
10.1021/ja00388a113
PDF
Synthesis of a new type of cyclic peptide: a bicyclic nonapeptide
John C. Tolle, Mark A. Staples, and Elkan R. Blout
pp 6883 - 6884; DOI:
10.1021/ja00388a114
PDF
Evidence for the intermediacy of hexamethyl-1,4-disilabenzene
Jonathan D. Rich and Robert West
pp 6884 - 6886; DOI:
10.1021/ja00388a115
PDF
Characterization of catalyzed carbon surfaces by derivatization: solid-state NMR
C. A. Mims, K. D. Rose, M. T. Melchior, and J. K. Pabst
pp 6886 - 6887; DOI:
10.1021/ja00388a116
PDF
Additions and Corrections - Optimized Geometries of the Saddle-Point Rotamers of Formamide
Roman F. Nalewajski
pp 6887 - 6887; DOI:
10.1021/ja00388a600
PDF
Additions and Corrections - Synthetic Applications of Conjugated Azocarbinols. Radical Chain Hydrophenylation and Hydrocyclohexenylation of Haloethenes.
Yau-Min Chang, Ralph Profetto, and John Workentin
pp 6887 - 6887; DOI:
10.1021/ja00388a601
PDF
Additions and Corrections - Electron-Rich Carboranes. Studies of a Stereochemically Novel System, (CH3)4C4B7H9, an 11-Vertex Arachno Cluster
David C. Finster, and Russell N. Grimes
pp 6887 - 6887; DOI:
10.1021/ja00388a602
PDF
Additions and Corrections - Stereoselective Total Synthesis of 1α,25-Dihydroxycholecalciferol
Enrico G. Baggiolini, Jerome A. Iacobelli, Bernard M. Hennessy, and Milan R. Uskokovic
pp 6887 - 6887; DOI:
10.1021/ja00388a603
PDF
Atomic Energy Levels
Libero J. Bartolotti
pp 6888 - 6888; DOI:
10.1021/ja00388a604
PDF
Additions and Corrections - Wavelength and Solvent Effects on Ionic Photodissociation of Charge-Transfer Complexes. The Hexamethyl(Dewar benzene) System
Guilford Jones II, and William G. Becker
pp 6888 - 6888; DOI:
10.1021/ja00388a605
PDF
Additions and Corrections - Role of Solvent in the Mechanism of Amine Oxide Thermolysis Elucidated by the Temperature Dependence of a Kinetic Isotope Effect
Harold Kwart, and Martin Brechibiel
pp 6888 - 6888; DOI:
10.1021/ja00388a606
PDF
Book Reviews

pp 6888 - 6890; DOI:
10.1021/ja00388a607
PDF

Issue 25


Electrogenerated chemiluminescence. 41. Electrogenerated chemiluminescence and chemiluminescence of the Ru(2,21 - bpy)32+-S2O82- system in acetonitrile-water solutions
Henry S. White and Allen J. Bard
pp 6891 - 6895; DOI:
10.1021/ja00389a001
PDF
Solution thermodynamic studies. Part 6. Enthalpy-entropy compensation for the complexation reactions of some crown ethers with alkaline cations: a quantitative interpretation of the complexing properties of 18-crown-6
Gabriel Michaux and Jacques Reisse
pp 6895 - 6899; DOI:
10.1021/ja00389a002
PDF
CI study of geometrical relaxation in the excited states of butadiene. Energy surfaces and properties for simultaneous torsion and elongation of one double bond
V. Bonacic-Koutecky, M. Persico, D. Dohnert, and A. Sevin
pp 6900 - 6907; DOI:
10.1021/ja00389a003
PDF
Optical studies of a simple polyene Schiff base: low-lying electronic levels in the free, hydrogen-bonded, and protonated species
Bruce Palmer, Brian Jumper, William Hagan, J. Clayton Baum, and Ronald L. Christensen
pp 6907 - 6913; DOI:
10.1021/ja00389a004
PDF
Spectroscopic studies of the thermal rearrangement reaction of dimethyl 3,6-dichloro-2,5-dihydroxyterephthalate in the solid state
Jacek Swiatkiewicz and Paras N. Prasad
pp 6913 - 6918; DOI:
10.1021/ja00389a005
PDF
Proton-induced quenching and hydrogen-deuterium isotope-exchange reactions of methoxynaphthalenes
Haruo Shizuka and Seiji Tobita
pp 6919 - 6927; DOI:
10.1021/ja00389a006
PDF
Nitrogen quadrupole coupling measurements on nitric oxide-nitrogen dioxide complex (ON-NO2) using the Flygare-Balle pulsed-beam spectrometer
Stephen G. Kukolich
pp 6927 - 6929; DOI:
10.1021/ja00389a007
PDF
Photochemical reactivity in organized assemblies. 30. Self-sensitized photooxidation of protoporphyrin IX derivatives in aqueous surfactant solutions; product and mechanistic studies
G. Sidney Cox, Marianne Krieg, and David G. Whitten
pp 6930 - 6937; DOI:
10.1021/ja00389a008
PDF
Triplet-to-singlet cyclopropylidene-allene rearrangement. A molecular example of spin angular momentum coupling in orthogonal π systems
Ying Nan Chiu
pp 6937 - 6942; DOI:
10.1021/ja00389a009
PDF
Hydrogen-evolving semiconductor photocathodes: nature of the junction and function of the platinum group metal catalyst
A. Heller, E. Aharon-Shalom, W. A. Bonner, and B. Miller
pp 6942 - 6948; DOI:
10.1021/ja00389a010
PDF
Effect of water activity on the rate of proton dissociation
D. Huppert, E. Kolodney, M. Gutman, and E. Nachliel
pp 6949 - 6953; DOI:
10.1021/ja00389a011
PDF
Intramolecular hydrogen bonding in gramicidin S. 2. Ornithine
Eric M. Krauss and Sunney I. Chan
pp 6953 - 6961; DOI:
10.1021/ja00389a012
PDF
Structural characterizations of salts of HCr(CO)5- and (μ-H)2BH2Cr(CO)4- and studies of their interconversions
Marcetta Y. Darensbourg, Robert Bau, Melodye W. Marks, Robert R. Burch, Jr., Joseph C. Deaton, and Sydney Slater
pp 6961 - 6969; DOI:
10.1021/ja00389a013
PDF
Phosphinonitrene, phosphazene, and aminophosphinidene. Structures and stabilities
Georges Trinquier
pp 6969 - 6977; DOI:
10.1021/ja00389a014
PDF
Crystal structure of dehydrated strontium-exchanged zeolite A. Absence of near-zero-coordinate strontium(2+) ion. Presence of aluminum complex
Joseph J. Pluth and Joseph V. Smith
pp 6977 - 6982; DOI:
10.1021/ja00389a015
PDF
Mixed-valence semiquinone-catecholate-iron complexes
Michael W. Lynch, Mark Valentine, and David N. Hendrickson
pp 6982 - 6989; DOI:
10.1021/ja00389a016
PDF
Competitive rates of reactions of molybdenum atoms with arenes
B. E. Wilburn and P. S. Skell
pp 6989 - 6994; DOI:
10.1021/ja00389a017
PDF
Dihydrido olefin and solvento complexes of iridium and the mechanisms of olefin hydrogenation and alkane dehydrogenation
Robert H. Crabtree, Peter C. Demou, Don Eden, Jean M. Mihelcic, Charles A. Parnell, Jennifer M. Quirk, and George E. Morris
pp 6994 - 7001; DOI:
10.1021/ja00389a018
PDF
Proton NMR study of the deprotonation of axial imidazole ligands in low-spin ferric porphyrin complexes
V. P. Chacko and Gerd N. La Mar
pp 7002 - 7007; DOI:
10.1021/ja00389a019
PDF
Electronic states of the quadruply bonded Re2Cl82- species: an ab initio theoretical study
P. Jeffrey Hay
pp 7007 - 7017; DOI:
10.1021/ja00389a020
PDF
Overlap control and stability of polyhedral molecules. closo-Carboranes
Eluvathingal D. Jemmis
pp 7017 - 7020; DOI:
10.1021/ja00389a021
PDF
Surface organometallic chemistry: formation of HFe3(CO)11- from Fe3(CO)12 and Fe(CO)5 on silica, alumina, magnesia, and zinc oxide
F. Hugues, J. M. Bassett, Y. Ben Taarit, A. Choplin, M. Primet, D. Rojas, and A. K. Smith
pp 7020 - 7024; DOI:
10.1021/ja00389a022
PDF
Bonding in the diruthenium molecule by ab initio calculations
F. Albert Cotton and Irene Shim
pp 7025 - 7029; DOI:
10.1021/ja00389a023
PDF
Metal alkoxides: models for metal oxides. 3. Further studies of the carbonylation of hexaalkoxides of dimolybdenum and ditungsten (M.tplbond.M) and characterization of M2(O-i-Pr)6(py)2(μ-CO)(M:M) compounds
M. H. Chisholm, J. C. Huffman, J. Leonelli, and I. P. Rothwell
pp 7030 - 7036; DOI:
10.1021/ja00389a024
PDF
Total synthesis of racemic chorismic acid and (-)-5-enolpyruvylshikimic acid ("compound Z1")
Donald A. McGowan and Glenn A. Berchtold
pp 7036 - 7041; DOI:
10.1021/ja00389a025
PDF
Synthesis of alkenes with P-(α-lithioalkyl)phosphinothioic amides
Carl R. Johnson and Robert C. Elliott
pp 7041 - 7044; DOI:
10.1021/ja00389a026
PDF
Nonlinear Broensted correlations: The roles of resonance, solvation, and changing transition-state structure
William P. Jencks, Steven R. Brant, Joseph R. Gandler, Gabriele Fendrich, and Charles Nakamura
pp 7045 - 7051; DOI:
10.1021/ja00389a027
PDF
Conversion of allyl alcohols to 1,3-dienes by sequential sulfenate sulfoxide [2,3]-sigmatropic rearrangement and syn-elimination
Hans J. Reich and Susan Wollowitz
pp 7051 - 7059; DOI:
10.1021/ja00389a028
PDF
Induced circular dichroism of β-cyclodextrin complexes with azanaphthalenes - polarization directions of the π → π transitions in azanaphthalenes
Hiroshi Shimizu, Akira Kaito, and Masahiro Hatano
pp 7059 - 7065; DOI:
10.1021/ja00389a029
PDF
A new total synthesis of the fungal toxin slaframine
Richard A. Gobao, Martin L. Bremmer, and Steven M. Weinreb
pp 7065 - 7068; DOI:
10.1021/ja00389a030
PDF
Thermal decomposition of peroxydisulfate in aqueous solution of benzene-nitrobenzene-benzonitrile mixtures. Formation of OH radicals from benzene radical cations and water at room temperature
Manfred K. Eberhardt, Gines A. Martinez, Juana I. Rivera, and Anselmo Fuentes-Aponte
pp 7069 - 7073; DOI:
10.1021/ja00389a031
PDF
Relative enthalpies of 1,3-dimethyl-2,4-pyrimidinedione, 2,4-dimethoxypyrimidine, and 4-methoxy-1-methyl-1-2-pyrimidinone: estimation of the relative stabilities of two protomers of uracil
Peter Beak and J. Matthew White
pp 7073 - 7077; DOI:
10.1021/ja00389a032
PDF
Structural Characterization of Channel Inclusion Compounds Formed by Furaltadone Hydrochloride: Comparison to the Crystal and Molecular Structures of Furaltadone Base and Moxnidazole Hydrochloride1
Israel Goldberg
pp 7077 - 7084; DOI:
10.1021/ja00389a033
PDF
Gas-phase heteroaromatic substitution. 2. Electrophilic methylation of pyrrole and N-methylpyrrole by CH3XCH3+ (X = fluoro, chloro) ions
Giancarlo Angelini, Cinzia Sparapani, and Maurizio Speranza
pp 7084 - 7091; DOI:
10.1021/ja00389a034
PDF
Gas-phase heteroaromatic substitution. 3. Electrophilic methylation of furan and thiophene by CH3XCH3+ (X = fluoro, chloro) ions
Giancarlo Angelini, Gaetano Lilla, and Maurizio Speranza
pp 7091 - 7098; DOI:
10.1021/ja00389a035
PDF
Time-Resolved Study of the Solvent and Temperature Dependence of Singlet Oxygen (1Δg) Reactivity toward Enol Ethers: Reactivity Parameters Typical of Rapid Reversible Exciplex Formation
A. A. Gorman, I. R. Gould, and I. Hamblett
pp 7098 - 7104; DOI:
10.1021/ja00389a036
PDF
High-Field 1H and 13C NMR Spectroscopic Study of the 2-Norbornyl Cation1a
George A. Olah, G. K. Surya Prakash, Massoud Arvanaghi, and Frank A. L. Anet
pp 7105 - 7108; DOI:
10.1021/ja00389a037
PDF
Betylates. 3. Preparative nucleophilic substitution by way of [2]-, [3]-, and [4]betylates. Stoichiometric phase transfer and substrate-reagent ion-pair (SRIP) reactions of betylates
J. F. King, S. M. Loosmore, M. Aslam, J. D. Lock, and M. J. McGarrity
pp 7108 - 7122; DOI:
10.1021/ja00389a038
PDF
Reactivity of nucleophiles toward and the site of nucleophilic attack on bis(alkylthio) selenides
John L. Kice and Henryka Slebocka-Tilk
pp 7123 - 7130; DOI:
10.1021/ja00389a039
PDF
Activation of reducing agents. Sodium hydride containing complex reducing agents. 18. Study of the nature of complex reducing agents prepared from nickel and zinc salts
Jean Jacques Brunet, Denis Besozzi, Alain Courtois, and Paul Caubere
pp 7130 - 7135; DOI:
10.1021/ja00389a040
PDF
Reagent design and study of 1,4-dithiins as a promising class of reagents (synthons) for cycloaddition. Diels-Alder reactions with anthracene derivatives via charge-transfer complexes
Kenji Hayakawa, Nobuko Mibu, Eiji Osawa, and Ken Kanematsu
pp 7136 - 7142; DOI:
10.1021/ja00389a041
PDF
Single and double ring-closure reactions of dianions of bis(diphenyl thioacetals). A new, synthetically useful principle of carbene generation and intramolecular capture
Theodore Cohen, Robert H. Ritter, and Daniel Ouellette
pp 7142 - 7148; DOI:
10.1021/ja00389a042
PDF
Hydroboration Kinetics. 6.1 Hydroboration of Alkenes with 9-Borabicyclo[3.3.1]nonane Dimer and 9-Borabicyclo[3.3.1]nonane-Lewis Base Complexes in Various Solvents: An Interpretation of the Catalytic Effect of Ether Solvents on the Hydroboration Reaction
Kung K. Wang and Herbert C. Brown
pp 7148 - 7155; DOI:
10.1021/ja00389a043
PDF
Photochemical and photophysical studies of amines with excited flavins. Relevance to the mechanism of action of the flavin-dependent monoamine oxidase
J. T. Simpson, A. Krantz, F. D. Lewis, and B. Kokel
pp 7155 - 7161; DOI:
10.1021/ja00389a044
PDF
Staggered models for asymmetric induction: attack trajectories and conformations of allylic bonds from ab initio transition structures of addition reactions
Michael N. Paddon-Row, Nelson G. Rondan, and K. N. Houk
pp 7162 - 7166; DOI:
10.1021/ja00389a045
PDF
Noninterconverting stereoisomeric bicyclo[4.4.1] bridgehead alkenes
Philip M. Warner, Marie Ah-King, and Richard F. Palmer
pp 7166 - 7173; DOI:
10.1021/ja00389a046
PDF
Conjugate addition of dithianylidene anions to α,β-unsaturated ketones. An application to the total synthesis of (±)-aromatin and (±)-confertin
Frederick E. Ziegler, Jim Min Fang, and Coretta Chan Tam
pp 7174 - 7181; DOI:
10.1021/ja00389a047
PDF
Tandem Cope-Claisen rearrangement. Scope and stereochemistry
Frederick E. Ziegler and John J. Piwinski
pp 7181 - 7190; DOI:
10.1021/ja00389a048
PDF
Picosecond laser photolysis studies of hydrogen-atom transfer reaction via heteroexcimer state in pyrene-primary and pyrene-secondary aromatic amine systems: role of hydrogen-bonding interaction between amino group of donor and π electrons of acceptor in the heteroexcimer
Tadashi Okada, Ichiro Karaki, and Noboru Mataga
pp 7191 - 7195; DOI:
10.1021/ja00389a049
PDF
1,8,17,24-Tetraoxa[8.8](2,6)naphthalenophane-3,5,19,21-tetrayne-10,30-dicarboxylic acid derivatives, novel complexors of aromatic guests
Esa T. Jarvi and Howard W. Whitlock
pp 7196 - 7204; DOI:
10.1021/ja00389a050
PDF
Tetrahedral intermediate in acyl transfer reactions. A revaluation of the significance of rate data used in deriving fundamental linear free energy relationships
DeLos F. DeTar
pp 7205 - 7212; DOI:
10.1021/ja00389a051
PDF
Cadmium binding by biological ligands. 1. Formation of protonated polynuclear complexes between cadmium and D-penicillamine in aqueous solution
Alex Avdeef and Diane L. Kearney
pp 7212 - 7218; DOI:
10.1021/ja00389a052
PDF
Observation of a tetrahedral intermediate and its anion in a hydrolysis reaction. Ring opening of a quinazolinium ion
Oswald S. Tee, Michael Trani, Robert A. McClelland, and N. Esther Seaman
pp 7219 - 7224; DOI:
10.1021/ja00389a053
PDF
Chair topology of the palladium dichloride catalyzed Cope rearrangement of acyclic 1,5-dienes
Larry E. Overman and E. Jon Jacobsen
pp 7225 - 7231; DOI:
10.1021/ja00389a054
PDF
Hydrolysis of adenosine 5'-triphosphate: an isotope-labeling study
Seymour Meyerson, Eugene S. Kuhn, Fausto Ramirez, and James F. Marecek
pp 7231 - 7239; DOI:
10.1021/ja00389a055
PDF
Conformational studies of S-adenosyl-L-homocysteine, a potential inhibitor of S-adenosyl-L-methionine-dependent methyltransferases
Toshimasa Ishida, Atsuko Tanaka, Masatoshi Inoue, Takaji Fujiwara, and Kenichi Tomita
pp 7239 - 7248; DOI:
10.1021/ja00389a056
PDF
Stereoelectronic and conformational effects in Meisenheimer complexes. Intrinsic reactivities of spiro vs. 1,1-dimethoxy and 1-methoxy-1-phenoxy complexes
Claude F. Bernasconi and Keith A. Howard
pp 7248 - 7257; DOI:
10.1021/ja00389a057
PDF
Excited-state σ succinimidyl and glutarimidyl radicals: reversible ring opening
Robert L. Tlumak, James C. Day, Joseph P. Slanga, and Philip S. Skell
pp 7257 - 7267; DOI:
10.1021/ja00389a058
PDF
Reactions of a graded set of radicals with N-bromosuccinimide; two transition states
Robert L. Tlumak and Philip S. Skell
pp 7267 - 7274; DOI:
10.1021/ja00389a059
PDF
Polyether biosynthesis. 2. Origin of the oxygen atoms of monensin A
David E. Cane, Tzyy Chyau Liang, and Heinz Hasler
pp 7274 - 7281; DOI:
10.1021/ja00389a060
PDF
Oligosaccharides from "standardized intermediates." Synthesis of a branched tetrasaccharide glycoside related to the blood group B determinant
Mina A. Nashed and Laurens Anderson
pp 7282 - 7286; DOI:
10.1021/ja00389a061
PDF
Protein-induced aggregation of lipid vesicles. Mechanism of the myelin basic protein-myelin interaction
Paul R. Young, Dominick A. Vacante, and William R. Snyder
pp 7287 - 7291; DOI:
10.1021/ja00389a062
PDF
Molecular structure of 18-deoxyaldosterone and its relationship to receptor binding and activity
William L. Duax, Jane F. Griffin, Phyllis D. Strong, John W. Funder, and Stanley Ulick
pp 7291 - 7293; DOI:
10.1021/ja00389a063
PDF
Quantitative analyses of biochemical kinetic resolutions of enantiomers
Ching Shih Chen, Y. Fujimoto, Gary Girdaukas, and Charles J. Sih
pp 7294 - 7299; DOI:
10.1021/ja00389a064
PDF
p-Guanidinobenzoic acid esters of fluorescein as active-site titrants of serine proteases
L. Lee Melhado, Stuart W. Peltz, Steven P. Leytus, and Walter F. Mangel
pp 7299 - 7306; DOI:
10.1021/ja00389a065
PDF
Biosynthetic and structural studies on pheomelanin
RoseMarie B. Deibel and Miles R. Chedekel
pp 7306 - 7309; DOI:
10.1021/ja00389a066
PDF
Exchangeable proton NMR without base-line distorsion, using new strong-pulse sequences
Pierre Plateau and Maurice Gueron
pp 7310 - 7311; DOI:
10.1021/ja00389a067
PDF
Fast hydrolysis of alkyl radicals with leaving groups in the β position
G. Koltzenburg, G. Behrens, and D. Schulte-Frohlinde
pp 7311 - 7312; DOI:
10.1021/ja00389a068
PDF
Synthesis of organovanadium sulfide cluster compounds via bis(methylcyclopentadienyl)divanadium tetrasulfide
C. Mark Bolinger, Thomas B. Rauchfuss, and Scott R. Wilson
pp 7313 - 7314; DOI:
10.1021/ja00389a069
PDF
Stereochemical consequences of photosensitized and electrode-catalyzed oxygenations of stereoisomeric di-tert-butylbi(bicyclo[3.3.1]non-9-ylidene)
Wataru Ando, Yoshio Kabe, and Toshikazu Takata
pp 7314 - 7316; DOI:
10.1021/ja00389a070
PDF
On the mechanism of oxidation of hydroxycyclohexadienyl radicals with molecular oxygen
N. Narita and T. Tezuka
pp 7316 - 7318; DOI:
10.1021/ja00389a071
PDF
Structural characterization of a complex of Manganese(V) nitrido[tetrakis(p-methoxyphenyl)porphinato] manganese(V)
Craig L. Hill and Frederick J. Hollander
pp 7318 - 7319; DOI:
10.1021/ja00389a072
PDF
Talaromycins: application of homonuclear spin correlation maps to structure assignment
David G. Lynn, Nancy J. Phillips, William C. Hutton, Jeffrey Shabanowitz, D. I. Fennell, and R. J. Cole
pp 7319 - 7322; DOI:
10.1021/ja00389a073
PDF
Transient Raman scattering observation of surface reactions in aqueous titanium dioxide colloids
R. Rossetti, S. M. Beck, and L. E. Brus
pp 7322 - 7324; DOI:
10.1021/ja00389a074
PDF
1H and 2H NMR studies of the catechol dioxygenases
Randall B. Lauffer and Lawrence Que, Jr.
pp 7324 - 7325; DOI:
10.1021/ja00389a075
PDF
Synthesis and structure of diosmacycloalkanes. Reversible addition of ethylene to a methylene-bridged dimer
Keith M. Motyl, Jack R. Norton, Cynthia K. Schauer, and Oren P. Anderson
pp 7325 - 7327; DOI:
10.1021/ja00389a076
PDF
Photosensitized fragmentation of some dinuclear metal carbonyls
Arnold Fox, Anthony Poe, and Ronald Ruminski
pp 7327 - 7329; DOI:
10.1021/ja00389a077
PDF
Definitive evidence for cycloheptatetraene from dehydrobromination of bromocycloheptatrienes
James W. Harris and W. M. Jones
pp 7329 - 7330; DOI:
10.1021/ja00389a078
PDF
Revision of assignment of structure to the pyrrolodiazepinone antitumor antibiotic sibiromycin
Kathlyn A. Parker and Robert E. Babine
pp 7330 - 7331; DOI:
10.1021/ja00389a079
PDF
Unimolecular dissociation of radical cations of monoalkyl acetals
Kiminori Ushida and Tadamasa Shida
pp 7332 - 7333; DOI:
10.1021/ja00389a080
PDF
Analysis of hydrocarbon chain conformation using double quantum coherence 13C NMR
Martin A. Phillippi, Richard J. Wiersema, James R. Brainard, and Robert E. London
pp 7333 - 7334; DOI:
10.1021/ja00389a081
PDF
Synthesis and structure of bis(μ-1-methylhydantoinato-N,O)bis(cis-diammineplatinum(II)) dinitrate. A structural analog of platinum blues
Jean Pierre Laurent, Paule Lepage, and Francoise Dahan
pp 7335 - 7336; DOI:
10.1021/ja00389a082
PDF
Intramolecular [6 + 4] cycloaddition: intramolecular control of periselectivity
Y. N. Gupta, Maria J. Doa, and K. N. Houk
pp 7336 - 7338; DOI:
10.1021/ja00389a083
PDF
Intramolecular addition of an aliphatic C-H bond to a tantalum-carbon double bond
Linda Chamberlain, Ian P. Rothwell, and John C. Huffman
pp 7338 - 7340; DOI:
10.1021/ja00389a084
PDF
Unambiguous assignments of the imino proton resonances of a G ·U wobble base pair
Seiichi Uesugi, Eiko Nakagawa, Eiko Ohtuska, Morio Ikehara, Mayumi Watanabe, Yuji Kobayashi, Yoshimasa Kyogoku, and Masatsune Kainosho
pp 7340 - 7341; DOI:
10.1021/ja00389a085
PDF
Four-center cyclic transition states and their associated deuterium kinetic isotope effects: hydrogenolysis of n-octyllithium
Arturo A. Vitale and Joseph San Filippo, Jr.
pp 7341 - 7343; DOI:
10.1021/ja00389a086
PDF
Midinfrared vibrational circular dichroism studies of cyclophosphamide and its congeners
C. N. Su, T. A. Keiderling, K. Misiura, and W. J. Stec
pp 7343 - 7344; DOI:
10.1021/ja00389a087
PDF
Synthesis of trilithiomethane
Frederick J. Landro, John A. Gurak, John W. Chinn, Jr., Robert M. Newman, and Richard J. Lagow
pp 7345 - 7346; DOI:
10.1021/ja00389a088
PDF
A general homogeneous catalytic method for the homologation of methanol to ethanol
M. J. Chen, H. M. Feder, and J. W. Rathke
pp 7346 - 7347; DOI:
10.1021/ja00389a089
PDF
Synthesis, characterization, and crystal structure of the [Ru10C2(CO)24] dianion. An edge-fused bioctahedral dicarbide cluster
Chi Mi Tai Hayward, John R. Shapley, Melvyn Rowen Churchill, Clifford Bueno, and Arnold L. Rheingold
pp 7347 - 7349; DOI:
10.1021/ja00389a090
PDF
Reactions of nucleophiles with α-halo ketones
Glen A. Russell and Francisco Ros
pp 7349 - 7351; DOI:
10.1021/ja00389a091
PDF
Photoinduced reductive elimination of iron atoms and methane from CH3FeH
Geoffrey A. Ozin and John G. McCaffrey
pp 7351 - 7352; DOI:
10.1021/ja00389a092
PDF
Substrate Organometallic Chemistry of Osmium Tetraoxide: Formation of a Novel Type of Carbon Dioxide Coordination
Jay D. Audett, Terrence J. Collins, Bernard D. Santarsiero, and George H. Spies
pp 7352 - 7353; DOI:
10.1021/ja00389a093
PDF
Resonance Raman spectra of the reaction intermediates of horseradish peroxidase catalysis
Junji Teraoka, Takashi Ogura, and Teizo Kitagawa
pp 7354 - 7356; DOI:
10.1021/ja00389a094
PDF
Photoacoustic measurement of photophysical properties. Lowest triple-state energy of a free base porphyrin
Thomas A. Moore, David Benin, and Roderick Tom
pp 7356 - 7357; DOI:
10.1021/ja00389a095
PDF
Intra- and intermolecular organoactinide carbon-hydrogen activation pathways. Formation, properties, and reactions of thoracyclobutanes
Joseph W. Bruno, Tobin J. Marks, and Victor W. Day
pp 7357 - 7360; DOI:
10.1021/ja00389a096
PDF
Formation of the bridging acylium complex (C5H5)2Fe2(CO)2(μ-CO)(μ-CHCO)+ PF6- by addition of carbon monoxide to a bridging methylidyne-iron complex
Charles P. Casey, Paul J. Fagan, and Victor W. Day
pp 7360 - 7361; DOI:
10.1021/ja00389a097
PDF
Stereochemistry of palytoxin. Part 1. C85-C115 segment
L. L. Klein, W. W. McWhorter, Jr., S. S. Ko, K. P. Pfaff, Y. Kishi, D. Uemura, and Y. Hirata
pp 7362 - 7364; DOI:
10.1021/ja00389a098
PDF
Stereochemistry of palytoxin. Part 2. C1-C6, C47-C74, and C77-C83 segments
S. S. Ko, J. M. Finan, M. Yonaga, Y. Kishi, D. Uemura, and Y. Hirata
pp 7364 - 7367; DOI:
10.1021/ja00389a099
PDF
Stereochemistry of palytoxin. Part 3. C7-C51 segment
H. Fujioka, W. J. Christ, J. K. Cha, J. Leder, Y. Kishi, D. Uemura, and Y. Hirata
pp 7367 - 7369; DOI:
10.1021/ja00389a100
PDF
Stereochemistry of palytoxin. Part 4. Complete structure
J. K. Cha, W. J. Christ, J. M. Finan, H. Fujioka, Y. Kishi, L. L. Klein, S. S. Ko, J. Leder, W. W. McWhorter Jr., K-P Pfaff, and M. Yonaga
pp 7369 - 7371; DOI:
10.1021/ja00389a101
PDF
Practical asymmetric synthesis of aklavinone
J. M. McNamara and Y. Kishi
pp 7371 - 7372; DOI:
10.1021/ja00389a102
PDF
Practical asymmetric syntheses of 11-deoxydaunomycinone and related compounds
H. Sekizaki, M. Jung, J. M. McNamara, and Y. Kishi
pp 7372 - 7374; DOI:
10.1021/ja00389a103
PDF
Inactivation of bovine opsin by all-trans-retinoyl fluoride
Corinne G. Wong and Robert R. Rando
pp 7374 - 7375; DOI:
10.1021/ja00389a104
PDF
Ditungsten(IV) alkoxides as reagents for carbon-carbon bond formation via the reductive coupling of ketones
F. Albert Cotton, David DeMarco, Larry R. Falvello, and Richard A. Walton
pp 7375 - 7376; DOI:
10.1021/ja00389a105
PDF
Squalene synthetase. Inhibition by an ammonium analogue of a carbocationic intermediate in the conversion of presqualene pyrophosphate to squalene
Ronda M. Sandifer, Michael D. Thompson, Roger G. Gaughan, and C. Dale Poulter
pp 7376 - 7378; DOI:
10.1021/ja00389a106
PDF
A long silicon-hydrogen bond or a short silicon-hydrogen nonbond? Neutron-diffraction study of (η5CH3C5H4)(CO)2(H)MnSiF(C6H5)2
Ulrich Schubert, Klaus Ackermann, and Barbara Woerle
pp 7378 - 7380; DOI:
10.1021/ja00389a107
PDF
Resolved 13 C NMR spectra of carbonium ions at cryogenic temperatures. The norbornyl cation at 5 K
Costantino S. Yannoni, Volker Macho, and Philip C. Myhre
pp 7380 - 7381; DOI:
10.1021/ja00389a108
PDF
Experimental evidence for the existence of catalytic sites with different steric structures in supported Ziegler-Natta catalysts
Piero Pino, Giovanni Fochi, Oreste Piccolo, and Umberto Giannini
pp 7381 - 7383; DOI:
10.1021/ja00389a109
PDF
Circular dichroism spectrum of C3-cyclotriguaiacylene after ionization of the phenolic groups. Experimental approach to the magic angle region in C3-cyclotriveratrylene derivatives
Andre Collet and Giovanni Gottarelli
pp 7383 - 7384; DOI:
10.1021/ja00389a110
PDF
Additions and Corrections - Electron Transfer to Complex Ligands. Radical Anions and Organomagnesium Radical Complexes of 2,2'-Bipyridines and 1,10-Phenanthrolines.
Wolfgang Kaim
pp 7385 - 7385; DOI:
10.1021/ja00389a600
PDF
Additions and Corrections - Tricyclo(5.1.0.02,8)octa-3,5-diene(Octavalene)
Manfred Christi, and Reinhard Lang
pp 7385 - 7385; DOI:
10.1021/ja00389a601
PDF
Additions and Corrections - Tris[phenyl(difluorophosphino)amino]phosphine (P[N(C6H5)PF2]3), a Novel Tridentate Strong π-Acceptor Ligand Forming Cage Chelates. Crystal Structure of the Chelate Complex P[N(C6-H5)PF2]3Mo(Co)3
George M. Brown, J. E. Finholt, R. B. King, and T. W. Lee
pp 7385 - 7385; DOI:
10.1021/ja00389a602
PDF
Additions and Corrections - Novel Reaction Course of Oxosulfonium Ylides to Sulfurane Oxides.
Yoshihiko Tanaka, and Hiroshi Ohta
pp 7385 - 7385; DOI:
10.1021/ja00389a603
PDF
Book Reviews

pp 7386 - 7394; DOI:
10.1021/ja00389a604
PDF

Issue 26


Spin density distribution and geometric isomerism in triplet carbenes
Richard S. Hutton and Heinz D. Roth
pp 7395 - 7399; DOI:
10.1021/ja00390a001
PDF
Kinetics of intramolecular electron transfer in binuclear (NC)5Fe(II)-CN-Co(III) chelate complexes by picosecond absorption spectroscopy
B. T. Reagor, D. F. Kelley, D. H. Huchital, and P. M. Rentzepis
pp 7400 - 7403; DOI:
10.1021/ja00390a002
PDF
Small-angle x-ray scattering by nonaqueous concentrated electrolytes: lithium perchlorate and zinc bromide in ethyl acetate
M. Nicolas and E. Dartyge
pp 7403 - 7406; DOI:
10.1021/ja00390a003
PDF
Photoinduced electron-transfer processes in monolayer assemblies. Supersensitization in a three-component system
Thomas L. Penner and Dietmar Moebius
pp 7407 - 7413; DOI:
10.1021/ja00390a004
PDF
Electron transmission study of the splitting of the .pi.* molecular orbitals of angle-strained cyclic acetylenes: implications for the electrophilicity of alkynes
Lily Ng, Kenneth D. Jordan, Adolf Krebs, and Wolfgang Rueger
pp 7414 - 7416; DOI:
10.1021/ja00390a005
PDF
Fourier analysis of the orbital momentum densities of carbon monoxide, nitric oxide, and oxygen
John A. Tossell, John H. Moore, Michael A. Coplan, Giovanni Stefani, and Rossana Camilloni
pp 7416 - 7423; DOI:
10.1021/ja00390a006
PDF
Topological study of chemical reactivity. Diels-Alder reaction
Jiri Pancir
pp 7424 - 7430; DOI:
10.1021/ja00390a007
PDF
Absolute configuration of 1,2-disubstituted trans-cyclodecenes based on chemical correlation with (+)-dimethyl (2R)-2-butyl-2-methyloctanedioate
James A. Marshall and Katherine E. Flynn
pp 7430 - 7435; DOI:
10.1021/ja00390a008
PDF
Collision-induced dissociation of proton-bound alcohol dimers by Fourier-transform mass spectrometry
R. C. Burnier, R. B. Cody, and B. S. Freiser
pp 7436 - 7441; DOI:
10.1021/ja00390a009
PDF
Multinuclear, multifield, and multiphase nuclear magnetic resonance study of cadmium meso-tetraphenylporphyrin and its pyridine adduct
Hans J. Jakobsen, Paul D. Ellis, Ruth R. Inners, and Claus F. Jensen
pp 7442 - 7452; DOI:
10.1021/ja00390a010
PDF
Surface structure and temperature dependence of light-alkane skeletal rearrangement reactions catalyzed over platinum single-crystal surfaces
S. Mark Davis, Francisco Zaera, and Gabor A. Somorjai
pp 7453 - 7461; DOI:
10.1021/ja00390a011
PDF
Tris(2,2'-bipyridine)ruthenium(II)-sensitized photooxidation of phenols. Environmental effects on electron transfer yields and kinetics
K. Miedlar and P. K. Das
pp 7462 - 7469; DOI:
10.1021/ja00390a012
PDF
Crystal and molecular structure of .beta.-maltose octaacetate. A model in retrospect for amylose triacetate?
F. Brisse, R. H. Marchessault, S. Perez, and P. Zugenmaier
pp 7470 - 7476; DOI:
10.1021/ja00390a013
PDF
Separability of endovesicular and exovesicular reactions
Rober A. Moss, Yasuji Ihara, and George O. Bizzigotti
pp 7476 - 7478; DOI:
10.1021/ja00390a014
PDF
Mechanism of the apparent electron-transfer reaction between tert-butoxide ion and nitrobenzene
Robert D. Guthrie and Dale E. Nutter
pp 7478 - 7482; DOI:
10.1021/ja00390a015
PDF
Multiple metal-carbon bonds. 27. Preparation of tungsten(VI) phenylimido alkyl and alkylidene complexes
Steven F. Pedersen and Richard R. Schrock
pp 7483 - 7491; DOI:
10.1021/ja00390a016
PDF
Kinetics and stereochemistry of the titanacyclobutane-titanaethylene interconversion. Investigation of a degenerate olefin metathesis reaction
J. Bosco Lee, Kevin C. Ott, and Robert H. Grubbs
pp 7491 - 7496; DOI:
10.1021/ja00390a017
PDF
Preparation, properties, and kinetics of the reaction of manganese(0) radicals Mn(CO)3(R3P)2 with tributyltin hydride
Sharon B. McCullen and Theodore L. Brown
pp 7496 - 7500; DOI:
10.1021/ja00390a018
PDF
Electron deformation density for the "supershort" chromium-chromium quadruple bond: a joint experimental and theoretical study
Andre Mitschler, Bernard Rees, Roland Wiest, and Marc Benard
pp 7501 - 7509; DOI:
10.1021/ja00390a019
PDF
Pentacyanoferrate(II) complexes of amino acids
Henrique Toma, Alzir A. Batista, and Harry B. Gray
pp 7509 - 7515; DOI:
10.1021/ja00390a020
PDF
Oxidation-reduction equilibrium of cytochrome b5
Lorne S. Reid, Vernon T. Taniguchi, Harry B. Gray, and A. Grant Mauk
pp 7516 - 7519; DOI:
10.1021/ja00390a021
PDF
Electrochemical and spectral investigations of ring-substituted bipyridine complexes of ruthenium
C. Michael Elliott and Elise J. Hershenhart
pp 7519 - 7526; DOI:
10.1021/ja00390a022
PDF
Photophysical and photochemical behavior of tetrahydridobis(bis(1,2-diphenylphosphino)ethane)molybdenum and -tungsten: optical emission and photoreduction of alkenes
James L. Graff, Ted J. Sobieralski, Mark S. Wrighton, and Gregory L. Geoffroy
pp 7526 - 7533; DOI:
10.1021/ja00390a023
PDF
Photochemistry of divinylboranamines
Ted J. Sobieralski and Kenneth G. Hancock
pp 7533 - 7541; DOI:
10.1021/ja00390a024
PDF
Mechanism of cyclization of divinyl-N-phenylboranamines
Ted J. Sobieralski and Kenneth G. Hancock
pp 7542 - 7548; DOI:
10.1021/ja00390a025
PDF
Organometallic electron reservoirs. 7. One-step multiple formation of carbon-carbon bonds in CpFe+(arene) sandwiches and unusual C6Et6 geometry in the x-ray crystal structure of CpFe+(.eta.6-C6Et6) PF6-
Jean Rene Hamon, Jean Yves Saillard, Albert Le Beuze, Michael J. McGlinchey, and Didier Astruc
pp 7549 - 7555; DOI:
10.1021/ja00390a026
PDF
Copper(I) and copper(II) complexes of a new tetradentate chelating ligand containing imidazole and thio ether groups. The x-ray structure of trigonal-bipyramidal [(1,6-bis(N-benzylimidazol-2-yl)-2,5-dithiahexane-N,N,S,S)]bromocopper(II) bromide
Paul J. M. W. L. Birker, Erik F. Godefroi, Janneke Helder, and Jan Reedijk
pp 7556 - 7560; DOI:
10.1021/ja00390a027
PDF
Single-crystal EPR spectra of two nickel(III) tetraazamacrocycle complexes
A. McAuley, J. R. Morton, and K. F. Preston
pp 7561 - 7563; DOI:
10.1021/ja00390a028
PDF
Mechanism of ozonolysis of acetylenes: evidence for a free-radical pathway for the decomposition of intermediates
William A. Pryor, C. K. Govindan, and Daniel F. Church
pp 7563 - 7566; DOI:
10.1021/ja00390a029
PDF
Simple enols. 2. Kinetics and mechanism of the ketonization of vinyl alcohol
Brian Capon and Cesar Zucco
pp 7567 - 7572; DOI:
10.1021/ja00390a030
PDF
Extending the scope of enantiomer resolution by complexation gas chromatography
Volker Schurig and Waldemar Buerkle
pp 7573 - 7580; DOI:
10.1021/ja00390a031
PDF
Charge transfer and addition products between alkylated phenazine donors and ethanetetracarbonitrile (TCNE): crystal and molecular structure of the dye 2,2'-(2,3,5,10-tetrahydro-5,10-dimethylphenazine-2,3-diylidene)bis(propanedinitrile) (TMPP)
K. Dietz, H. J. Keller, D. Noethe, and D. Wehe
pp 7581 - 7585; DOI:
10.1021/ja00390a032
PDF
Chemistry of anthocyanin pigments. 9. UV-visible spectrophotometric determination of the acidity constants of apigeninidin and three related 3-deoxyflavylium salts
R. Brouillard, G. A. Iacobucci, and J. G. Sweeny
pp 7585 - 7590; DOI:
10.1021/ja00390a033
PDF
Total synthesis of dl-tazettine and 6a-epipretazettine: a formal synthesis of dl-pretazettine. Some observations on the relationship of 6a-epipretazettine and tazettine
Samuel Danishefsky, Joel Morris, George Mullen, and Ronald Gammill
pp 7591 - 7599; DOI:
10.1021/ja00390a034
PDF
Transition-state barrier for electrophilic reactions. Solvation of charge-transfer ion pairs as the unifying factor in alkene addition and aromatic substitution with bromine
S. Fukuzumi and J. K. Kochi
pp 7599 - 7609; DOI:
10.1021/ja00390a035
PDF
Syntheses of polycyclic ring systems based on the new generation of o-quinodimethanes
Yoshihiko Ito, Masashi Nakatsuka, and Takeo Saegusa
pp 7609 - 7622; DOI:
10.1021/ja00390a036
PDF
Synthetic studies in the indole series. Preparation of the unique antibiotic alkaloid chuangxinmycin by a nitro group displacement reaction
Alan P. Kozikowski, Michael N. Greco, and James P. Springer
pp 7622 - 7626; DOI:
10.1021/ja00390a037
PDF
Structure and conformation of the antiviral nucleoside 2'-fluoro-5-iodoarabinosylcytosine (FIAC). The gauche effect in nucleosides
George I. Birnbaum, Miroslaw Cygler, Kyoichi A. Watanabe, and Jack J. Fox
pp 7626 - 7630; DOI:
10.1021/ja00390a038
PDF
Photophysical properties of biologically important molecules related to proximity effects: psoralens
Ting Ing Lai, Bee T. Lim, and E. C. Lim
pp 7631 - 7635; DOI:
10.1021/ja00390a039
PDF
Modification of DNA with potent mutacarcinogenic 2-amino-6-methyldipyrido[1,2-a:3',2'-d]imidazole isolated from a glutamic acid pyrolysate: structure of the modified nucleic acid base and initial chemical event caused by the mutagen
Yuichi Hashimoto, Koichi Shudo, and Toshihiko Okamoto
pp 7636 - 7640; DOI:
10.1021/ja00390a040
PDF
Cyclic voltammetry and derivative cyclic voltabsorptometry of purified horse heart cytochrome c at tin-doped indium oxide optically transparent electrodes
Edmond F. Bowden, Fred M. Hawkridge, Jan F. Chlebowski, Eric E. Bancroft, Colin Thorpe, and Henry N. Blount
pp 7641 - 7644; DOI:
10.1021/ja00390a041
PDF
Restricted intramolecular rotation of the potent uncoupler of oxidative phosphorylation of SF 6847 [(3,5-di-tert-butyl-4-hydroxybenzylidene)malononitrile]: enhanced motional freedom of SF 6847 anion by formation of a 1:1:1 complex with valinomycin and potassium(+) ion
Kenichi Yoshikawa and Hiroshi Terada
pp 7644 - 7646; DOI:
10.1021/ja00390a042
PDF
Hydrophobic effect on chain folding. The trans to gauche isomerization of n-butane in water
R. O. Rosenberg, R. Mikkilineni, and B. J. Berne
pp 7647 - 7649; DOI:
10.1021/ja00390a043
PDF
Structures and stabilities of 1,6-methano[10]annulene and its derivatives
Leslie Farnell and Leo Radom
pp 7650 - 7654; DOI:
10.1021/ja00390a044
PDF
Analysis of the kinetics of electron transfer between blue copper proteins and inorganic redox agents. Reactions involving bis(dipicolinate) complexes of cobalt(III) and iron(II) and stellacyanin, plastocyanin, and azurin
A. Grant Mauk, Emilio Bordignon, and Harry B. Gray
pp 7654 - 7657; DOI:
10.1021/ja00390a045
PDF
Synthesis of (trifluoromethanesulfonato)pentaammineosmium(III): osmium(III) pentaammine complexes
Peter A. Lay, Roy H. Magnuson, Henry Taube, and J. Sen
pp 7658 - 7659; DOI:
10.1021/ja00390a046
PDF
Electron transfer across polypeptides. 4. Intramolecular electron transfer from ruthenium(II) to iron(III) in histidine-33-modified horse heart cytochrome c
Stephan S. Isied, Greg Worosila, and Stephen J. Atherton
pp 7659 - 7661; DOI:
10.1021/ja00390a047
PDF
Reaction between cyanate ion and ethylene coordinated to platinum: a new route to carbamoyl complexes
Luciana Maresca, Giovanni Natile, Anna Maria Manotti-Lanfredi, and Antonio Tiripicchio
pp 7661 - 7662; DOI:
10.1021/ja00390a048
PDF
Selective coupling of [(alkylthio)allyl]titanium reagent with carbonyl compounds. Facile entry to alkenyloxiranes and 2-(arylthio)-1,3-butadienes
Yoshihiko Ikeda, Kyoji Furuta, Noriyuki Meguriya, Nobuo Ikeda, and Hisashi Yamamoto
pp 7663 - 7665; DOI:
10.1021/ja00390a049
PDF
First experimental demonstration of NMR dynamic frequency shifts: dispersion versus absorption (DISPA) line shape analysis of sodium-23 in aqueous sodium laurate/lauric acid solution
Alan G. Marshall, T. C. L. Wang, Charles E. Cottrell, and Lawrence G. Werbelow
pp 7665 - 7666; DOI:
10.1021/ja00390a050
PDF
Silicon-induced fragmentations: stereoselective preparation of (Z,E)- and (Z,Z)-1,4-dienamine derivatives. Synthesis of (9Z,12E)-tetradecadien-1-yl acetate, pheromone of various Lepidoptera
N. V. Bac and Y. Langlois
pp 7666 - 7667; DOI:
10.1021/ja00390a051
PDF
Chiral allenylboronic esters: a practical reagent for enantioselective carbon-carbon bond formation
Ryuichi Haruta, Masaharu Ishiguro, Nobuo Ikeda, and Hisashi Yamamoto
pp 7667 - 7669; DOI:
10.1021/ja00390a052
PDF
Structure of the [B2H7]- anion
Sheldon G. Shore, Steven H. Lawrence, Michael I. Watkins, and Robert Bau
pp 7669 - 7670; DOI:
10.1021/ja00390a053
PDF
A [4 + 4] annulation approach to eight-membered carbocyclic compounds
Rick L. Danheiser, Stephen K. Gee, and Howard Sard
pp 7670 - 7672; DOI:
10.1021/ja00390a054
PDF
Stabilization of dimercury through coordination to platinum cluster units
Alberto Albinati, Alfred Moor, Paul S. Pregosin, and Luigi M. Venanzi
pp 7672 - 7673; DOI:
10.1021/ja00390a055
PDF
Book Reviews

pp 7673 - 7674; DOI:
10.1021/ja00390a600
PDF